Abstract
The paper is a mini review on the authors own work related to laser induced processes at metal nanoparticle/oxidic support systems. A number of aspects will be addressed ranging from the nano particle size dependence on the efficiency of the photochemical process, the influence of low coordination sites of the nano particles and dynamical processes such as energy transfer between adsorbates, light induced particle changes or spill over processes. The paper reviews nano and femtosecond laser experiments as well as quantum state resolved experiments. Results will be compared to typical findings from simple oxidic supports and metal single crystals. This review may be of interest for future photocatalyst development for applications such as solar fuel synthesis and related problems.
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References
K. Al-Shamery, Appl. Phys. A 63, 509 (1996)
K. Al-Shamery, H.-J. Freund, Current Opinion in Solid State & Materials Science 1, 622 (1996)
P.V. Kamat, J. Phys. Chem. C 111, 2834 (2007)
F. Pan, J. Zhang, W. Zhang, T. Wang, C. Cai, Appl. Phys. Lett. 90, 122114 (2007)
C. Campbell, Surf. Sci. Rep. 27, 1 (1997)
H.-J. Freund, Angew. Chem. Int. Ed. Engl. 36, 453 (1997)
C. Henry, Surf. Sci. Rep. 31, 235 (1998)
H.-J. Freund, M. Bäumer, J. Libuda, H. Kuhlenbeck, T. Risse et al., Cryst. Res. Technol. 33, 977 (1998)
M. Bäumer, H.-J. Freund, Prog. Surf. Sci. 61, 127 (1999)
C.R. Henry, Prog. Surf. Sci. 80, 92 (2005)
D. Fenske, W.-L. Yim, S. Neuendorf, D. Hoogestraat, D. Greshnykh et al., Chem. Phys. Chem. 8, 654 (2007)
S. Glass, H. Nienhaus, Phys. Rev. Lett. 93, 168302 (2004)
H. Borchert, D. Fenske, J. Kolny-Olesiak, J. Parisi, K. Al-Shamery et al., Angew. Chem. Int. Ed. 46, 2923 (2007)
D. Fenske, P. Sonström, J. Stöver, X. Wang, H. Borchert et al., Chem. Cat. Chem. 2, 198 (2010)
D.J. Ehrlich, J.Y. Taso, Laser microfabrication: thin film processes and lithography (Academic Press, San Diego, 1989)
U. Okoroanyanwu, P. Kunze, K. Al-Shamery, J. Romero, J. Bernard, SPIE 4691, 746 (2002)
K.J. Al-Shamery, Phys.: Condens. Matter 18, 1581 (2006)
K. Watanabe, D. Menzel, N. Nilius, H. Freund, Chem. Rev. 106, 4301 (2006)
H.-L. Dai, W. Ho, Laser Spectroscopy and Photochemistry on Metal Surfaces (World Scientific Hongkong, 1993)
R.R. Cavanagh, D.S. King, J.C. Stephenson, J. Phys. Chem. 97, 786 (1993)
W. Ho, J. Phys. Chem. 100, 13050 (1996)
X.L. Zhou, X.Y. Zhu, J.M. White, Surf. Sci. Rep. 13, 73 (1991)
F. Zimmermann, W. Ho, Surf. Sci. Rep. 22, 127 (1995)
T. Klüner, H.-J. Freund, V. Staemmler, R. Kosloff, Phys. Rev. Lett. 80, 5208 (1998)
S.J. Clemett, A.W. Parker, K.v. Puttkamer, A. Takami, C.J.S.M. Simpson, J. Electron Spectrosc. Rel. Phenom. 54/55, 211 (1990)
S. Borowski, T. Klüner, H.-J. Freund, I. Klinkmann, K. Al-Shamery et al., Appl. Phys. A: Mat. Sci. Proc. 78, 223 (2004)
M. Menges, B. Baumeister, K. Al-Shamery, H.-J. Freund, C. Fischer et al., Surf. Sci. 316, 103 (1994)
M. Wilde, K. Fukutani, Y. Murata, M. Kampling, K. Al-Shamery et al., Surf. Sci. 427, 27 (1999)
H. Zacharias, G. Eichhorn, R. Schliesing, K. Al-Shamery, Appl. Phys. B 68, 605 (1999)
I. Beauport, K. Al-Shamery, H.-J. Freund, Chem. Phys. Lett. 256, 641 (1996)
R.N. Zare, Science 279, 1875 (1998)
G. Eichhorn, M. Richter, K. Al-Shamery, H. Zacharias, Chem. Phys. Lett. 289, 367 (1998)
