Skip to main content
SpringerLink
Log in

The Ion-Exchange Properties of Polymeric Zirconium Phosphate and Zirconium Dioxide

  • Published:
Inorganic Materials: Applied Research Aims and scope

Abstract

The ion-exchange properties of polymeric zirconium phosphate and zirconium dioxide were studied and their ion-exchange capacities with respect to pyridine bases and pyridinecarboxylic acids were determined. The ion-exchange capacities of polymeric zirconium phosphate with respect to pyridine bases and pyridinecarboxylic acids were 0.53–0.76 and 0.18–0.2 meq/g, respectively. The ion-exchange capacity of polymeric zirconium dioxide with respect to pyridinecarboxylic acids was 0.43–0.44 meq/g. Polymeric zirconium phosphate and zirconium dioxide containing 1–3% of immobilized metallic palladium particles were obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Amphlett, C.B., Inorganic Ion Exchangers, Amsterdam: Elsevier, 1964.

    Google Scholar 

  2. Yurchenko, V.V., Sviridov, A.V., Nikiforov, A.F., Kutergin, A.S., and Voronina, A.V., Concentration of cesium and strontium from aqueous systems by adsorbents based on bentonite clays, Butlerovskie Soobshch., 2016, vol. 47, no. 7, pp. 52–57.

    Google Scholar 

  3. Khodyakov, A.A., Kaiman, E.P., Konstantinova, L.I., and Zakharova, E.V., Electrical and sorption properties of sandy-clay rocks in diluted solutions of electrolytes, Materialovedenie, 2009, no. 5, pp. 38–43.

    Google Scholar 

  4. Polunina, I.A., Goncharova, I.S., Petukhova, T.A., Vysotskiy, V.V., Polunin, K.E., and Buryak, A.K., Preparation of a new sorption material based on modified shungite, Inorg. Mater.: Appl. Res., 2017, vol. 8, no. 1, pp. 181–185.

    Article  Google Scholar 

  5. Razdorkina, S.P., Waste inorganic sorbents of chemical production as a cheap material for water purification from long-lived fission products, Materialovedenie, 2003, no. 3, pp. 51–53.

    Google Scholar 

  6. Sukharev, Yu.A. and Egorov, Yu.V., Neorganicheskie ionity tipa fosfata tsirkoniya (Inorganic Ionites of Zirconium Phosphate Type), Moscow: Energoatomizdat, 1983.

    Google Scholar 

  7. Zhang, Q.R., Du, W., Pan, B.C., Pan, B.J., Zhang, W.M., Zhang, Q.J., Xu, Z.W., and Zhang, Q.X., A comparative study on Pb2+, Zn2+, and Cd2+ sorption onto zirconium phosphate supported by a cation exchanger, J. Hazard. Mater., 2008, vol. 152, pp. 469–475.

    CAS  PubMed  Google Scholar 

  8. Pan, B.C., Zhang, Q.R., Du, W., Zhang, W.M., Pan, B.J., Xu, Z., and Zhang, Q.X., Selective heavy metals removal from waters by amorphous zirconium phosphate: behavior and mechanism, Water Res., 2007, vol. 41, pp. 3103–3111.

    Article  CAS  PubMed  Google Scholar 

  9. Sharma, G., Pathania, D., and Nanshad, M., Preparation, characterization and ion exchange behavior of nanocomposite polyaniline zirconium (IY) selenotungstophosphate for the separation to toxic metal ions, Ionics, 2015, vol. 21, no. 4, pp. 1049–1055.

    Google Scholar 

  10. Kuznetsov, P.N., Tverdokhlebov, V.P., and Kuznetsova, L.I., New zirconia-based catalysts for the isomerization of alkanes of petroleum fractions, Zh. Sib. Fed. Univ., 2011, no. 4, pp. 438–452.

    Google Scholar 

  11. Abramova, L.P., Al’tshuler, G.N., Malyshenko, N.V., et al., Solid-phase nanoreactors for alkyl pyridine oxidation, Khim. Interesakh Ustoich. Razvit., 2015, vol. 23, no. 2, pp. 151–156.

    CAS  Google Scholar 

  12. Al’tshuler, G.N., Synthesis of pyridinecarboxylic acids by the catalytic oxidation of coal tar components on metal-polymer nanocomposites, Solid Fuel Chem., 2012, vol. 46, no. 4, pp. 275–278.

    Article  CAS  Google Scholar 

  13. Al’tshuler, G.N. and Sapozhnikova, L.A., Preparation of ultradispersed transition metals in immobilized microreactors, Russ. J. Appl. Chem., 2004, vol. 77, no. 11, pp. 1896–1898.

    Article  Google Scholar 

  14. Baetsle, L. and Pelsmaekers, J., Ion exchange properties of zirconyl phosphates—I: Contribution to the structure of zirconyl phosphates, J. Inorg. Nucl. Chem., 1961, vol. 21, pp. 124–132.

    Article  CAS  Google Scholar 

  15. Blumenthal, W.B., The Chemical Behavior of Zirconium, Princeton, NJ: Van Nostrand Reinhold, 1958.

    Google Scholar 

  16. Jiang, P., Pan, P.G., Pan, P.C., and Zhang, Q.R., A comparative study on lead sorption by amorphous and crystalline zirconium phosphates, Colloids Surf., A, 2008, vol. 322, no. 1–3, pp. 108–112.

    Article  CAS  Google Scholar 

  17. JCPDS PDF no. 03-065-6174.

Download references

Author information

Authors and Affiliations

  1. Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences, Kemerovo, Russia

    G. N. Altshuler, N. V. Malyshenko & A. N. Popova

Authors
  1. G. N. Altshuler
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. V. Malyshenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. N. Popova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. N. Altshuler.

Additional information

Original Russian Text © G.N. Altshuler, N.V. Malyshenko, A.N. Popova, 2018, published in Materialovedenie, 2018, No. 2, pp. 18–22.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Altshuler, G.N., Malyshenko, N.V. & Popova, A.N. The Ion-Exchange Properties of Polymeric Zirconium Phosphate and Zirconium Dioxide. Inorg. Mater. Appl. Res. 9, 746–750 (2018). https://doi.org/10.1134/S2075113318040032

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2075113318040032

Keywords

Search

Navigation