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Electrical conductivity of solutions of copper(II) nitrate crystalohydrate in dimethyl sulfoxide

  • Colloid Chemistry and Electrochemistry
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Abstract

Conductometry is used to investigate the electric conductivity of Cu(NO3)2 ⋅ 3Н2О solutions in dimethyl sulfoxide in the 0.01–2.82 M range of concentrations and at temperatures of 288–318 K. The limiting molar conductivity of the electrolyte and the mobility of Cu2+ and NO -3 ions, the effective coefficients of diffusion of copper(II) ions and nitrate ions, and the degree and constant of electrolytic dissociation are calculated for different temperatures from the experimental results. It is established that solutions containing 0.1–0.6 M copper nitrate trihydrate in DMSO having low viscosity and high electrical conductivity can be used in electrochemical deposition.

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References

  1. G. F. Volodin, L. N. Signal, and Yu. M. Tyurin, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 32 (11), 64 (1989).

    CAS  Google Scholar 

  2. L. I. Fedortsov, Yu. V. Duzhak, and O. G. Zarubitskii, in Proceedings of the Seminar on Modern High-Performance, Non-Toxic Electrolytes in Electroplating (Penza, 1985), p. 31.

    Google Scholar 

  3. D. N. Gritsan, G. V. Pentsova, A. P. Radchenkova, and A. A. Pravda, in Proceedings of the Conference on Theory and Practice of Metal Protection from Corrosion (Kuibyshev, 1985), p. 50.

    Google Scholar 

  4. A. M. Kirgintsev, L. P. Trushnikova, and V. G. Lavrent’eva, Solubility of Inorganic Substances in Water (Khimiya, Leningrad, 1995) [in Russian].

    Google Scholar 

  5. S. I. Troyanov, I. V. Morozov, K. O. Znamenkov, and Yu. M. Korenev, Russ. J. Inorg. Chem. 41, 1411 (1996).

    Google Scholar 

  6. N. T. Kudryavtseva and P. M. Vyacheslavova, Practical Guide on Applied Electrochemistry (Khimiya, Leningrad, 1980) [in Russian].

    Google Scholar 

  7. A. M. Sukhotin, Handbook on Electrochemistry (Khimiya, Leningrad, 1981) [in Russian].

    Google Scholar 

  8. A. Parker, Quart. Rev. (London) 16, 163 (1962).

    Article  CAS  Google Scholar 

  9. D. Martin and H. Hauthal, Dimethylsulfoxid (Academic, Berlin, 1971).

    Google Scholar 

  10. M. V. Ionin, L. G. Lazareva, and T. V. Sherstneva, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 33 (5), 17 (1990).

    CAS  Google Scholar 

  11. Yu. N. Kukushkin, Achievements of the Chemistry of Coordination Compounds (Naukova Dumka, Kiev, 1975) [in Russian].

    Google Scholar 

  12. B. G. Rao and U. J. Singh, J. Am. Chem. Soc. 112, 3803 (1990).

    Article  CAS  Google Scholar 

  13. V. I. Skomorokhov and A. F. Dregalin, Zh. Fiz. Khim. 66, 2947 (1992).

    CAS  Google Scholar 

  14. Sh. A. Markaryan, R. S. Arutyunyan, V. V. Grigoryan, and N. M. Beileryan, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 28 (9), 18 (1985).

    CAS  Google Scholar 

  15. J. M. Cowie and P. M. Toporowski, Can. J. Chem. 39, 2240 (1981).

    Article  Google Scholar 

  16. R. S. Vakhidov, Elektrokhimiya 30, 1165 (1994).

    CAS  Google Scholar 

  17. R. S. Vakhidov, A. K. Mamyrbekova, U. M. Dzhemilev, et al., in Proceedings of the 10th All-Russia Workshop on Improving of Electroplating Technology (Vyat. Gos. Tekh. Univ., Kirov, 1997), p. 112.

    Google Scholar 

  18. A. K. Mamyrbekova, Russ. J. Phys. Chem. A 87, 414 (2013).

    Article  CAS  Google Scholar 

  19. N. A. Izmailov, Electrochemistry of Solutions (Khimiya, Moscow, 1986), p. 153 [in Russian].

    Google Scholar 

  20. Yu. A. Karapetyan and V. N. Eichis, Physicochemical Properties of Nonaqueous Electrolyte Solutions (Khimiya, Moscow, 1989) [in Russian].

    Google Scholar 

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Authors and Affiliations

  1. Higher School of Chemical Engineering and Biotechnology, Auezov South Kazakhstan State University, Shymkent, 160012, Kazakhstan

    Aigul K. Mamyrbekova & A. D. Mamitova

  2. Faculty of Medicine, Ahmet Yesevi International University, Turkistan, Kazakhstan

    Aizhan K. Mamyrbekova

Authors
  1. Aigul K. Mamyrbekova
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  2. A. D. Mamitova
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  3. Aizhan K. Mamyrbekova
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Correspondence to Aigul K. Mamyrbekova or Aizhan K. Mamyrbekova.

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Original Russian Text © Aigul K. Mamyrbekova, A.D. Mamitova, Aizhan K. Mamyrbekova, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 6, pp. 934–938.

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Mamyrbekova, A.K., Mamitova, A.D. & Mamyrbekova, A.K. Electrical conductivity of solutions of copper(II) nitrate crystalohydrate in dimethyl sulfoxide. Russ. J. Phys. Chem. 90, 1265–1268 (2016). https://doi.org/10.1134/S003602441606011X

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  • DOI: https://doi.org/10.1134/S003602441606011X

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