Abstract
A method of chloroalkylalkoxysilanes synthesis scalable to pilot production has been proposed. Morpholinotrialkoxysilanes have been prepared and studied as vulcanizing agents for low-molecular silicone rubbers. The reaction of N-morpholinomethyltrialkoxysilanes with triethanolamine has afforded N-[(silatranyl)-methyl]morpholine; it has been studied by X-ray analysis.
Similar content being viewed by others
References
Sheludyakov, V.D., Khatuntsev, G.D., and Mironov, V.F., Zh. Obshch. Khim., 1973, vol. 43, no. 12, p. 2697.
Shorr, L.M., J. Am. Chem. Soc., 1954, vol. 76, no. 5, p. 1390. doi 10.1021/ja01634a076.
Khananashvili, L.M., Khimiya i tekhnologiya elementorganicheskikh monomerov i polimerov (Chemistry and Technology of Organoelement Monomers and Polymers), Moscow Khimiya, 1998.
Lukevits, E., Pestunovich, A.E., and Voronkov, M.G., Khim. Geterotsikl. Soedin., 1968, no. 5, p. 949.
Sheludyakov, V.D., Viktorov, N.A., Tkachev, A.S., and Mironov, V.F., Zh. Obshch. Khim., 1977, vol. 47, no. 1, p. 90.
Mironov, V.F., Sheludyakov, V.D., Viktorov, N.A., Ryasin, G.V., and Chizhikova, M.P., Authot’s Certificate 346306, 1972, Byull. Izobret., 1972, no. 23.
Voronkov, M.G. and D’yakov, V.M., Silatrany (Silatranes), Novosibirsk Nauka, 1978.
Sheludyakov, V.D., Kuz’mina, N.E., Abramkin, A.M., Korlyukov, A.A., Archipov, D.E., Loginov, S.V., Cheshkov, D.A., and Storozhenko, P.A., Russ. J. Gen. Chem., 2011, vol. 81, no. 12, p. 2459. doi 10.1134/S1070363211120073.
Sheludyakov, V.D., Kuz’mina, N.E., Abramkin, A.M., Korlyukov, A.A., Archipov, D.E., Loginov, S.V., Cheshkov, D.A., and Storozhenko, P.A., Russ. J. Gen. Chem., 2011, vol. 81, no. 12, p. 2468. doi 10.1134/S1070363211120085.
Allen, F.H., Kennard, O., and Watson, D.G., Chem. Soc., Perkin Trans. 2, 1987, p. 1. doi 10.1039/P298700FX001.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © А.V. Lebedev, R.М. Minas’yan, А.М. Abramkin, V.D. Sheludyakov, N.Е. Kuzmina, А.B. Lebedeva, G.Е. Surikov, V.B. Rybakov, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 8, pp. 1321–1326.
Rights and permissions
About this article
Cite this article
Lebedev, A.V., Minas’yan, R.M., Abramkin, A.M. et al. Synthesis and properties of functionalized alkylalkoxysilanes. Russ J Gen Chem 86, 1859–1863 (2016). https://doi.org/10.1134/S1070363216080144
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363216080144