Abstract
Nanocrystalline powder (~20 nm) with the composition of (ZrO2)0.6(In2O3)0.04 is synthesized on the basis of a co-precipitation method. After its consolidation, a dense and porous ceramic matrix for supercapacitor electrodes is obtained. The deposition conditions are determined for thin nanocarbon and MnO2, Co3O4 layers on the porous ceramic or metal matrix. It is shown that the model supercapacitor with composite electrodes based on nickel foam and thin layers of nanocarbon and MnO2 has the highest average specific capacitance.
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Arsent’ev, M.Yu., Tikhonov, P.A., Kalinina, M.V., Tsvetkova, I.N., and Shilova, O.A., Synthesis and physico-chemical properties of the electrode and electrolyte nanocomposites for supercapacitors, Fiz. Khim. Stekla, 2012, vol. 38, no. 5, pp. 653–664.
Vol’fkovich, Yu.M. and Serdyuk, T.M., Electrochemical capacitors, Elektrokhim. Energ., 2001, vol. 1, no. 4, pp. 14–28.
Shilova, O.A., Antipov, V.N., Tikhonov, P.A., Kruchinina, I.Y., Arsentev, M.Y., Panova, T.I., Morozova, L.V., Moskovskaya, V.V., Kalinina, M.V., and Tsvetkova, I.N., Ceramic nanocomposites based on oxides of transition metals for ionistors, Glass Phys. Chem., 2013, vol. 39, no. 5, pp. 570–578.
Cottineau, T., Toupin, M., Delahaye, T., Brousse, T., and Bélanger, D., Nanostructured transition metal oxides for aqueous hybrid electrochemical supercapacitors, Appl. Phys. A: Mater. Sci. Process., 2006, vol. 82, no. 4, pp. 599–606.
Kovalenko, A.S, Shilova, O.A., Morozova, L.V., Kalinina, M.V., Drozdova, I.A., and Arsent’ev, M.Yu., Feature of the synthesis and the study of nanocrystalline cobalt-nickel spinel, Glass Phys. Chem., 2014, vol. 40, no. 1, pp. 106–113.
Kalinina, M.V., Morozova, L.V., Khlamov, I.I., Egorova, T.L., Arsent’ev, M.Yu., Drozdova, I.A., and Shilova, O.A., Synthesis and analysis of nanoceramics based on cobalt metaniobate, Fiz. Khim. Stekla, 2014, vol. 40, no. 5, pp. 759–765.
Avinash Balakrishnan and Subramanian, K.R.V., Nanostructured Ceramic Oxides for Supercapacitor Applications, Boca Raton, FL: CRC Press, 2014.
Duran, P., Villegas, M., and Capel, F., Low-temperature sintering and microstructural development of nanocrystalline Y-TZP powders, J. Eur. Ceram. Soc., 1996, vol. 16, no. 9, pp. 945–952.
Morozova, L.V., Panova, T.I., Popov, V.P., Tsvetkova, I.N., and Shilova, O.A., Synthesis and study of oxide and phosphorsilicate nanocomposites for the creation of new-generation supercapacitors, Glass Phys. Chem., 2012, vol. 38, no. 3, pp. 332–338.
Khimiya tverdogo tela. Khimicheskie problemy sozdaniya novykh materialov (Solid State Chemistry. Chemical Problems of Creating New Materials), Murin, I.V., Ed., St. Petersburg: St.-Peterb. Gos. Univ., 2003.
Arsent’ev, M.Yu., Kalinina, M.V., and Tikhonov, P.A., RF Patent 134534, 2013.
Kukovitskii, E.F., L’vov, S.G., Sainov, N.A., Shustov, N.A., Kiselev, N.A., Izrael’yants, K.P., and Musatov, L.A., The role of the structure of the surface layers of metallic nickel in the catalytic synthesis of carbon nanotube field emitters, Mikrosist. Tekh., 2002, no. 7, pp. 28–31.
Kukovitskii, E.F. and L’vov, S.G., Carbon nanotube cathodes on nickel cores, Nano-Mikrosist. Tekh., 2010, no. 6, pp. 2–5.
Mishchenko, S.V., Rukhov, A.V., Tkachev, A.G., and Tugolukov, E.N., Specific features of the synthesis of carbon nanomaterials in the device with induction heating of the catalyst, Vestn. Tambov. Gos. Tekh. Univ., 2008, vol. 14, no. 4, pp. 820–824.
Pavlov, G., Technological equipment for the formation of carbon layers, Nanoindustriya, 2007, no. 2, pp. 28–29.
Chou, S.-L., Wang, J.-Z., Chew, S.-Y., Liu, H.-K., and Dou, S.-X., Electrodeposition of MnO2 nanowires on carbon nanotube paper as free-standing, flexible electrode for supercapacitors, Electrochem. Commun., 2008, vol. 10, no. 11, pp. 1724–1727.
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Original Russian Text © M.V. Kalinina, L.V. Morozova, T.L. Egorova, M.Yu. Arsentyev, I.I. Khlamov, P.A. Tikhonov, O.A. Shilova, 2016, published in Perspektivnye Materialy, 2016, No. 8, pp. 22–30.
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Kalinina, M.V., Morozova, L.V., Egorova, T.L. et al. Composite materials based on oxides of d and f elements and carbon layers. Inorg. Mater. Appl. Res. 8, 254–259 (2017). https://doi.org/10.1134/S2075113317020071
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DOI: https://doi.org/10.1134/S2075113317020071