Abstract—The article presents data on the synthesis of nanostructured, X-ray amorphous lithium aluminosilicate, with a Si : Al ratio of 3 : 1. The composition, morphology, and thermal behavior were studied. The sorption isotherm of Cs+ ions was obtained under static conditions with a ratio of T : L = 1 : 400. The maximum sorption capacity, degree of extraction, and distribution coefficients of cesium were determined. Data on the sorption kinetics of Cs+ ions were obtained at temperatures 30 and 60°C, and the activation energy of the sorption process and diffusion coefficients were calculated.
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The study was carried out within the state task of the Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, FWFN (0205)-2022-0002, topic 2, section 3.
The registration number of the topic in the Plan of the Scientific Council of the Russian Academy of Sciences on Physical Chemistry (section “Adsorption Phenomena”) is 22-03-460-05. ICP-MS analysis was performed on equipment of the Center for Shared Use Primorsky Center for Local, Elemental, and Isotope Analysis, Far East Geological Institute, Far Eastern Branch, Russian Academy of Sciences; elemental and XRD analyses were performed on equipment of the Shared Use Center Far Eastern Center for Structural Research, Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences.
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Gordienko, P.S., Pashnina, E.V., Yarusova, S.B. et al. Synthesis and Sorption Properties of Lithium Aluminosilicate. Prot Met Phys Chem Surf 59, 860–867 (2023). https://doi.org/10.1134/S2070205123701046
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DOI: https://doi.org/10.1134/S2070205123701046