Low temperature dielectric relaxation study of aqueous solutions of diethylsulfoxide

  • Liana Gabrielyan
  • Shiraz Markarian
  • Peter Lunkenheimer
  • Alois Loidl
Regular Article

Abstract

In the present work, dielectric spectra of mixtures of diethylsulfoxide (DESO) and water are presented, covering a concentration range of 0.2-0.3 molar fraction of DESO. The measurements were performed at frequencies between 1Hz and 10MHz and for temperatures between 150 and 300K. It is shown that DESO/water mixtures have strong glass-forming abilities. The permittivity spectra in these mixtures reveal a single relaxation process. It can be described by the Havriliak-Negami relaxation function and its relaxation times follow the Vogel-Fulcher-Tammann law, thus showing the typical signatures of glassy dynamics. The concentration dependence of the relaxation parameters, like fragility, broadening, and glass temperature, are discussed in detail.

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Copyright information

© Società Italiana di Fisica and Springer-Verlag Berlin Heidelberg 2014

Authors and Affiliations

  • Liana Gabrielyan
    • 1
  • Shiraz Markarian
    • 1
  • Peter Lunkenheimer
    • 2
  • Alois Loidl
    • 2
  1. 1.Department of Physical ChemistryYerevan State UniversityYerevanArmenia
  2. 2.Experimental Physics VUniversity of AugsburgAugsburgGermany

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