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Effect of Low-Temperature Plasma on Polyketone Films: Changes in the Chemical Structure and Surface Morphology

  • NEW TECHNOLOGIES FOR OBTAINING AND PROCESSING MATERIALS
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Inorganic Materials: Applied Research Aims and scope

Abstract

X-ray photoelectron spectroscopy was used to study the change in the chemical composition of the surface of polyketone films as a result of exposure to a low-pressure direct-current (DC) discharge. The films were placed at the anode and cathode; filtered atmospheric air was used as a working gas. It was shown that a significant number of oxygen-containing groups is formed on the polymer surface. An atomic force microscopy study detected that plasma treatment leads to a considerable increase in the surface roughness of the films. Such changes improve the contact and adhesion properties of polyketone films.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation (subject no. FFSM-2021-0006). XPS studies were carried out using the equipment of the Center for Shared Use “Materials Science and Metallurgy,” National University of Science and Technology MISIS, Moscow, Russia, with the financial support of the Ministry of Science and Higher Education of the Russian Federation (agreement no. 075-15-2021-696).

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Authors and Affiliations

  1. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 117393, Moscow, Russia

    M. S. Piskarev, A. V. Zinoviev, A. B. Gilman & A. A. Kuznetsov

  2. National University of Science and Technology MISiS, 119049, Moscow, Russia

    E. A. Skryleva & B. R. Senatulin

  3. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    A. K. Gatin

Authors
  1. M. S. Piskarev
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  2. A. V. Zinoviev
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  3. A. B. Gilman
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  4. E. A. Skryleva
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  5. B. R. Senatulin
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  6. A. K. Gatin
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  7. A. A. Kuznetsov
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Corresponding authors

Correspondence to M. S. Piskarev or A. B. Gilman.

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Translated by V. Glyanchenko

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Piskarev, M.S., Zinoviev, A.V., Gilman, A.B. et al. Effect of Low-Temperature Plasma on Polyketone Films: Changes in the Chemical Structure and Surface Morphology. Inorg. Mater. Appl. Res. 14, 1377–1382 (2023). https://doi.org/10.1134/S2075113323050362

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  • DOI: https://doi.org/10.1134/S2075113323050362

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