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Determination of transition dipole moments from time-resolved photoelectron spectroscopy

  • T. Lohmüller
  • M. Erdmann
  • O. Rubner
  • V. Engel
Original Paper

Abstract.

We show how to extract the energy- and coordinate dependence of dipole-moments for a neutral-to-ionic molecular transition from time-resolved photoelectron spectra. The procedure needs the potential surfaces of the neutral and the cationic state which are involved in the ionization process as an input. Given these potentials and the laser parameters it is possible to determine the functional form of the transition dipole moment from the measured time- and energy-resolved transient signals.

Keywords

Spectroscopy Dipole Moment Functional Form Potential Surface Transition Dipole 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin/Heidelberg 2003

Authors and Affiliations

  • T. Lohmüller
    • 1
  • M. Erdmann
    • 1
  • O. Rubner
    • 2
  • V. Engel
    • 1
  1. 1.Institut für Physikalische ChemieUniversität WürzburgWürzburgGermany
  2. 2.Institut für NanotechnologieForschungszentrum Karlsruhe GmbHKarlsruheGermany

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