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The European Physical Journal D

, Volume 61, Issue 1, pp 33–38 | Cite as

Chemiluminescence studies of the reactions of Ca*(3P J ) atoms with C6H5X (X = F, Cl, Br, I) and C6F5I molecules

  • B. PranszkeEmail author
  • S. Werbowy
  • A. Kowalski
Article
  • 47 Downloads

Abstract.

Chemiluminescent reactions of Ca*(3P J ) atoms with C6H5X (X = F, Cl, Br, I) and C6F5I molecules were studied in a beam-gas arrangement. The A \(^2{\rm \Pi}\)–X 2 \({\rm\Sigma}^+\) and B 2 \({\rm\Sigma}^+\)–X 2 \({\rm\Sigma}^+\) transitions in calcium monohalide products have been observed for all targets except C6H5F. The total collision cross sections for the systems studied are about 10-18 m2, in agreement with the harpoon model, while the chemiluminescence photon yields are below 1%.

Keywords

Reactive Cross Section Rotational State CaBr Alkaline Earth Atom C6F5I Molecule 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© EDP Sciences, SIF, Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  1. 1.Institute of Experimental Physics, University of GdańskGdańskPoland

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