The European Physical Journal B

, Volume 84, Issue 3, pp 439–449 | Cite as

Size effect in spin-crossover systems investigated by FORC measurements, for surfacted [Fe(NH2-trz)3](Br)2·3H2O nanoparticles: reversible contributions and critical size

  • A. Rotaru
  • F. Varret
  • A. Gindulescu
  • J. Linares
  • A. Stancu
  • J. F. Létard
  • T. Forestier
  • C. Etrillard
Regular Article Mesoscopic and Nanoscale Systems

Abstract

We investigated the thermal transition of coated nano-particles of the title compound, on a set of samples of average diameter ⟨d⟩ ~ 30, 50, 70, 110 nm, with rather broad size distributions. As expected, the width of the major hysteresis loop was an increasing function of ⟨d⟩. We recorded first-order reversal curves (FORC), the initial parts of which displayed a finite slope, revealing the presence of reversible contributions expected from particles smaller than the critical size dC associated with the collapse of the hysteresis loop. Kinetic effects were also evidenced thanks to isothermal stages. Reversibility of the FORC curves at the vicinity of the reversal temperature was controlled. Thanks to the reversibility property we could determine the reversible contributions to the total response of all samples and derive the corresponding dC values. Consistent results were obtained by accounting for an anhysteretic contribution from the large particles, leading to an accurate determination dC ~ 45−50 nm, much better than the width of the size distributions.

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Copyright information

© EDP Sciences, SIF, Springer-Verlag Berlin Heidelberg 2011

Authors and Affiliations

  • A. Rotaru
    • 1
    • 2
    • 3
  • F. Varret
    • 1
  • A. Gindulescu
    • 1
    • 3
  • J. Linares
    • 1
  • A. Stancu
    • 2
  • J. F. Létard
    • 4
  • T. Forestier
    • 4
  • C. Etrillard
    • 4
  1. 1.Groupe d’Étude de la Matière Condensée (GEMaC), CNRS-UMR 8635Université de Versailles Saint-QuentinVersailles CedexFrance
  2. 2.Department of PhysicsAlexandru Ioan Cuza UniversityIasiRomania
  3. 3.Faculty of Electrical Engineering and Computer Science“Stefan cel Mare” UniversitySuceavaRomania
  4. 4.ICMCB, CNRS-UPR 9048Université de Bordeaux 1PessacFrance

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