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The European Physical Journal Special Topics

, Volume 224, Issue 9, pp 1769–1773 | Cite as

14 N NMR of tetrapropylammonium based crystals

  • E. Dib
  • T. Mineva
  • P. Gaveau
  • B. Alonso
Regular Article
Part of the following topical collections:
  1. Advances in Design and Modeling of Porous Materials

Abstract

We have investigated using 14N NMR different types of materials containing tetrapropylammonium cations. We consider the tetrapropylammonium bromide crystal as well as two different microporous materials silicalite-1 and AlPO-5, with MFI and AFI topology respectively, where the tetrapropylammonium cation plays the role of structure directing agent. 14N NMR quadrupolar coupling parameters were determined experimentally for all the crystals. In addition calculations based on Density Functional Theory with empirical dispersion (DFT-D) were performed on the MFI type zeolite. The sensitivity of the 14N quadrupolar coupling parameters to the spatial distribution of the anions in the zeolite’s framework is emphasized.

Keywords

Zeolite European Physical Journal Special Topic Structure Directing Agent Microporous Material Tetrapropylammonium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© EDP Sciences and Springer 2015

Authors and Affiliations

  • E. Dib
    • 1
  • T. Mineva
    • 1
  • P. Gaveau
    • 1
  • B. Alonso
    • 1
  1. 1.ICGM-MACS, UMR 5253 CNRS-ENSCM-UM2-UM1, Institut Charles Gerhardt de MontpellierMontpellier Cedex 5France

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