Abstract—
Silver–polymer composite samples were obtained by the matrix synthesis method. The matrix was polyethylene terephthalate track membranes with pores of different diameters and concentrations. The matrix pores were filled by electrochemical deposition. The structure and mechanical properties of the composite, which consisted of the porous polymer matrix and silver nano- and microwires deposited into pores, were studied. The mechanical properties were determined experimentally by stretching the samples and building the stress–strain diagrams. The length and concentration of nano- and microwires filling the pores of the polyethylene terephthalate matrix were determined by scanning electron microscopy. The nano- and microwire lengths in the same sample are not equal; frequent crossings of the wires were also observed. The crossing probability and the number of nano- and microwire crossings were calculated using a previously developed procedure based on the single bond method. It was shown that the mechanical properties of the metal–polymer composite are significantly affected by the number of wire crossings and, at the same concentration of wires, by the wire diameter.
REFERENCES
Eliseev, A.A. and Lukashin, A.V., Funktsional’nye materialy (Functional Nanomaterials), Tret’yakov, Yu.D., Ed., Moscow: Fizmatlit, 2010.
Anishchik, V.M. et al., Nanomaterialy i nanotekhnologii (Nanomaterials and Nanotechnology), Borisenko, V.E. and Tolochko, N.K., Eds., Minsk: Belorus. State Univ., 2008.
Borisenko, V.E., Danilyuk, A.L., and Migas, D.B., Spintronika (Spintronics), Moscow: Lab. Znanii, 2017.
Martin, C.R., Nanomaterials: A membrane-based synthetic approach, Science, 1994, vol. 23, no. 266, pp. 1961–1966.
Electrodeposited Nanowires and Their Applications, Lupu, N., Ed., IntechOpen, 2010.
Pena, D.J. and Mbindyo, J.K.N., Template growth of photoconductive metal–CdSe–metal nanowires, J. Phys. Chem., 2002, vol. 106, pp. 7458–7462.
Petukhov, D.I., Napolskii, K.S., and Eliseev, A.A., Permeability of anodic alumina membranes with branched channels, Nanotechnology, 2012, vol. 23, p. 335601.
Masuda, H. and Fukuda, K., Ordered metal nanohole arrays made by a two-step replication of honeycomb structures of anodic alumina, Science, 1995, vol. 268, no. 5216, pp. 1466–1468.
Proenca, M.P., Sousa, C.T., Ventura, J., Vazquez, M., and Araujo, J.P., Ni growth inside ordered arrays of alumina nanopores: Enhancing the deposition rate, Electrochim. Acta, 2012, vol. 72, pp. 215–221.
Davydov, A.D. and Volgin, V.M., Template electrodeposition of metals, Rev. Russ. J. Electrochem., 2016, vol. 52, no. 9, pp. 806–831. https://doi.org/10.1134/S1023193516090020
Magnetic Nano- and Microwires: Design, Synthesis, Properties and Applications, Vázquez, M., Ed., Woodhead, 2015.
Pullini, D., Influence of deposition potential on structure of ZnO nanowires synthesized in track-etched membranes, J. Electrochem. Soc., 2012, vol. 159, no. 4, pp. 45–52.
Mitrofanov, A.V., Apel, P.Yu., Blonskaya, I.V., and Orelovitch, O.L., Diffraction filters based on polyimide and poly(ethylene naphthalate) track membranes, Tech. Phys., 2006, vol. 76, no. 9, pp. 121–127.
Volgin, V.M. and Davydov, A.D., Natural-convective instability of electrochemical systems: A review, Russ. J. Electrochem., 2006, vol. 42, pp. 567–608.
Kalinin, I.A., Davydov, A.D., Leontiev, A.P., Napolskii, K.S., Sobolev, A., Shatalov, M., Zinigrad, M., and Bograchev, D., Influence of natural convection on the electrodeposition of copper nanowires in anodic aluminium oxide templates, Electrochim. Acta, 2023, vol. 441, p. 141766.
Doludenko, I.M., Volchkov, I.S., Turenko, B.A., Koshelev, I.O., Podkur, P.L., Zagorskiy, D.L., and Kanevskii, V.M., Electrical properties arrays of intersecting of nanowires obtained in the pores of track membranes, Mater. Chem. Phys., 2022, vol. 287, p. 126285.
Clark, P.J. and Evans, F.C., Distance to nearest neighbor as a measure of spatial relationships in populations, Ecology, 1954, vol. 35, pp. 445–453.
ACKNOWLEDGMENTS
The scanning electron microscopy study was carried out on the equipment of the Center for Collective Use, Federal Research Center “Crystallography and Photonics,” Russian Academy of Sciences, Moscow, Russia.
Funding
This study was carried out in part within the State Assignment of the Ministry of Science and Higher Education of the Russian Federation for the Federal Research Center “Crystallography and Photonics,” Russian Academy of Sciences, Moscow, Russia.
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Translated by E. Bondareva
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Panov, D.V. Studying the Mechanical Properties and Structure of the Silver–Polyethylene Terephthalate Composite. Inorg. Mater. Appl. Res. 14, 1245–1250 (2023). https://doi.org/10.1134/S2075113323050337
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DOI: https://doi.org/10.1134/S2075113323050337