Skip to main content
Log in

Electrophysical Characteristics of Epoxy Nanocomposites with Ultralow Percolation Thresholds

  • GENERAL PURPOSE MATERIALS
  • Published:
Inorganic Materials: Applied Research Aims and scope

Abstract

Nanocomposites based on ED-20 epoxy resin and single-walled carbon nanotubes (SWCNT) with high aspect ratios (l/d ~ 2500) have been produced. The filler has been introduced into a matrix using a high speed mixer without solvents. The electrical and physical characteristics of produced composites have been examined at various SWCNT concentrations. A low percolation threshold is experimentally established, indicating weak filler agglomerates in the epoxy matrix. The dielectric permittivity and tangent loss are plotted as the functions of the SWCNT concentration within a wide frequency range. All dependences exhibit the presence of a relaxation peak shifting toward the higher frequencies as the filler concentration increases. The investigation of nanocomposite cleavages via scanning electron microscopy reveals a uniform SWCNT distribution in the matrix.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. Mittal, V., Polymer Nanotube Nanocomposites: Synthesis, Properties, and Applications, New York: Wiley, 2010.

    Book  Google Scholar 

  2. Rakov, E.G., Carbon nanotubes in new materials, Russ. Chem. Rev., 2013, vol. 82, no. 1, pp. 27–47.

    Article  Google Scholar 

  3. Irzhak, V.I., Epoxide composite materials with carbon nanotubes, Russ. Chem. Rev., 2011, vol. 80, no. 8, pp. 787–806.

    Article  CAS  Google Scholar 

  4. Yurkov, G.Yu. and Kondrashov, S.V., Nanocomposites based on high-density polyethylene and cobalt nanoparticles: synthesis, structure and properties, Aviats. Mater. Tekhnol., 2014, suppl. 2, pp. 29–33.

  5. Eletskii, A.V., Knizhnik, A.A., Potapkin, B.V., and Kenny, J.M., Electrical characteristics of carbon nanotube-doped composites, Phys.-Usp., 2015, vol. 58, no. 3, pp. 209–251.

    Article  CAS  Google Scholar 

  6. Feng, C. and Jiang, L., Micromechanics modeling of the electrical conductivity of carbon nanotube (CNT)–polymer nanocomposites, Composites, Part A, 2013, vol. 47, pp. 143–149.

    Article  CAS  Google Scholar 

  7. Dyre, J.C. and Schrøder, T.B., Hopping models and ac universality, Phys. Status Solidi B, 2002, vol. 230, no. 1, pp. 5–13.

    Article  CAS  Google Scholar 

  8. Psarras, G.C., Manolakaki, E., and Tsangaris, G.M., Electrical relaxations in polymeric particulate composites of epoxy resin and metal particles, Composites, Part A, 2002, vol. 33, pp. 375–384.

    Article  Google Scholar 

  9. Thostenson, E., Li C., and Chou, T., Nanocomposites in context, Compos. Sci. Technol., 2005, vol. 65, nos. 3–4, pp. 491–516.

Download references

Funding

This work was supported by the Federal Agency for Scientific Organizations of Russia within the framework of the State task (project no. 45.11).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to I. Yu. Klyuev.

Additional information

Translated by O. Maslova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Klyuev, I.Y., Shevchenko, V.G., Kuperman, A.M. et al. Electrophysical Characteristics of Epoxy Nanocomposites with Ultralow Percolation Thresholds. Inorg. Mater. Appl. Res. 11, 416–419 (2020). https://doi.org/10.1134/S2075113320020197

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2075113320020197

Keywords:

Navigation