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Ion-Functionalized Silver(I) Carboxylates: Synthesis and Application in Ru-Catalyzed Olefin Metathesis Reaction

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Abstract

The Grubbs–Hoveyda catalysts have a wide range of applications in catalyzed formation of the carbon-carbon double bonds. In this study, several imidazolium- functionalized or pyridinium-functionalized silver carboxylates have been prepared, and their reaction with Grubbs–Hoveyda 2nd generation (G–H 2nd) catalyst leads a new type of processes. Activity and selectivity of the catalysts have been preliminarily evaluated using cross olefin metathesis reactions.

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Funding

This work was supported by National Natural Science Foundation of China (grant no. 21673183), and Natural Science Foundation of Shaanxi Province (grant no. 2016JM2005).

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Authors and Affiliations

  1. College of Chemistry and Pharmacy, Northwest A&F University, 712100, Yangling, China

    Xiao-Lu Chen, Xiang-Yu Li, Shuai-Shuai Li, Xue Bai, Tao Li & Chong-Min Zhong

  2. College of Life Science, Northwest A&F University, 712100, Yangling, China

    Erukala Yadaiah Goud

  3. College of Natural Resources and Environment, Northwest A&F University, 712100, Yangling, China

    Ya-Jie Zuo

Authors
  1. Xiao-Lu Chen
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  2. Xiang-Yu Li
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  3. Shuai-Shuai Li
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  4. Xue Bai
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  5. Tao Li
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  6. Erukala Yadaiah Goud
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Correspondence to Chong-Min Zhong or Ya-Jie Zuo.

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Chen, XL., Li, XY., Li, SS. et al. Ion-Functionalized Silver(I) Carboxylates: Synthesis and Application in Ru-Catalyzed Olefin Metathesis Reaction. Russ J Gen Chem 90, 2163–2169 (2020). https://doi.org/10.1134/S1070363220110237

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