Abstract
Magnetic circular dichroism magnetization measurements on a monolayer of single molecule magnets have been performed and the results are presented. At the measurement temperature (2 K) the hysteresis cycle shows no opening, contrary to what is seen in the bulk with SQUID magnetometry. This result could surprisingly imply that XMCD is unsuited for such measurements given the fact that it excites the core electrons at the origin of the magnetism. This result could also mean that the blocking temperature is greatly decreased or that these molecules loose their hallmark when deposited as adsorbed films, precluding therefore their much sought-after use in magnetic memories.
Similar content being viewed by others
References
“Single-Molecule Magnet and Related Phenomena”, Structure and Bonding, edited by R.E.P. Winpenny (Springer-Verlag, 2006)
O. Roubeau, R. Clérac, Eur. J. Inorg. Chem. 4325 (2008)
G. Aromí, S.M.J. Aubin, M.A. Bolcar, G. Christou, H.J. Eppley, K. Folting, D.N. Hendrickson, J.C. Huffman, R.C. Squire, H.-L. Tsai, S. Wang, M.W. Wemple, Polyhedron 17, 3005 (1998)
E.K. Brechin, Chem. Commun. 5141 (2005)
C.J. Milios, S. Piligkos, E.K. Brechin, Dalton Trans. 1809 (2008)
L. Bogani, W. Wernsdorfer, Nat. Mater. 7, 179 (2008)
J. Gómez-Segura, J. Veciana, D. Ruiz-Molina, Chem. Commun. 3699 (2007)
J. Gómez-Segura, I. Diez-Pérez, N. Ishikawa, M. Nakano, J. Veciana, D. Ruiz-Molina, Chem. Commun. 2866 (2006)
Magnetism and synchrotron radiation, edited by E. Beaurepaire, F. Scheurer, G. Krill, J.-P. Kappler (Springer, Berlin, 2001)
Z. Salman, K.H. Chow, R.I. Miller, A. Morello, T.J. Parolin, M.D. Hossain, T.A. Keeler, C.D.P. Levy, W.A. MacFarlane, G.D. Morris, H. Saadaoui, D. Wang, R. Sessoli, G.G. Condorelli, R.F. Kiefl, Nano Lett. 7, 1551 (2007)
E. Terazzi, C. Bourgogne, R. Welter, J.-L. Gallani, D. Guillon, G. Rogez, B. Donnio, Angew. Chem. Int. Ed. 47, 490 (2008)
B. Donnio, S. Buathong, I. Bury, D. Guillon, Chem. Soc. Rev. 36, 1495 (2007)
D. Gatteschi, R. Sessoli, Angew. Chem. Int. Ed. 42, 268 (2003)
K. Awaga, Y. Suzuki, H. Hachisuka, K. Takeda, J. Mater. Chem. 16, 2516 (2006)
R. Lucht, Ch. Bahr, Phys. Rev. Lett. 85, 4080 (2000)
L. Xu, M. Salmeron, S. Bardon, Phys. Rev. Lett. 84, 1519 (2000)
M. Mannini, D. Gatteschi, R. Sessoli, L. Zobbi, A. Cornia, C. Cartier dit Moulin, P. Sainctavit, J.-P. Kappler, BESSY Highlights 14 (2005), also available from http://www.bessy.de/publicRelations/publications/files/Highlights2005.pdf
U. del Pennino, V. De Renzi, R. Biagi, V. Corradini, L. Zobbi, A. Cornia, D. Gatteschi, F. Bondino, E. Magnano, M. Zangrando, M. Zacchigna, A. Lichtenstein, D.W. Boukhvalov, Surf. Sci. 600, 4185 (2006)
M. Fonin, S. Voss, M. Burger, Y.S. Dedkov, U. Groth, U. Rüdiger, BESSY Highlights 10 (2007)
XAS: X-ray absorption spectroscopy, XES: X-ray emission spectroscopy, RPES: resonant photoelectron spectroscopy
S. Voss, M. Fonin, U. Rudiger, M. Burgert, U. Groth, Y.S. Dedkov, Phys. Rev. B 75, 045102 (2007)
G.G. Condorelli, A. Motta, M. Favazza, P. Nativo, I.L. Fragal`a, D. Gatteschi, Chem. Eur. J. 12, 3558 (2006)
S. Voss, M. Burgert, M. Fonin, U. Groth, U. Rudiger, Dalton Trans., 499 (2008)
S. Voss, S. Herr, M. Fonin, U. Rudiger, M. Burgert, U. Groth, Appl. Phys. Lett. 103, 07B901 (2008)
