Abstract
Two dimension (2D) Blume–Emery–Griffiths (BEG) spin-1 model is used to investigate spin-crossover (SCO) and Prussian Blue Analogs (PBAs) solids. The model considered here allows the system to switch between two fundamental spin states named high-spin (HS) and low-spin (LS) states subsequent to the strength of magnetic and elastic interactions which acting on lattice nearest neighbors sites. These interactions are assumed as temperature-dependent due to the system volume changes accompanying with the spin transition phenomenon. In addition, SCO molecules are subject to a variable frequency of magnetic-field lifting the degeneracy in the HS state. A stochastic cooperative dynamics of this BEG-like Hamiltonian, describing the nonequilibrium properties of ferromagnetic SCO solids, is derived from the Glauber approach, with appropriate Arrhenius microscopic transition rates. At the vicinity of the thermal hysteresis loop of the free system (obtained with zero-magnetic field), investigations with variable oscillation frequency of the magnetic-field, h, demonstrated significant changes on the isothermal relaxation curves of the magnetization, m, and the high-spin fraction, \(n_{HS}\), which fall down on dynamical equilibrium characterized by limiting cycles in the spaces m-h and \(n_{HS}\)-h. In addition, the clear evidence of dephasing between the responses of the two order parameters (m and \(n_{HS}\)) and the particular “butterfly” shape of the limiting cycles of the HS fraction, enforces the idea that the non-linear effects, propagating through the interaction parameters, are operating in this system. These behaviors demonstrate that radio-frequency magnetic field can be used in these SCO systems to achieve a reversible switch and control of both magnetization and HS fraction, even if the latter is partial. These results are in direct relation with the intrinsic static multi-stability of the system under static magnetic-field, which is enhanced/revealed by applying an oscillating magnetic-field.
Graphical abstract
The nonequilibrium properties of spin-crossover (SCO) solids are analyzed within 2D Blume–Emery–Griffiths (BEG) spin-1 model in which SCO molecules are subjected to a variable frequency of magnetic-field energy controlled by the parameter \(\lambda \). Within the lattice configuration, to account for spin-phonon interactions, the strengths of magnetic and elastic interactions between nearest neighbors (nn) sites are temperature-dependent. At the vicinity of the thermal hysteresis loop of the free system, the isothermal relaxation curves of the magnetization m and the high-spin fraction, \(n_{HS}\) fall down on dynamical equilibrium characterized by limiting cycles which depend on the initial conditions in the spaces \(m-h\) and \(n_{HS}-h\). The shift phase appears between the response of the two parameters (m and \(n_{HS}\)) which particular non-linear behaviors would seem to stem from the interactions propagating within the system through the interaction parameters. These behaviors revealed that radio-frequency magnetic-field can be used in these SCO systems to achieve a reversible switch and control of both magnetization and HS fraction.
Graphic abstract
Similar content being viewed by others
Data Availability Statement
This manuscript has associated data in a data repository. [Authors’ comment: Numerical results are obtained with ForTran Code based on evolving system equations and help us to display all Figures reported in this paper, which are available on request by T. D. OKE.]
References
P. Gütlich, H.A. Goodwin, Spin-Crossover in transition Metal Compounds\(I\), \(II\)and\(III\) (Springer, Berlin, 2004), pp. 233–235
