Low energy electron induced reactions in fluorinated acetamide – probing negative ions and neutral stable counterparts*

  • Janina Kopyra
  • Constanze König-Lehmann
  • Eugen Illenberger
  • Jonas Warneke
  • Petra Swiderek
Open Access
Regular Article
Part of the following topical collections:
  1. Topical Issue: Advances in Positron and Electron Scattering

Abstract

Electron impact to trifluoroacetamide (CF3CONH2, TFAA) in the energy range 0–12 eV leads to a variety of negative fragment ions which are formed via dissociative electron attachment (DEA). The underlying reactions range from single bond cleavages to remarkably complex reactions that lead to loss of the neutral units HF, H2O and HNCO as deduced from their directly observed ionic counterparts (M – H2O), (M – HF) and (M – HNCO). Also formed are the pseudo-halogen ions CN and OCN. All these reactions proceed dominantly via a resonance located near 1 eV, i.e., electrons at subexcitation energies trigger reactions involving multiple bond cleavages. The electron induced generation of the neutral molecules HF, H2O and HNCO in condensed TFAA films is probed by temperature controlled thermal desorption spectrometry (TDS) which can be viewed as a complementary techniques to gas-phase experiments in DEA to directly probe the neutral counterparts.

Graphical abstract

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Copyright information

© The Author(s) 2016

This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Authors and Affiliations

  • Janina Kopyra
    • 1
  • Constanze König-Lehmann
    • 2
  • Eugen Illenberger
    • 2
  • Jonas Warneke
    • 3
  • Petra Swiderek
    • 3
  1. 1.Siedlce University, Faculty of SciencesSiedlcePoland
  2. 2.Institut für Chemie und Biochemie - Physikalische und Theoretische Chemie, Freie Universität BerlinBerlinGermany
  3. 3.Institut für Angewandte und Physikalische Chemie, Universität BremenBremenGermany

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