M. Mannini, P. Sainctavit, R. Sessoli, C. Cartier dit Moulin, F. Pineider, M.-A. Arrio, A. Cornia, D. Gatteschi, Chem. Eur. J. 14, 7530 (2008)
M. Mannini, F. Pineider, P. Sainctavit, L. Joly, A. Fraile-Rodríguez, M.-A. Arrio, C. Cartier dit Moulin, W. Wernsdorfer, A. Cornia, D. Gatteschi, R. Sessoli, Adv. Mater. 20, 1 (2008)
I. Letard, P. Sainctavit, C. Cartier dit Moulin, J.-P. Kappler, P. Ghigna, D. Gatteschi, B. Doddi, J. Appl. Phys. 101, 113920 (2007)
R. Moroni, C. Cartier dit Moulin, G. Champion, M.A. Arrio, P. Sainctavit, M. Verdaguer, D. Gatteschi, Phys. Rev. B 68, 064407 (2003)
P. Ghigna, A. Campana, A. Lascialfari, A. Caneschi, D. Gatteschi, A. Tagliaferri, F. Borgatti, Phys. Rev. B 64, 132413 (2001)
Plane grating monochromator was set with a grating of 1200 l/mm, 5 µm-wide slits and a c ff of 15, c ff = c fixed focus = cos β/ cos α is a constant with α the input angle and β the output angle
The uncertainty on the sample temperature is about 5%. The calibration of the temperature has been performed with a calibrated thermometer in place of the sample; the lowest temperature obtained with the current setup is T = (1.3 ± 0.02) K on the heat exchanger and a corresponding temperature (2.0 ± 0.1) K at the sample position. This was confirmed by the sub-Kelvin experiments, see details in reference [27]
The spin was determined from magnetization measurements as a function of temperature under a very small oscillating magnetic field (0.35 mT, oscillating at various frequencies between 1 and 1000 Hz). Above a certain temperature (typically 8 K), a plateau is reached, its value gives that of the spin of the ground state. In the present case, the value of χac T at the plateau is ca. 41 emu Kmol−1, which corresponds to S = 9 and g = 1.91 A S = 9 ground state for Mn12 type complexes is not the most commonly observed, yet there are several examples of such complexes: with propionate, S.M.J. Aubin, Z. Sun, H.J. Eppley, E.M. Rumberger, I.A. Guzei, K. Folting, P.K. Gantzel, A.L. Rheingold, G. Christou, D.N. Hendrickson, Inorg. Chem. 40, 2127 (2001), benzoate, K. Takeda, K. Awaga, T. Inabe, Phys. Rev. B 57, R11062 (1998), metachlorobenzoate, J. An, Z.-D. Chen, J. Bian, J.-T. Chen, S.-X. Wang, S. Gao, G.-X. Xu, Inorg. Chim. Acta 299, 28 (2000), ligands for instance
T. Lis, Acta Cryst. B 36, 2042 (1980)
S.M.J. Aubin, Z. Sun, H.J. Eppley, E.M. Rumberger, I.A. Guzei, K. Folting, P.K. Gantzel, A.L. Rheingold, G. Christou, D.N. Hendrickson, Inorg. Chem. 40, 2127 (2001)
A. Caneschi, D. Gatteschi, R. Sessoli, J. Am. Chem. Soc. 113, 5873 (1991)
D. Ruiz-Molina, P. Gerbier, E. Rumberger, D.B. Amabilino, I.A. Guzei, K. Folting, J.C. Huffman, A. Rheingold, G. Christou, J. Veciana, D.N. Hendrickson, J. Mater. Chem. 12, 1152 (2002)
K. Takeda, K. Awaga, Phys. Rev. B 56, 14560 (1997)
M. Mannini, F. Pineider, P. Sainctavit, C. Danieli, E. Otero, C. Sciancalepore, A. M. Talarico, M. A. Arrio, A. Cornia, D. Gatteschi, R. Sessoli, Nature Mater. 8, 194 (2009)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Grumbach, N., Barla, A., Joly, L. et al. Loss of single-molecule-magnet behavior of a Mn12-based compound assembled in a monolayer. Eur. Phys. J. B 73, 103–108 (2010). https://doi.org/10.1140/epjb/e2009-00430-x
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1140/epjb/e2009-00430-x