Abstract
The physicochemical properties of artificial hybrid inorganic-organic material based on highly dispersed porous shungite and silver nanoparticles are investigated via energy dispersive X-ray microanalysis and surface activated spectrometry with laser desorption/ionization. Silver is found to be firmly secured on the shungite surface, forming clusters with shungite carbon. The hybrid material is well wetted by water and forms stable nanodispersions in water.
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REFERENCES
Eliseev, A.A. and Lukashin, A.V., Funktsional’nye nanomaterialy (Functional Materials), Tret’yakov, Yu.D., Ed., Moscow: Fizmatlit, 2010.
Krutyakov, Yu.A., Kudrinskiy, A.A., Olenin, A.Yu., and Lisichkin, G.V., Synthesis and properties of silver nanoparticles: advances and prospects, Russ. Chem. Rev., 2008, vol. 77, no. 3, pp. 233–257.
Polunina, I.A., Goncharova, I.S., Petukhova, G.A., Vysotskiy, V.V., Polunin, K.E., and Buryak, A.K., Preparation of a new sorption material based on modified shungite, Inorg. Mater.: Appl. Res., 2017, vol. 8, no. 1, pp. 181–185.
Polunina, I.A., Visotskii, V.V., Senchikhin, I.N., Polunin, K.E., and Buryak, A.K., The effect of the modification on the physicochemical characteristics of shungite, Colloid J., 2017, vol. 79, no. 2, pp. 244–249. https://doi.org/10.1134/S1061933X17020107
Shungity—novoe uglerodistoe syr’e (Shungites as a New Carbon Material), Sokolov, V.A., Kalinin, Yu.K., and Dyukkiev, E.F., Eds., Petrozavodsk: Kareliya, 1984.
Revina, A.A. and Baranova, E.K., Modification of carbon nanotubes by nanosize metal particles, Prot. Met. Phys. Chem. Surf., 2010, vol. 46, no. 4, pp. 452–455.
Revina, A.A., Kezikov, A.N., Alekseev, A.V., Khailova, E.B., and Volod’ko, V.V., Radiochemical synthesis of stable metal nanoparticles, Nanotekhnika, 2005, no. 4, pp. 105–111.
Revina, A.A., RF Patent 2212268, 2003.
Polunin, K.E., Goncharova, I.S., Ulyanov, A.V., Polunina, I.A., and Buryak, A.K., Soft ionization mass spectrometry for studying desorption of bioactive compounds from a shungite surface, Colloid J., 2017, vol. 79, no. 2, pp. 250–257. https://doi.org/10.1134/S1061933X17020090
Kezikov, A.N., Baranova, E.K., Khailova, E.B., and Revina, A.A., Comparison of the sorption activity of silver and palladium nanoparticles on porous adsorbents, Sorbtsionnye Khromatogr. Protsessy, 2017, vol. 17, no. 2, pp. 916–923.
Belyakova, L.D., Kolomiets, L.N., Larionov, O.G., Bulanova, A.V., Myakisheva, E.A., and Revina, A.A., Analysis of the surface properties of silicagel modified by silver nanoparticles by gas chromatography, Sorbtsionnye Khromatogr.Protsessy, 2007, vol. 7, no. 1, pp. 98–105.
Polunina, I.A., Goncharova, I.S., Polunin, K.E., and Buryak, A.K., Effect of chemical composition of shungite material on its sorption properties, Inorg. Mater.: Appl. Res., 2018, vol. 9, no. 4, pp. 772–776.
Anderson, J.R., Structure of Metallic Catalysts, London: Academic, 1975.
Akimbaeva, A.M., Sorption of phenol by modified schungites, Pet. Chem., 2007, vol. 47, no. 3, pp. 205–208.
Funding
This work was supported by the Russian Foundation for Basic Research (project no. 18‑08‑01224) and by OOO Laboratoriya nanokompozitnykh materialov (Laboratory of Nanocomposite Materials) (Moscow) for providing silver nanoparticles.
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Polunina, I.A., Goncharova, I.S., Polunin, K.E. et al. Hybrid Inorganic-Organic Materials Based on Shungite and Silver Nanoparticles. Inorg. Mater. Appl. Res. 11, 50–54 (2020). https://doi.org/10.1134/S2075113320010281
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DOI: https://doi.org/10.1134/S2075113320010281