J.H. Ammeter, Nov. J. Chem. 4, 631 (1980)
S. Ohkoshi, K. Hashimoto, J. Am. Chem. Soc. 121, 10591 (1999)
S. Ohkoshi, S. Ikeda, T. Hozumi, T. Kashiwagi, K. Hashimoto, J. Am. Chem. Soc. 128, 5320 (2006)
S. Ohkoshi, K. Imoto, Y. Tsunobuchi, S. Takano, H. Tokoro, Nat. Chem. 3, 564 (2011). https://doi.org/10.1038/nchem.1067
P. Gütlich, A. Hauser, H. Spiering, Angew. Chem. Int. Ed. 33, 2024 (1994)
J.M. Herrera, V. Marvand, M. Verdager, J. Marrot, M. kalisz, C. Mathoniere, Angew. Chem. Int. Ed. 43, 5468 (2004)
N. Nègre, C. Conséjo, M. Goiran, A. Bousseksou, F. Varret, J.P. Tuchagues, R. Barbaste, S. Askénazy, J.G. Haasnoot, Phys. B 294–295, 91 (2001)
H. Tokoro, S.-I. Ohkoshi, K. Hashimoto, Appl. Phys. Lett. 82, 1245 (2003)
F. Varret, K. Boukheddaden, C. Chong, A. Goujon, B. Gillon, J. Jeftic, A. Hausser, Eur. Phys. Lett. 77, 30007 (2007)
D.A. Pejakovíc, J.L. Maison, C. Kitamura, J.S. Miller, A.J. Epstein, Polyhedron 20, 1435 (2001)
K. Kato, Y. Moritomo, M. Takata, M. Sakata, M. Umekawa, N. Hamada, S. Ohkoshi, H. Tokoro, K. Hashimoto, Phys. Lett. 91, 255502 (2003)
H. Banerjee, S. Chakraborty, T. Saha-Dasgupta, Inorganics 5, 47 (2017)
A. Gîndulescu, A. Rotaru, J. Linares, M. Dimian, J. Naser, J. Phys: Conf. Ser. 268, 012007 (2011)
M. Nishino, S. Miyashita, P.A. Rikvold, Phys. Rev. B 96, 144425 (2017)
C. Enashescu, L. Stoleriu, A. Stancu, A. Hausser, Phys. Rev. B 82, 104114 (2010)
M. Sorai, S. Seki, J. Phys. Chem. Solids 35, 555 (1974)
M.M. Dîrtu, C. Neuhausen, A.D. Naik, A. Rotaru, L. Spinu, Y. Garcia, Inorg. Chem. 49, 5723 (2010)
W. Nicolazzi, J. Pavlik, S. Bedoui, G. Molnár, A. Bousseksou, Eur. Phys. J. Spec. Topics 222, 1137 (2013)
M. Paez-Espejo, M. Sy, K. Boukheddaden, J. Am. Chem. Soc. 138, 3202 (2016)
M.A. Halcrow, Spin-Crossover Materials: Properties and Applications (Wiley, New York, 2013)
P. Gütlich, A.B. Gasper, Y. Garcia, Beilstein J. Org. Chem. 9, 342 (2013)
C.M. Quintero, G. Félix, I. Suleimanov, J.S. Costa, G. Molnár, L. Salmon, W. Nicolazzi, A. Bousseksou, Beilstein J. Nanotechnol. 5, 2230 (2014)
E. König, Struct. Bond. 7, 51 (1991)
H. Spiering, N. Willenbacher, J. Phys.: Condens. Matter 1, 10089 (1989)
Y. Ogawa, A. Mino, S. Keshihara, K. Koshino, T. Ogawa, C. Urano, H. Tagaki, Phys. Rev. Lett. 84, 3181 (2000)
K. Boukheddaden, J. Linares, H. Spiering, F. Varret, Eur. Phys. J. B 15, 317 (2000)
K. Boukheddaden, I. Shteto, B. Hôo, F. Varret, Phys. Rev. B 62, 14796 (2000)
K. Boukheddaden, I. Shteto, B. Hôo, F. Varret, Phys. Rev. B 62, 14806 (2000)
M. Nishino, S. Miyashita, Phys. Rev. B 63, 174404 (2001)
M. Nishino, K. Boukheddaden, S. Miyashita, F. Varret, Phys. Rev. B 72, 064452 (2005)
K. Boukheddaden, M. Nishino, S. Miyashita, F. Varret, Phys. Rev. 72, 014467 (2005)
H. Watanabe, N. Bréfuel, S. Mouri, J.-P. Tuchagues, E. Collet, and Tanaka. Eur. Phys. Lett. 96, 17004 (2011)
K. Boukheddaden, M. Sy, F. Varret, M. Paez-Espejo, A. Slimani, F. Varret, Phys. Rev. B 486, 187 (2016)
M. Paez-Espejo, M. Sy, F. Varret, K. Boukheddaden, Phys. Rev. B 89, 024306 (2014)
C. Chong, F. Varret, K. Boukheddaden, Phys. Rev. B 81, 014104 (2010)
C. Enachescu, R. Tanasa, A. Stancu, F. Varret, J. Linares, E. Codjovi, Phys. Rev. B 72, 054413 (2005)
M. Sy, D. Garrot, A. Slimani, M. Paez-Espejo, F. Varret, K. Boukheddaden, Angew. Chem. 55, 1755 (2016)
K. Boukheddaden, Eur. J. Inorg. Chem. https://doi.org/10.1002/ejic.201201093
B. Hôo, K. Boukheddaden, F. Varret, Eur. Phys. J. B 17, 449 (2000)
A. Slimani, F. Varret, K. Boukheddaden, D. Garrot, H. Oubouchou, S. Kaizaki, Phys. Rev. Lett. 110, 087208 (2013)
H. Romstedt, A. Hauser, H. Spiering, J. Phys. Chem. Solids 59, 265 (1998)
