Abstract
Optical homogeneity and subtle features of the structural distortions in a series of lithium niobate (LiNbO3) single crystals of congruent composition doped with Mg2+ (0.01–5.5 mol %) are analyzed by laser conoscopy using a He-Ne laser (λ = 632.8 nm) with a power below 1 mW. Standard and distorted conoscopic patterns are observed for LiNbO3:Mg (0.01–1.5 mol %) and LiNbO3:Mg (3.0–5.5 mol %) samples, respectively. It is shown that the structural imperfection and optical anomalies reach a maximum at concentrations of about 3 mol % Mg2+ and are due to the inhomogeneity of Mg2+ incorporation into the structure at concentrations ≥3 mol %. The latter can be caused by the change in the mechanism of Mg2+ incorporation into the crystal structure at Mg2+ concentrations ≥3 mol %.
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Original Russian Text © O.Yu. Pikul’, N.V. Sidorov, O.V. Makarova, M.N. Palatnikov, 2013, published in Perspektivnye Materialy, 2013, No. 12, pp. 72–81.
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Pikul’, O.Y., Sidorov, N.V., Makarova, O.V. et al. Laser conoscopy of LiNbO3:Mg single crystals. Inorg. Mater. Appl. Res. 5, 189–197 (2014). https://doi.org/10.1134/S2075113314020166
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DOI: https://doi.org/10.1134/S2075113314020166