Abstract
We synthesized ionic liquids with 2-(alkyldimethylamino)ethanol cation and inorganic anions and studied the electrical conductivity of their solutions in acetonitrile. The ion association constants (Ka), limiting molar electrical conductivities (λ0), and standard Gibbs association energies (ΔG°) in acetonitrile solutions at 25°С were calculated by the Lee–Wheaton equation.
REFERENCES
Welton, T., Chem. Rev., 1999, vol. 9, p. 2071.
Ohno, H., Electrochemical Aspects of Ionic Liquids, Wiley: Hoboken, 2005.
Hapiot, P. and Lagrost, C., Chem. Rev., 2008, vol. 108, p. 2238.
Han, X.X. and Armstrong, D.W., Acc. Chem. Res., 2007, vol. 40, p. 1079.
Bhat, M.A. and Ingole, P.P., Electrochim. Acta, 2012, vol. 72, p. 18.
Behar, D., Gonzalez, C., and Neta, P., J. Phys. Chem. A, 2001, vol. 105, p. 7607.
Robinson, R.A. and Stokes, R.H., Electrolyte Solutions, New York: Dover, 2002.
Barthel, J.M.G., Krienke, H., and Kunz, W., Physical Chemistry of Electrolyte Solutions: Modern Aspects, Darmstadt: Springer, 1998.
Lee, W.H. and Wheaton, R.J., J. Chem. Soc., Faraday Trans. 2, 1979, vol. 75, no. 8, p. 1128.
Pethybridge, A.D. and Taba, S.S., J. Chem. Soc., Faraday Trans. 1, 1980, vol. 76, no. 9, p. 368.
Chumak, V.L., Maksimyuk, M.R., and Neshta, T.V., Vost.-Evr. Zh. Peredovykh Tekhnol., 2013, vol. 62, no. 2/5, p. 59.
Safonova, L.P. and Kolker, A.M., Russ. Chem. Rev., 1992, vol. 61, no. 9, p. 959.
Zhuravlev, O.E., Russ. J. Phys. Chem. A, 2021, vol. 95, no. 2, p. 298.
Zhuravlev, O.E., Russ. J. Phys. Chem. A, 2021, vol. 95, no. 12, p. 2503.
Zhuravlev, O.E., Voronchikhina, L.I., and Gerasimova, K.P., Russ. J. Gen. Chem., 2016, vol. 86, no. 12, p. 2606.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by O. Zhukova
Rights and permissions
About this article
Cite this article
Zhuravlev, O.E., Gorbunova, D.V., Kaftanov, A.D. et al. A Study of the Electrical Conductivity of Ammonium Ionic Liquids Based on 2-(Dimethylamino)ethanol in an Acetonitrile Solution. rev. and adv. in chem. 12, 259–263 (2022). https://doi.org/10.1134/S2634827623700071
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2634827623700071