Skip to main content
Log in

Polymorphism of 2D monolayer J-aggregates of cyanine dyes

  • Published:
Inorganic Materials: Applied Research Aims and scope

Abstract

Meso- and nanoscale structural polymorphism of monolayer J-aggregates of four cyanine dyes are investigated. Three mesoscale morphological types are observed: ribbons, rhombic leaves, and tubes. Tubes are formed during cylindrical spinning of ribbons. Lined substructure characterized by the line width of about 7 nm is found in the case of monolayers of monomethine cyanine dyes at the nanoscale.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Würthner, F., Kaiser, T.E., and Saha-Möller, C.R., J-Aggregates: From serendipitous discovery to supramolecular engineering of functional dye materials, Angew. Chem. Int., 2011, vol. 50, pp. 3376–3410.

    Article  Google Scholar 

  2. Shapiro, B.I., Molecular assemblies of polymethine dyes, Russ. Chem. Rev., 2006, vol. 75, no. 5, pp. 433–456.

    Article  CAS  Google Scholar 

  3. Tani, T., Suzumoto, T., Kemnitz, K., and Yoshihara, K., Picosecond kinetics of light-induced electron transfer from J-aggregated cyanine dyes to silver bromide microcrystals: Effect of aggregate size, J. Phys. Chem., 1992, vol. 96, pp. 2778–2783.

    Article  CAS  Google Scholar 

  4. Mal’tsev, E.I., Lypenko, D.A., Bobinkin, V.V., Tameev, A.R., Kirillov, S.V., Shapiro, B.I., Schoo, H.F.M., and Vannikov, A.V., Near-infrared electroluminescence in polymer composites based on organic nanocrystals, Appl. Phys. Lett., 2002, vol. 81, pp. 3088–3090.

    Article  Google Scholar 

  5. Yang, Y., Omi, S., Goto, R., Yahiro, M., Era, M., Watanabe, H., and Oki, Y., Wavelength sensitive photodiodes in the visible based on J-type aggregated films patterned by inkjet method, Org. Electron., 2011, vol. 12, pp. 405–410.

    Article  CAS  Google Scholar 

  6. Walker, B.J., Dorn, A., Bulovic, V., and Bawendi, M.G., Color-selective photocurrent enhancement in coupled J-aggregate/nanowires formed in solution, Nano Lett., 2011, vol. 11, pp. 2655–2659.

    Article  CAS  Google Scholar 

  7. Akselrod, G.M., Walker, B.J., Tisdale, W., Bawendi, M.G., and Bulović, V., Twenty-fold enhancement of molecular fluorescence by coupling to a J-aggregate critically coupled resonator, ACS Nano, 2012, vol. 6, pp. 467–471.

    Article  CAS  Google Scholar 

  8. Yao, H., Morphology transformations in solutions: dynamic supramolecular aggregates, Annu. Rep. Prog. Chem., Sect. C: Phys. Chem., 2004, vol. 100, pp. 99–148.

    Article  CAS  Google Scholar 

  9. Prokhorov, V.V., Mal’tsev, E.I., Perelygina, O.M., Lypenko, D.A., Pozin, S.I., and Vannikov, A.V., High precision nanoscale AFM height measurements of J-aggregates, Nanotechnol. Russ., 2011, vol. 6, nos. 5–6, pp. 286–297.

    Article  Google Scholar 

  10. Prokhorov, V.V., Pozin, S.I., Lypenko, D.A., Perelygina, O.M., Mal’tsev, E.I., and Vannikov, A.V., Molecular arrangements in polymorphous monolayer structures of carbocyanine dye J-aggregates, Chem. Phys. Lett., 2012, vol. 535, pp. 94–99.

    Article  CAS  Google Scholar 

  11. Prokhorov, V.V., Pozin, S.I., Perelygina, O.M., Lypenko, D.A., and Mal’tsev, E.I., Symmetry of monolayer structures of J-aggregates of a monomethin dye, Materialovedenie, 2012, no. 2, pp. 38–41.

    Google Scholar 

  12. Prokhorov, V.V., Pozin, S.I., Lypenko, D.A., Perelygina, O.M., Mal’tsev, E.I., and Vannikov, A.V., Molecular arrangements in two-dimensional J-aggregate monolayers of cyanine dyes, Macroheterocycles, 2012, vol. 5, pp. 371–376.

    Article  CAS  Google Scholar 

  13. Prokhorov, V.V., Perelygina, O.M., Mal’tsev, E.I., and Vannikov, A.V., Crystalline structure of two-dimensional cyanine dye J-aggregates, Crystallogr. Rep., 2014, vol. 59, no. 6, pp. 896–899.

    Article  CAS  Google Scholar 

  14. Prokhorov, V.V., Perelygina, O.M., Pozin, S.I., Mal’tsev, E.I., Vannikov, A.V., and Tsivadze, A.Yu., Tubular structure of J-aggregates of cyanine dye, Dokl. Chem., 2015, vol. 460, no. 1, pp. 1–4.

    Article  CAS  Google Scholar 

  15. Prokhorov, V.V., Perelygina, O.M., Pozin, S.I., Mal’tsev, E.I., and Vannikov, A.V., Polymorphism of two-dimensional cyanine dye J-aggregates and its genesis: fluorescence microscopy and atomic force microscopy study, J. Phys. Chem. B, 2015, vol. 119, no. 48, pp. 15046–15053.

    Article  CAS  Google Scholar 

  16. von Berlepsch, H., Böttcher, C., and Dähne, L., Structure of J-aggregates of pseudoisocyanine dye in aqueous solution, J. Phys. Chem. B, 2000, vol. 104, no. 37, pp. 8792–8799.

    Article  Google Scholar 

  17. von Berlepsch, H., Kirstein, S., Hania, R., Pugžlys, A., and Böttcher, C., Modification of the nanoscale structure of the J-aggregate of a sulfonate-substituted amphiphilic carbocyanine dye through incorporation of surface-active additives, J. Phys. Chem. B, 2007, vol. 111, no. 7, pp. 1701–1711.

    Article  Google Scholar 

  18. Toda, A., Okamura, M., Hikosaka, M., and Nakagawa, Y., AFM observation of polyethylene single crystals: Selective handedness of screw dislocations in a chair type, Polymer, 2003, vol. 44, no. 20, pp. 6135–6138.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. V. Prokhorov.

Additional information

Original Russian Text © V.V. Prokhorov, S.I. Pozin, O.M. Perelygina, V.I. Zolotarevskii, E.I. Mal’tsev, A.V. Vannikov, 2016, published in Materialovedenie, 2016, No. 10, pp. 19–26.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Prokhorov, V.V., Pozin, S.I., Perelygina, O.M. et al. Polymorphism of 2D monolayer J-aggregates of cyanine dyes. Inorg. Mater. Appl. Res. 8, 494–501 (2017). https://doi.org/10.1134/S2075113317040219

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2075113317040219

Keywords

Navigation