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Hydrogen atom transfer in indole clusters: formation dynamics of , n = 1-6, fragments

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The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics Aims and scope Submit manuscript

Abstract:

The H atom transfer reaction in electronically excited indole(NH 3 ) n clusters is studied in pump-probe experiments with femtosecond laser pulses. By applying different probe photon energies we are able to detect the dissociation products (NH 3 ) n - 1 NH 4 for n = 1-6. Furthermore we show that the analysis of the corresponding ion signals is not distorted by contributions from larger cluster ions due to evaporation of NH 3 molecules. The formation times of the products are ca. 140ps for n = 2-4 and about 80ps for n = 5, 6.

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Authors and Affiliations

  1. Max-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie, Max-Born-Str. 2A, 12489 Berlin-Adlershof, Germany, , , , , , DE

    H. Lippert, V. Stert, L. Hesse, C.P. Schulz, W. Radloff & I.V. Hertel

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  1. H. Lippert
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  2. V. Stert
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  3. L. Hesse
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  4. C.P. Schulz
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  5. W. Radloff
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  6. I.V. Hertel
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Received 30 April 2002 / Received in final form 29 May 2002 Published online 13 September 2002

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Lippert, H., Stert, V., Hesse, L. et al. Hydrogen atom transfer in indole clusters: formation dynamics of , n = 1-6, fragments. Eur. Phys. J. D 20, 445–448 (2002). https://doi.org/10.1140/epjd/e2002-00161-8

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  • DOI: https://doi.org/10.1140/epjd/e2002-00161-8

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