Abstract
We consider the influence of internal fluctuations on the behavior of a bistable thermochemical system with a low temperature stable focus surrounded by a stable limit cycle arising from the subcritical Hopf bifurcation. We use a master equation approach to study the transitions between basins of these attractors. Distribution functions of first passage times from the limit cycle to the focus are obtained for systems with various numbers of molecules and reaction heats. We consider in detail the specific, multi-peak form of the distributions caused by eccentric location of the limit cycles with respect to the focus.
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Kolbus, A., Nowakowski, B. & Kawczyński, A. Distributions of first passage times in a bistable thermochemical system with a low temperature stationary state. Eur. Phys. J. B 86, 262 (2013). https://doi.org/10.1140/epjb/e2013-31146-9
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DOI: https://doi.org/10.1140/epjb/e2013-31146-9