Skip to main content
SpringerLink
Log in

Kinetics of phase formation in a Li2CO3-TiO2-Fe2O3 system during radiation-thermal synthesis

  • Physico-Chemical Principles of Materials Development
  • Published:
Inorganic Materials: Applied Research Aims and scope

Abstract

Kinetic changes in the concentration of source components in a Li2CO3-TiO2-Fe2O3 system during radiation-thermal (RT) synthesis are considered. The phase composition control is realized by X-ray diffraction (XRD) analysis, thermogravimetry (TG/DTG) analysis, and differential scanning calorimetry (DSC). The initial composition of reaction mixtures corresponds to the stoichiometric formula of spinel Li0.5(1 + x)Fe2.5 − 1.5x Ti x O4, where x = 0.2, 0.4, 0.6.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ahniyaz, A., Fujiwara, T., Song, S.-W., and Yoshimura, M., Low temperature preparation of β-LiFe5O8 fine particles by hydrothermal ball milling, J. Solid State Ionics, 2002, vol. 151, pp. 419–423.

    Article  CAS  Google Scholar 

  2. Lyakhov, N.Z., Boldyrev, V.V., Voronin, A.P., Gribkov, O.S., Bochkarev, L.G., Rusakov, S.V., and Auslender, V.L., Electron beam stimulated chemical reaction in solids, J. Therm. Anal. Calorim., 1995, vol. 43, pp. 21–31.

    Article  CAS  Google Scholar 

  3. Surzhikov, A.P., Pritulov, A.M., Ivanov, Y.F., Shabardin, R.S., and Usmanov, R.U., Electron-microscopic study of morphology and phase composition of lithium-titanium ferrites, J. Russ. Phys., 2001, vol. 44, pp. 420–423.

    Article  CAS  Google Scholar 

  4. Surzhikov, A.P., Pritulov, A.M., Lysenko, E.N., Sokolovskiy, A.N., Vlasov, V.A., and Vasendina, E.A., Calorimetric investigation of radiation-thermal synthesized lithium pentaferrite, J. Therm. Anal. Calorim., 2010, vol. 101, pp. 11–13.

    Article  CAS  Google Scholar 

  5. Surzhikov, A.P., Lysenko, E.N., Vasendina, E.A., Sokolovskii, A.N., Vlasov, V.A., and Pritulov, A.M., Thermogravimetric investigation of the effect of annealing conditions on the soft ferrite phase homogeneity, J. Therm. Anal. Calorim., 2011, vol. 104, pp. 613–617.

    Article  CAS  Google Scholar 

  6. Surzhikov, A.P., Pritulov, A.M., Lysenko, E.N., Sokolovsky, A.N., Vlasov, V.A., and Vasendina, E.A., Influence of solid-phase ferritization method on phase composition of lithium-zinc ferrites with various concentration of zinc, J. Therm. Anal. Calorim., 2012, vol. 109, pp. 63–67.

    Article  CAS  Google Scholar 

  7. Surzhikov, A.P., Pritulov, A.M., Lysenko, E.N., Sokolovsky, A.N., Vlasov, V.A., and Vasendina, E.A., Dependence of lithium-zinc ferrospinel phase composition on the duration of synthesis in an accelerated electron beam, J. Therm. Anal. Calorim., 2012, vol. 110, pp. 733–738.

    Article  CAS  Google Scholar 

  8. Baba, P.D., Argentina, G.M., Courtney, W.E., Dionne, G.F., and Temme, D.H., Fabrication and properties of microwave lithium ferrites, IEEE Trans. Magn., 1972, vol. 8, pp. 83–94.

    Article  CAS  Google Scholar 

  9. Gorter, E.V., Magnetization of saturation and crystallochemistry of ferromagnetic oxides, Usp. Fiz. Nauk, 1955, vol. 57, no. 2, pp. 279–346.

    Article  Google Scholar 

  10. Blyasse, Zh., Kristallokhimiya ferroshpinelei (Crystallochemistry of Ferrospinels), Moscow: Metallurgiya, 1968.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. National Research Tomsk Polytechnic University, ul. Lenina 30, Tomsk, 634050, Russia

    A. P. Surzhikov, E. A. Vasendina, E. N. Lysenko & E. V. Nikolaev

Authors
  1. A. P. Surzhikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Vasendina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. N. Lysenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. V. Nikolaev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. P. Surzhikov.

Additional information

Original Russian Text © A.P. Surzhikov, E.A. Vasendina, E.N. Lysenko, E.V. Nikolaev, 2013, published in Perspektivnye Materialy, 2013, No. 8, pp. 5–10.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Surzhikov, A.P., Vasendina, E.A., Lysenko, E.N. et al. Kinetics of phase formation in a Li2CO3-TiO2-Fe2O3 system during radiation-thermal synthesis. Inorg. Mater. Appl. Res. 5, 102–106 (2014). https://doi.org/10.1134/S207511331402021X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S207511331402021X

Keywords

Search

Navigation