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Effect of Hydrogenation of C60 Fullerenes on the Properties of Their Transformation Products at High Pressures and Temperatures

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Abstract

New superelastic superhard carbon materials are obtained from C60 fullerites hydrogenated in the solid state in a hydrogen atmosphere to a content of 0.4 wt % H (formula ~C60H3.5). Raman spectroscopy, light and electron microscopy, dynamic indentation, and tribological tests are used to study composite materials (CM) synthesized from mixtures of powders of Co and 10-wt % fullerites C60 or C60H3.5 under a pressure of 8 GPa at a temperature of 800°C. Hydrogenation of the initial fullerites increases the degree of amorphization of the structure of the high-pressure graphite-like phase, while its hardness increases by more than 2.5 times, up to ~52 GPa, and the elastic modulus during indentation increases by about 3 times, up to 333 GPa. The hydrogenation of C60 fullerites is a promising method for improving the tribotechnical characteristics of the superelastic hard phase formed during the thermobaric treatment of fullerites, as well as CMs reinforced with particles of such a phase: the CM friction coefficient decreases from 0.25 to 0.01 with a significant increase in wear resistance.

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Funding

The work was carried out within the framework of the State Task 075-00328-21-00.

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Authors and Affiliations

  1. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

    O. P. Chernogorova, E. I. Drozdova, I. N. Lukina & V. P. Sirotinkin

  2. Kotelnikov Institute of Radioengineering and Electronics, Russian Academy of Sciences, 141120, Fryazino, Moscow oblast, Russia

    A. A. Khomich

  3. Lomonosov Moscow State University, 119991, Moscow, Russia

    S. N. Klyamkin

  4. Vereshchagin Institute for High Pressure Physics, Russian Academy of Sciences, 142190, Troitsk, Moscow, Russia

    E. A. Ekimov

Authors
  1. O. P. Chernogorova
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  2. E. I. Drozdova
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  3. I. N. Lukina
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  4. V. P. Sirotinkin
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  5. A. A. Khomich
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  6. S. N. Klyamkin
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  7. E. A. Ekimov
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Corresponding authors

Correspondence to O. P. Chernogorova, E. I. Drozdova, I. N. Lukina, V. P. Sirotinkin, A. A. Khomich, S. N. Klyamkin or E. A. Ekimov.

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Translated by V. Selikhanovich

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Chernogorova, O.P., Drozdova, E.I., Lukina, I.N. et al. Effect of Hydrogenation of C60 Fullerenes on the Properties of Their Transformation Products at High Pressures and Temperatures. Nanotechnol Russia 17, 534–540 (2022). https://doi.org/10.1134/S2635167622040061

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  • DOI: https://doi.org/10.1134/S2635167622040061

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