K. Boukheddaden, F. Varret, S. Salinke, J. Linares, E. Codjovi, Phase Trans. 75, 733 (2002)
S. Mouri, K. Tanaka, S. Bonhommeau, N.O. Moussa, G. Molnár, A. Bousseksou, Phys. Rev. B 78, 174308 (2008)
A. Bousseksou, J. Nasser, J. Linares, K. Boukheddaden, F. Varret, J. Phys. I 2, 1381 (1992)
A. Bousseksou, F. Varret, J. Nasser, J. Phys. I 3, 1463 (1993)
N. Sasaki, T. Kambara, J. Phys. C 15, 1035 (1982)
A. Bousseksou, N. Nègre, M. Goiran, L. Salmon, J.-P. Tuchagues, M.-L. Boillot, K. Boukheddaden, F. Varret, Eur. Phys. J. B 13, 451 (2000)
A. Bousseksou, F. Varret, M. Goiran, K. Boukheddaden, J.-P. Tuchagues, Top. Curr. Chem. 235, 65 (2004)
A. Bousseksou, K. Boukheddaden, M. Goiran, C. Consejo, M.-L. Boillot, J.-P. Tuchagues, Phys. Rev. 65, 172412 (2002)
S. Bonhommeau, G. Molnár, M. Goiran, K. Boukheddaden, A. Bousseksou, Phys. Rev. B 74, 064424 (2006)
J.L. Her, Y.H. Matsuda, M. Nakano, Y. Niva, Y. Inada, J. Appl. Phys. 111, 053921 (2012)
Y. Garcia, O. Kahn, J.-P. Ader, A. Buzdin, Y. Meurdesoif, M. Guillot, Phys. Lett. A 271, 145 (2000)
S.B. Ogou, T.D. Oke, F. Hontinfinde, K. Boukheddaden, Adv. Theory Simul. 2, 1800192 (2019)
T.D. Oke, M. Ndiaye, F. Hontinfinde, K. Boukheddaden, Eur. Phys. J. B 94, 38 (2021)
T.D. Oke, F. Hontinfinde, K. Boukheddaden, Eur. Phys. J. B 86, 271 (2013)
T.D. Oke, F. Hontinfinde, K. Boukheddaden, Appl. Phys. A 120, 309 (2015)
T.D. Oke, F. Hontinfinde, K. Boukheddaden, Comput. Condens. Matter 9, 27 (2016)
M. Nishino, K. Boukheddaden, S. Miyashita, F. Varret, Polyhedron 24, 2852 (2005)
M. Nishino, K. Boukheddaden, S. Miyashita, F. Varret, Phys. Rev. B, 68, 224402 (2003) (references therein)
G. D’Avino, A. Painelli, K. Boukheddaden, Phys. Rev. B 84, 104119 (2011)
T. Sauer, Numerical Analysis, 2nd edn. (Pearson Education, Inc., Hoboken, 2012)
R.L. Burden, J.D. Faires, Numerical Analysis, 9th edn. (Cengage, Boston, 2010)
A. Quarteroni, R. Sacco, F. Saleri, Méthodes Numériques: Algorithmes, analyse et applications (Springer-Verlag, Milano, 2007)
S.D. Conte, C. de Boor, Elementary Numerical Analysis: An Algorithmic Approach, 3rd edn. (McGraw-Hill, New-York, 1980)
Acknowledgements
This research was funded by ANR (Agence Nationale de la Recherche Scientifique), grant number Mol-CoSM N\(^\circ \) ANR-20-CE07-0028-02 and the Universities of Versailles and Paris-Saclay-UPSAY, the CNRS (Centre National de la Recherche Scientifique) and LIA (International Associate French Japan Laboratory). T.D. OKE acknowledges financial support from the “Groupe d’Etudes de la Matière Condensée” (GEMaC) of the “Université de Versailles Saint-Quentin” during a visit.
Author information
Authors and Affiliations
Contributions
All authors equally contribute to the present work in the calculations and in the manuscript writing process.
Corresponding authors
Ethics declarations
Conflict of interest
All authors approve for submission and declare that they have no known competing financial interests as well as no conflict of personal relationships that could have influenced the obtained results. The authors declare that this original manuscript is not currently being considered for publication elsewhere.
Additional information
We dedicate the present work to the memory of our colleague Dr. Yogendra Singh who passed away prematurely these days.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Oke, T.D., Ogou, S.B., Hontinfinde, F. et al. Emergence of multi-stability and limit cycles in ferromagnetic spin-crossover solids under an oscillating magnetic-field: dynamic mean-field study. Eur. Phys. J. B 95, 96 (2022). https://doi.org/10.1140/epjb/s10051-022-00354-5
Received:
Accepted:
Published:
DOI: https://doi.org/10.1140/epjb/s10051-022-00354-5