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Poly(urethane-imides) and Poly(ester-imides) as Promising Materials for Gas Separation and Pervaporation Membranes

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Abstract—

This review focuses on the separation properties of membranes based on poly(urethane-imides)—modern products of the chemical modification of polyimides and polyurethanes. The membrane properties of poly(urethane-imides) are reviewed in terms of their chemical design. Membranes based on multiblock (segmented) polymers, polyimides crosslinked by polyurethanes, hybrid poly(urethane-imide) materials, and poly(urethane-imides) subjected to the selective destruction of urethane blocks are considered. The main directions of synthesis of membrane poly(urethane-imides) are described, and reactants and reaction conditions are presented. The transport and separation properties of poly(urethane-imide) membranes in separation, pervaporation, and ultrafiltration processes are addressed in detail. Applications of poly(urethane-imide) membranes are discussed. The review provides insight into the importance of poly(urethane-imide) gas separation and pervaporation membranes for separation processes.

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Funding

This work was supported by the Russian Science Foundation, grant no. 22-19-00831.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. L. Didenko, A. S. Nesterova, T. S. Anokhina, I. L. Borisov & V. V. Kudryavtsev

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  1. A. L. Didenko
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  2. A. S. Nesterova
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  3. T. S. Anokhina
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  4. I. L. Borisov
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  5. V. V. Kudryavtsev
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Correspondence to A. L. Didenko or I. L. Borisov.

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Translated by T. Soboleva

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Didenko, A.L., Nesterova, A.S., Anokhina, T.S. et al. Poly(urethane-imides) and Poly(ester-imides) as Promising Materials for Gas Separation and Pervaporation Membranes. Membr. Membr. Technol. 6, 43–53 (2024). https://doi.org/10.1134/S2517751624010037

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