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The European Physical Journal Special Topics

, Volume 224, Issue 9, pp 1831–1841 | Cite as

Ni-exchanged AlSBA-15 mesoporous materials as outstanding catalysts for ethylene oligomerization

  • R.D. Andrei
  • M. Mureseanu
  • M.I. Popa
  • C. Cammarano
  • F. Fajula
  • V. HuleaEmail author
Regular Article
Part of the following topical collections:
  1. Advances in Design and Modeling of Porous Materials

Abstract

Ni-exchanged mesoporous materials with SBA-15 topology were prepared by post-synthesis alumination of SBA-15 silica with sodium aluminate at room temperature, followed by ion exchange with nickel. Exploration of various parameters resulted in a simple preparation method for catalysts with perfect pore system and aluminium tetrahedrally coordinated in the silica framework for Si/Al > 6. These properties were proved by using appropriate characterisation techniques, including powder X-ray diffraction, N2 sorption, TEM, and 27Al MAS NMR. Ni-AlSBA-15 exhibited outstanding catalytic properties in the oligomerization reaction of ethylene performed at 150 C and 3.5 MPa. Activity up to 175 g of oligomers per gram of catalyst per hour was the highest reported to date with Ni-based solid catalysts.

Keywords

European Physical Journal Special Topic Sodium Aluminate Ethylene Oligomerization Mesoporous Catalyst Nickel Site 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© EDP Sciences and Springer 2015

Authors and Affiliations

  • R.D. Andrei
    • 1
    • 2
  • M. Mureseanu
    • 3
  • M.I. Popa
    • 2
  • C. Cammarano
    • 1
  • F. Fajula
    • 1
  • V. Hulea
    • 1
    Email author
  1. 1.Institut Charles Gerhardt Montpellier, UMR 5253, CNRS-UM2-ENSCM-UM1, Matériaux Avancés pour la Catalyse et la SantéMontpellier Cedex 5France
  2. 2.Faculty of Chemical Engineering and Environment Protection, Technical University of IasiIasiRomania
  3. 3.Faculty of Chemistry, University of CraiovaCraiovaRomania

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