Abstract
Δ\( \mathop {G^{im} }\limits^ \eqsim \) (ΔT) dependences for oversegmental structures of polymers obtained within a macrothermodynamic hierarchy model qualitatively and quantitatively correspond to analogous correlations for a wide set of substances obtained earlier, which confirms the reality of these nanostructures for the amorphous state of polymers. Derived equations are equally applicable for the description of thermodynamic behavior of these nanostructures and can be used for their quantitative modeling. If it is necessary to carry out more rigorous calculations, corrections should be made to the change in the heat capacity at phase transitions.
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Original Russian Text © G.V. Kozlov, M.T. Bashorov, A.K. Mikitaev, G.E. Zaikov, 2010, published in Materialovedenie, 2010, No. 1, pp. 10–13.
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Kozlov, G.V., Bashorov, M.T., Mikitaev, A.K. et al. Thermodynamics of the formation of nanostructure of polymers in amorphous state. Inorg. Mater. Appl. Res. 1, 195–199 (2010). https://doi.org/10.1134/S2075113310030044
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DOI: https://doi.org/10.1134/S2075113310030044