Advertisement

The European Physical Journal Special Topics

, Volume 224, Issue 9, pp 1977–1983 | Cite as

In situ characterization of (poly)molybdate and (poly)tungstate ions sorbed onto iron (hydr)oxides by ATR-FTIR spectroscopy

  • A. Davantès
  • G. LefèvreEmail author
Regular Article
Part of the following topical collections:
  1. Advances in Design and Modeling of Porous Materials

Abstract

The sorption of (poly)molybdate and (poly)tungstate ions onto four iron (hydr)oxides, hematite (α-Fe2O3), goethite (α-FeOOH), akaganeite (β-FeOOH) and lepidocrocite (γ-FeOOH), was followed by in situ attenuated total reflection infrared spectroscopy. The different behaviors of the ionic species and the surface reactivity of these various solids have been investigated and different inner-sphere complexes have been found. On lepidocrocite and goethite a monodentate structure is preferred, while a polymerization of molybdate and tungstate species has been observed onto hematite surface. Both ions have a different behavior on akaganeite: molybdate ions polymerize while tungstate species seems to have the same monodentate structure than those found on goethite.

Keywords

Iron Oxide Hematite Molybdate Goethite European Physical Journal Special Topic 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    A. Davantès, G. Lefèvre, J. Phys. Chem. A 117, 12922 (2013)CrossRefGoogle Scholar
  2. 2.
    G. Lefèvre, Adv. Colloid Interfac. 107, 109 (2004)CrossRefGoogle Scholar
  3. 3.
    J.J. Cruywagen, Adv. Inorg. Chem. 49, 127 (2000)CrossRefGoogle Scholar
  4. 4.
    J.J. Cruywagen, A.G. Draaijer, J.B.B. Heyns, E.A. Rohwer, Inorg. Chim. Acta 331, 322 (2002)CrossRefGoogle Scholar
  5. 5.
    J.J. Cruywagen, I.F.J. van der Merwe, J. Chem. Soc. Dalton, 1701 (1987)Google Scholar
  6. 6.
    R.P.J. Rietra, T. Hiemstra, W.H. van Riemsdijk, Geoch. Cosmoch. Acta 63, 3009 (1999)ADSCrossRefGoogle Scholar
  7. 7.
    P.C. Zhang, D.L. Sparks, Soil Sci. Soc. Am. J. 53, 1028 (1989)CrossRefGoogle Scholar
  8. 8.
    S. Goldberg, S. Chunming, H.S. Forster, in Adsorption of Metals by Geomedia, edited by E.A. Jenne (Academic Press, San Diego, 1998), p. 401Google Scholar
  9. 9.
    S. Goldberg, H.S. Forster, C.L. Godfrey, Soil Sci. Soc. Am. J. 60, 425 (1996)CrossRefGoogle Scholar
  10. 10.
    N. Xu, C. Christodoulatos, W. Braida, Chemosphere 64, 1325 (2006)CrossRefGoogle Scholar
  11. 11.
    Y. Arai, Environ. Sci. Technol. 44, 8491 (2010)ADSCrossRefGoogle Scholar
  12. 12.
    T. Kashiwabara, Y. Takahashi, M. Tanimizu, A. Usui, Geochim. Cosmochim. Ac. 75, 5762 (2011)ADSCrossRefGoogle Scholar
  13. 13.
    T. Kashiwabara, Y. Takahashi, M.A. Marcus, T. Uruga, H. Tanida, Y. Terada, A. Usui, Geochim. Cosmochim. Ac. 106, 364 (2013)ADSCrossRefGoogle Scholar
  14. 14.
    U. Schwertmann, R.M. Cornell, Iron Oxides in the Laboratory: Preparation and Characterization (VCH, 1991)Google Scholar
  15. 15.
    K.E. Cole, Y. Paik, R.J. Reeder, M. Schoonen, C.P. Grey, J. Phys. Chem. B 108, 6938 (2004)CrossRefGoogle Scholar
  16. 16.
    K. Müller, G. Lefeévre, Langmuir 27, 6830 (2011)CrossRefGoogle Scholar
  17. 17.
    G. Lefèvre, J. Kneppers, M. Fédoroff, J. Colloid Interf. Sci. 327, 15 (2008)CrossRefGoogle Scholar
  18. 18.
    S.J. Hug, J. Colloid Interf. Sci. 188, 415 (1997)CrossRefGoogle Scholar
  19. 19.
    G. Lefèvre, M. Fédoroff, Phys. Chem. Earth 31, 499 (2006)CrossRefGoogle Scholar
  20. 20.
    R. Thouvenot, M. Fournier, R. Franck, C. Rocchiccioli-Deltcheff, Inorg. Chem. 23, 598 (1984)CrossRefGoogle Scholar
  21. 21.
    B. Courcot, A.J. Bridgeman, J. Phys. Chem. A 113, 10540 (2009)CrossRefGoogle Scholar
  22. 22.
    K. Otte, W.W. Schmahl, R. Pentcheva, J. Phys. Chem. C 117, 15571 (2013)CrossRefGoogle Scholar
  23. 23.
    M. Isaac, T. Pradip, V.U. Nayar, J. Solid State Chem. 112, 132 (1994)ADSCrossRefGoogle Scholar
  24. 24.
    B.L. George, G. Aruldhas, I.L. Botto, J. Mater. Sci. Lett. 11, 1421 (1992)CrossRefGoogle Scholar

Copyright information

© EDP Sciences and Springer 2015

Authors and Affiliations

  1. 1.CNRS-ENSCP, IRCP – UMR8247Paris Cedex 05France

Personalised recommendations