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Extraction Properties of 4-[(Hexylsulfanyl)methyl]-3,5-dimethyl-1-phenyl-1H-pyrazole in the Palladium(II) Recovery from Nitric Acid Solutions

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Abstract

Palladium(II) extraction from nitric acid solutions with the complex-forming reagent 4-[(hexylsulfanyl)methyl]-3,5-dimethyl-1-phenyl-1H-pyrazole, was studied using chloroform as a diluent. The reagent extracts Pd(II) with high efficiency from 0.5–5 M HNO3 solutions. It has been established that palladium(II) is extracted from 2 M HNO3 solutions by a coordination mechanism with the formation of the extracted compound [Pd(NO3)2μ-L]n (n > 2). Palladium(II) is quantitatively re-extracted with a nitric acid solution of thiourea. The reagent is promising for concentrating Pd(II) from nitric acid solutions and its highly selective separating from Fe(III), lanthanides(III), Al(III), Cu(II), and Ni(II).

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ACKNOWLEDGMENTS

The authors express their gratitude to the Center for Collective Use “Chemistry” of the Ufa Institute of Chemistry of the Ufa Federal Research Center of the Russian Academy of Sciences and the Regional Center for Collective Use “Agidel” for the opportunity to carry out elemental analysis and to record IR and NMR spectra of compounds.

Funding

The work was carried out within the framework of the state task (topics nos. 123011300044-5 and 122031400274-4).

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Authors and Affiliations

  1. Ufa Institute of Chemistry, Ufa Federal Research Centre of Russian Academy of Sciences, 450054, Ufa, Russia

    G. R. Anpilogova, L. A. Baeva & R. M. Nugumanov

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  1. G. R. Anpilogova
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  2. L. A. Baeva
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  3. R. M. Nugumanov
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Correspondence to G. R. Anpilogova.

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Anpilogova, G.R., Baeva, L.A. & Nugumanov, R.M. Extraction Properties of 4-[(Hexylsulfanyl)methyl]-3,5-dimethyl-1-phenyl-1H-pyrazole in the Palladium(II) Recovery from Nitric Acid Solutions. Russ J Gen Chem 93, 1115–1121 (2023). https://doi.org/10.1134/S1070363223050110

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