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Transport Properties and Structure of Anisotropic Composites Based on Cation-Exchange Membranes and Polyaniline

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Abstract

Comprehensive characterization of basic MK-40 and Ralex CMH heterogeneous cation-exchange membranes and composite membranes with polyaniline based on them is performed including the determination of specific electrical conductivity and diffusion permeability; measurement of current–voltage curves in solutions of sodium, calcium, and magnesium chlorides and hydrochloric acid and curves of distribution of water with respect to the bond energies and effective pore radii as well as assessment of the transport structural parameters of a microheterogeneous model. The time of synthesis of polyaniline on the surface of cation-exchange membranes for obtaining samples with an anisotropic structure and asymmetric electric transport properties is determined by successive diffusion of a solution of an oxidizing agent and a monomer through the membrane into water. It is shown based on the analysis of the electric transport properties, structural characteristics, and model transport structural parameters of the membranes in solutions of singly and doubly charged ions that the obtained materials are promising for use in the processes of electrodialysis desalination of multicomponent solutions.

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Funding

This work was financially supported by the Russian Foundation for Basic Research and Administration of Krasnodar Krai (project no. 19-48-230040 p_а).

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Authors and Affiliations

  1. Kuban State University, 350040, Krasnodar, Russia

    N. V. Loza, N. A. Kutenko & N. A. Kononenko

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    Yu. M. Volfkovich & V. E. Sosenkin

Authors
  1. N. V. Loza
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  2. N. A. Kutenko
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  3. N. A. Kononenko
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  4. Yu. M. Volfkovich
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  5. V. E. Sosenkin
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Correspondence to N. V. Loza.

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Translated by E. Boltukhina

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Loza, N.V., Kutenko, N.A., Kononenko, N.A. et al. Transport Properties and Structure of Anisotropic Composites Based on Cation-Exchange Membranes and Polyaniline. Membr. Membr. Technol. 5, 193–208 (2023). https://doi.org/10.1134/S2517751623030058

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  • DOI: https://doi.org/10.1134/S2517751623030058

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