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Thermooxidative decomposition of heterocyclic N-oxides

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Abstract

Thermooxidative decomposition of pyridine N-oxide, 4-(4-dimethylaminostyryl)pyridine N-oxide, 4-(4-methoxystyryl)pyridine N-oxide, quinoline N-oxide, 2-methylquinoline N-oxide, 4-chloroquinoline N-oxide, 2-styrylquinoline N-oxide, and 2-(4-dimethylaminostyryl)quinoline N-oxide was studied. The kinetic parameters of the thermooxidative processes were calculated according to three independent procedures. The relation between the nature of heterocyclic N-oxide and its stability to thermal oxidation was analyzed.

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Authors and Affiliations

  1. Institute of Solution Chemistry, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    Yu. A. Gubarev, N. Sh. Lebedeva & A. I. V’yugin

  2. Petrozavodsk State University, Petrozavodsk, Karelia, Russia

    V. P. Andreev & Ya. P. Nizhnik

Authors
  1. Yu. A. Gubarev
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  2. N. Sh. Lebedeva
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  3. V. P. Andreev
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  4. Ya. P. Nizhnik
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  5. A. I. V’yugin
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Original Russian Text © Yu.A. Gubarev, N.Sh. Lebedeva, V.P. Andreev, Ya.P. Nizhnik, A.I. V’yugin, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 6, pp. 1006–1013.

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Gubarev, Y.A., Lebedeva, N.S., Andreev, V.P. et al. Thermooxidative decomposition of heterocyclic N-oxides. Russ J Gen Chem 77, 1093–1099 (2007). https://doi.org/10.1134/S1070363207060254

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  • DOI: https://doi.org/10.1134/S1070363207060254

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