Abstract.
The FTIR spectrum of monoisotopic stannane 116SnH4 has been recorded in the 600-850 cm-1 range, with the Bruker 120 HR interferometer at Giessen, Germany. The resolution was 2.1 x 10-3 cm-1. The analysis of infrared transitions in this region enabled Brunet et al. [1] to assign many lines to the bending dyad \(\nu_2/\nu_4\). However, several lines in this spectrum were found to be unassigned. In a recent work [2], we have analysed the infrared spectrum of stannane in the bending triad region at 1400 cm-1. The results obtained enabled us to assign directly, for the spectrum in the region 600-850 cm-1, 163 of the observed transitions to the hot band {bending triad} minus {bending dyad} up to J = 9. These transitions were combined to the infrared data corresponding to the bending triad (\(2\nu_2,\nu_2 + \nu_4,2\nu_4\)), to refine a set of Hamiltonian parameters for the two bands \(2\nu_2\) and (\(\nu_2 + \nu_4\)) [2].
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Received: 7 August 2003, Published online: 8 October 2003
PACS:
33.20.Vq Vibration-rotation analysis - 33.20.Ea Infrared spectra
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Tabyaoui, A., Pierre, G. & Bürger, H. Analysis of the hot band of stannane \(\mathsf{^{116}}\)SnH\(\mathsf{_4}\) in the 600-850 cm \(\mathsf{^{-1}}\) range. Eur. Phys. J. D 28, 49–57 (2004). https://doi.org/10.1140/epjd/e2003-00283-5
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DOI: https://doi.org/10.1140/epjd/e2003-00283-5