Abstract
We derive an analytical expression for the magnetochiral birefringence of a dilute diamagnetic chiral molecular medium subjet to a constant magnetic field. We use the single-oscillator model of Condon [Rev. Mod. Phys. 9, 432 (1937)] and Condon et al. [J. Chem. Phys. 5, 753 (1937)] to describe the optical properties of the individual molecules. The result is a function of the refractive index and the rotatory power. This result is compared to experimental data.
Similar content being viewed by others
References
E.U. Condon, Rev. Mod. Phys. 9, 432 (1937)
E.U. Condon, W. Altar, H. Eyring, J. Chem. Phys. 5, 753 (1937)
M.P. Groenewege, Mol. Phys. 5, 541 (1962)
D.L. Portigal, E. Burstein, J. Phys. Chem. Solids 32, 603 (1971)
L.D. Barron, J. Vrbancich, Mol. Phys. 51, 715 (1984)
G.H. Wagnière, A. Meier, Chem. Phys. Lett. 93, 78 (1982)
N.B. Baranova, Y.V. Bogdanov, B.Y. Zel’dovich, Opt. Commun. 22, 243 (1977)
G.L.J.A. Rikken, E. Raupach, Nature 390, 493 (1997)
P. Kleindienst, G.H. Wagnière, Chem. Phys. Lett. 288, 89 (1998)
N.B. Baranova, B.Y. Zel’dovich, Mol. Phys. 38, 1085 (1979)
S. Coriani, M. Pecul, A. Rizzo, P. Jørgensen, M. Jaszuński, J. Chem. Phys. 117, 6417 (2002)
B. Jansík, A. Rizzo, L. Frediani, K. Ruud, S. Coriani, J. Chem. Phys. 125, 234105 (2006)
J. Applequist, J. Chem. Phys. 58, 4251 (1973)
F.U. Pinheiro, B.A. van Tiggelen, Phys. Rev. E 66, 016607 (2002)
T. Ruchon, M. Vallet, D. Chauvat, A. Le Floch, J. Chem. Phys. 125, 084104 (2006)
H. Herold, H. Ruder, G. Wunner, J. Phys. B 14, 751 (1981)
O. Dippel, P. Schmelcher, L.S. Cederbaum, Phys. Rev. A 49, 4415 (1994)
J. Jackson, Classical Electrodynamics, 3rd edn. (Wiley, New York, 1999)
M. Vallet, R. Ghosh, A. Le Floch, T. Ruchon, F. Bretenaker, J.-Y. Thépot, Phys. Rev. Lett. 87, 183003 (2001)
N.G. Kalugin, P. Kleindienst, G.H. Wagnière, Chem. Phys. 248, 105 (1999)
D.R. Lide, Handbook of Chemistry and Physics, 84th edn. (CRC Press LLC, 2004)
T. Ruchon, M. Vallet, D. Chauvat, A. Le Floch, J.-Y. Thépot, Phys. Rev. A 72, 043405 (2005)
E. Charney, The Molecular Basis of Optical Activity (John Wiley & Sons, New York, 1979)
J.G. Kirkwood, J. Chem. Phys. 5, 479 (1937)
M. Donaire, B.A. van Tiggelen, G.L.J.A. Rikken, Phys. Rev. Lett. 111, 143602 (2013)
D.P. Craig, T. Thirunamachandran, Molecular Quantum Electrodynamics (Dover Publications, New York, 1998)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Donaire, M., Rikken, G. & van Tiggelen, B. A single-oscillator quantum model for magnetochiral birefringence. Eur. Phys. J. D 68, 33 (2014). https://doi.org/10.1140/epjd/e2013-40445-2
Received:
Revised:
Published:
DOI: https://doi.org/10.1140/epjd/e2013-40445-2