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Synthesis and properties of functionalized alkylalkoxysilanes

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Abstract

A method of chloroalkylalkoxysilanes synthesis scalable to pilot production has been proposed. Morpholinotrialkoxysilanes have been prepared and studied as vulcanizing agents for low-molecular silicone rubbers. The reaction of N-morpholinomethyltrialkoxysilanes with triethanolamine has afforded N-[(silatranyl)-methyl]morpholine; it has been studied by X-ray analysis.

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References

  1. Sheludyakov, V.D., Khatuntsev, G.D., and Mironov, V.F., Zh. Obshch. Khim., 1973, vol. 43, no. 12, p. 2697.

    CAS  Google Scholar 

  2. Shorr, L.M., J. Am. Chem. Soc., 1954, vol. 76, no. 5, p. 1390. doi 10.1021/ja01634a076.

    Article  CAS  Google Scholar 

  3. Khananashvili, L.M., Khimiya i tekhnologiya elementorganicheskikh monomerov i polimerov (Chemistry and Technology of Organoelement Monomers and Polymers), Moscow Khimiya, 1998.

    Google Scholar 

  4. Lukevits, E., Pestunovich, A.E., and Voronkov, M.G., Khim. Geterotsikl. Soedin., 1968, no. 5, p. 949.

    Google Scholar 

  5. Sheludyakov, V.D., Viktorov, N.A., Tkachev, A.S., and Mironov, V.F., Zh. Obshch. Khim., 1977, vol. 47, no. 1, p. 90.

    CAS  Google Scholar 

  6. Mironov, V.F., Sheludyakov, V.D., Viktorov, N.A., Ryasin, G.V., and Chizhikova, M.P., Authot’s Certificate 346306, 1972, Byull. Izobret., 1972, no. 23.

    Google Scholar 

  7. Voronkov, M.G. and D’yakov, V.M., Silatrany (Silatranes), Novosibirsk Nauka, 1978.

    Google Scholar 

  8. Sheludyakov, V.D., Kuz’mina, N.E., Abramkin, A.M., Korlyukov, A.A., Archipov, D.E., Loginov, S.V., Cheshkov, D.A., and Storozhenko, P.A., Russ. J. Gen. Chem., 2011, vol. 81, no. 12, p. 2459. doi 10.1134/S1070363211120073.

    Article  CAS  Google Scholar 

  9. Sheludyakov, V.D., Kuz’mina, N.E., Abramkin, A.M., Korlyukov, A.A., Archipov, D.E., Loginov, S.V., Cheshkov, D.A., and Storozhenko, P.A., Russ. J. Gen. Chem., 2011, vol. 81, no. 12, p. 2468. doi 10.1134/S1070363211120085.

    Article  CAS  Google Scholar 

  10. Allen, F.H., Kennard, O., and Watson, D.G., Chem. Soc., Perkin Trans. 2, 1987, p. 1. doi 10.1039/P298700FX001.

    Google Scholar 

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Correspondence to A. V. Lebedev.

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Original Russian Text © А.V. Lebedev, R.М. Minas’yan, А.М. Abramkin, V.D. Sheludyakov, N.Е. Kuzmina, А.B. Lebedeva, G.Е. Surikov, V.B. Rybakov, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 8, pp. 1321–1326.

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Lebedev, A.V., Minas’yan, R.M., Abramkin, A.M. et al. Synthesis and properties of functionalized alkylalkoxysilanes. Russ J Gen Chem 86, 1859–1863 (2016). https://doi.org/10.1134/S1070363216080144

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  • DOI: https://doi.org/10.1134/S1070363216080144

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