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Kinetics of oxidative ammonolysis of 4-bromo-o-xylene: I. Transformations of 4-bromo-o-xylene and 4-bromo-o-tolunitrile

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Abstract

Kinetic laws of 4-bromo-phthalonitrile synthesis by vapor-phase oxidative ammonolisis of 4-bromo-o-xylene in the range of 633–69 K were studied. It was shown that formation of 4-bromophthalonitrile proceeds successively through 4-bromo-o-tolunitrile. Conversion rates of 4-bromo-o-xylene and 4-bromo-o-toluinitrile were found to be described by half-order equations on the corresponding components and not to depend on the oxygen and ammonia concentrations.

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References

  1. Rizaev, R.G., Bagirzade, G.A., Sheinin, V.E., et. al., Abstracts of Papers, Nauchnaya konferentsiya posvyashchennaya 95-letnemu yubileyu akademika M.F. Nagieva (Scientific Conference Devoted to 95 Anniversary of Academician M.F. Nagiev), Baku: IKhP NANA, 2003, p. 14.

    Google Scholar 

  2. Mikhalenko, S.A., Derkacheva, V.M., and Lukyanets, E.A., Zh. Obshch. Khim., 1981, vol. 51, no. 7, p. 1650.

    CAS  Google Scholar 

  3. Rizaev, R.G., Sheinin, V.E., Magerramova, Z.Yu., et. al., Abstracts of Papers, Nauchno-tekhnicheskaya konferentsiya v oblasti neorganocheskoi i fizicheskoi khimii posvyashchennaya 60-letiyu instituta (Scientific Technical Conference on Inorganic and Physical Chemistry Devoted to 60 Anniversary of Institute), Baku: INFKh ANA, 1995, p.16.

    Google Scholar 

  4. Rizaev, R.G., Sheinin, V.E., Allakhkulu, A. Ogly, et. al., Kinetika i Kataliz, 1985, vol. 26, no. 2, p. 345.

    CAS  Google Scholar 

  5. Rizaev, R.G., Sheinin, V.E., Allakhkulu, A. Ogly, et. al., Kinetika i Kataliz, 1986, vol. 27, no. 2, p. 339.

    CAS  Google Scholar 

  6. Magerramova, Z.Yu., Doct. Sci. (Chem.) Dissertation, Baku, 1993.

  7. Shapovalov, A.A., Sembaev, D.Kh., and Suvorov, B.V., Author’s Certificate no. 1057491, 1982, Bull. Izobret., 1983, no. 44.

  8. Kiperman, S.L., Vvedenie v kinetiku eterogennykh kataliticheskikh reaktsii (Kinetics of Heterogeneous Catalytic Reactions), Moscow: Nauka, 1964.

    Google Scholar 

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Authors and Affiliations

  1. Nagiev Institute of Chemical Problems, Azerbaijan National Academy of Sciences, Pr. G. Dzhavida 29, Baku, AZ1143, Azerbaijan

    G. A. Bagirzade

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  1. G. A. Bagirzade
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Correspondence to G. A. Bagirzade.

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Original Russian Text © G.A. Bagirzade, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 8, pp. 1360–1364.

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Bagirzade, G.A. Kinetics of oxidative ammonolysis of 4-bromo-o-xylene: I. Transformations of 4-bromo-o-xylene and 4-bromo-o-tolunitrile. Russ J Gen Chem 80, 1672–1676 (2010). https://doi.org/10.1134/S1070363210080177

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  • DOI: https://doi.org/10.1134/S1070363210080177

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