Paramagnetic relaxation of spin polarized 3He at coated glass walls
In this second in a series of three papers on wall relaxation of 3He-spins we discuss relaxation in metal-coated glass cells in terms of hyperfine coupling to paramagnetic conduction electrons at the Fermi surface. This scales with the square of the work function of the coating and thereby also with its He-adsorption energy. In this sense we investigate coatings with particularly low work function and adsorption energy, namely Cs and Cs-suboxides. Although we observe a suppression of relaxation rates by two orders of magnitude as compared to bare Pyrex and fused silica walls, their temperature dependence still shows the same Arrhenius dependence as observed for bare substrates, instead of a T 3/2 dependence expected for a metallic surface. From this finding we conclude that, on one hand, the surface coverage is not complete and, on the other hand, the relaxation at the alkali surface itself is extremely slow. This finding is supported, too, by a semi-empirical estimate based on measured relaxation rates at ordinary metal surfaces, rescaled then with the respective dependence on adsorption energy.
PACS.33.25.+k Nuclear resonance and relaxation 34.50.Dy Interactions of atoms and molecules with surfaces; photon and electron emission; neutralization of ions 67.65.+z Spin-polarized hydrogen and helium
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