T. Mull, M. Menges, B. Baumeister, B. Adam, K. Al-Shamery et al., Communications 258 (1992)
M. Menges, B. Baumeister, K. Al-Shamery, H.-J. Freund, C. Fischer et al., J. Chem. Phys. 101, 3318 (1994)
G. Eichhorn, M. Richter, K. Al-Shamery, H. Zacharias, Surf. Sci. 368, 67 (1996)
G. Eichhorn, M. Richter, K. Al-Shamery, H. Zacharias, Proceedings of the SPIES OE/LASER 98 conference, Laser Techniques for Surface Science III 3272, 187 (1998)
G. Eichhorn, M. Richter, K. Al-Shamery, H. Zacharias, J. Chem. Phys. 111, 386 (1999)
K. Al-Shamery, I. Beauport, H.-J. Freund, H. Zacharias, Chem. Phys. Lett. 222, 107 (1994)
I. Beauport, K. Al-Shamery, Proceedings of the SPIES OE/LASER 95 conference, Laser Techniques for Surface Science II 2547, 176 (1995)
I. Beauport, K. Al-Shamery, H.-J. Freund, Surf. Sci. 363, 252 (1996)
K. Al-Shamery, M. Menges, I. Beauport, B. Baumeister, T. Klüner et al., Proceedings of the SPIES OE/LASER 94 conference, Laser Techniques for Surface Science III 2125, 182 (1994)
S. Thiel, T. Klüner, M. Wilde, K. Al-Shamery, H.-J. Freund, Chem. Phys. 228, 185 (1998)
M. Wilde, K. Al-Shamery, H.-J. Freund, Proceedings of the SPIES OE/LASER 98 conference, Laser Techniques for Surface Science III 3272, 152 (1998)
M. Wilde, O. Seiferth, K. Al-Shamery, H.-J. Freund, J. Chem. Phys. 111, 1158 (1999)
M. Wilde, I. Beauport, K. Al-Shamery, H.-J. Freund, Surf. Sci. 390, 186 (1997)
B. Gehl, U. Leist, V. Aleksandrovic, P. Nickut, V. Zielasek et al., Rev. Sci. Instrum. 77, 083902–1 (2006)
M. Kampling, K. Al-Shamery, H.-J. Freund, M. Wilde, K. Fukutani et al., Phys. Chem. Chem. Phys. 4, 2629 (2002)
A. Wille, R. Buchwald, K. Al-Shamery, Appl. Phys. A 78, 205 (2004)
A. Sandell, J. Libuda, P.A. Brühwiler, S. Andersson, M. Bäumer et al., Phys. Rev. B 55, 7233 (1997)
A. Wille, P. Nickut, K. Al-Shamery, J. Mol. Struct. 695, 345 (2004)
A. Wille, S. Haubitz, K. Al-Shamery, Chem. Phys. Lett. 367, 609 (2003)
A. Wille, K. Al-Shamery, Surf. Sci. 528, 230 (2003)
A. Al-Shemmary, R. Buchwald, K. Al-Shamery, J. Phys.: Condens. Matter 22, 084011 (2010)
K. Watanabe, Y. Matsumoto, M. Kampling, K. Al-Shamery, H.-J. Freund, Angew. Chem. Int. Ed. 38, 2192 (1999)
T. Matsumoto, P. Nickut, T. Sawada, H. Tsunoyama, K. Watanabe et al., Surf. Sci. 601, 5226 (2007)
D. Cappus, C. Xu, D. Ehrlich, B. Dillmann, C.A. Ventrice Jr. et al., Chem. Phys. 177, 533 (1993)
D. Cappus, M. Haßel, E. Neuhaus, M. Heber, F. Rohr et al., Surf. Sci. 337, 268 (1995)
M. Schiek, K. Al-Shamery, M. Kunat, F. Traeger, C. Wöll, Phys. Chem. Chem. Phys. 8, 1505 (2006)
Y.D. Kim, R.M. Lynden-Bell, A. Alavi, J. Stulz, D.W. Goodman, Chem. Phys. Lett. 352, 318 (2002)
R. Schaub, P. Thostrup, N. Lopez, E. L’gsgaard, I. Stensgaard et al., Phys. Rev. Lett. 87, 266104–1 (2001)
U. Leist, W. Ranke, K. Al-Shamery, Phys. Chem. Chem. Phys. 5, 2435 (2003)
P.A. Thiel, T.E. Madey, Surf. Sci. Rep. 7, 211 (1987)
M. Neises, M. Roeb, M. Schmücker, C. Sattler, R. Pitz-Paal, Int. J. Energy Res. (2009), DOI:1002/er. 1565
D. Hoogestraat, K. Al-Shamery, J. Phys.: Condens. Matter 22, 084015 (2010)
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Al-Shamery, K., Al-Shemmary, A., Buchwald, R. et al. Elementary processes at nanoparticulate photocatalysts. Eur. Phys. J. B 75, 107–114 (2010). https://doi.org/10.1140/epjb/e2010-00114-6
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DOI: https://doi.org/10.1140/epjb/e2010-00114-6