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Enhanced NMR of \(^{51}\hbox {V}\)

  • Regular Article - Solid State and Materials
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Abstract

The enhanced \(^{51}\hbox {V}\) NMR in \(\hbox {Al}_{2} \hbox {O}_{{3}}\) and [C(\(\hbox {NH}_{2})_{3}\)]Al(\(\hbox {SO}_{4})_{2} {\cdot }6\hbox {H}_{2}\)O have been studied. Both systems are Van Vleck paramagnets. Analysis of enhanced \(^{51}\hbox {V}\) NMR and \(\hbox {V}^{{3+}}\) ESR data allowed us to estimate vanadium nuclear quadrupole frequencies and hyperfine interaction constant B for \(^{51} \hbox {V}^{{3+}}\) ions in corundum for the first time.

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Data Availability Statement

This manuscript has no associated data or the data will not be deposited. [Authors’ comment: The data that support the relevant results within this paper are available from the corresponding author on reasonable request.]

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Acknowledgements

This work was funded by the subsidy allocated to Kazan Federal University for the state assignment in the sphere of scientific activities (project number: 0671-2020-0051).

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Authors and Affiliations

  1. Tatarstan Academy of Sciences, Bauman str. 20, Kazan, 420111, Russia

    A. V. Egorov, E. I. Kondratyeva & M. S. Tagirov

  2. Kazan Federal University, Kremlevskaya str. 18, Kazan, 420008, Russia

    E. I. Kondratyeva & M. S. Tagirov

Authors
  1. A. V. Egorov
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  2. E. I. Kondratyeva
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  3. M. S. Tagirov
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Contributions

The article preparation took very long time starting from the \(^{51}\hbox {V}\) NMR experiments in GASH (1984). It has been followed by the first analysis of experimental data, initiation of the common analysis of \(^{51}\hbox {V}\) NMR in corundum and GASH, and the final outline of enhanced NMR in the ions of the iron transition group. The authors contributed equally into these items.

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Correspondence to E. I. Kondratyeva.

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Egorov, A.V., Kondratyeva, E.I. & Tagirov, M.S. Enhanced NMR of \(^{51}\hbox {V}\). Eur. Phys. J. B 94, 184 (2021). https://doi.org/10.1140/epjb/s10051-021-00197-6

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  • DOI: https://doi.org/10.1140/epjb/s10051-021-00197-6

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