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Selective Sorbents Based on 2-Hydroxyethylmethacrylate and Ethylene Glycol Dimethacrylate Modified with Boric Acid as High-Affinity Ligands for Glucose

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Abstract

A synthesis method of granulated polymeric sorbents based on 2-hydroxyethylmethacrylate and ethylene glycol dimethacrylate that possess affinity to glucose sorption sites formed by boric acid molecules has been developed. The participation of boric acid as an additional crosslinking agent and the effect of the amount of the introduced ligand on the surface morphology of the granules and physicochemical properties of the polymeric sorbents have been determined. It has been found that this modification of the polymer matrix promotes an increase in the affinity of the sorption surface and its adsorption capacity to bind glucose in a dynamic mode, as well as high selectivity in comparison with the sorption of its structural analogue, fructose. This can further be used in the development of a method of isolation of glucose from a multicomponent solution and a sorption method of separation of sugars.

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Funding

This work was performed in accordance with a state task, topic no. AAAA-A20-120022090044-2.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004, St. Petersburg, Russia

    I. S. Garkushina, A. S. Panyuta, P. Yu. Morozova & A. A. Osipenko

Authors
  1. I. S. Garkushina
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  2. A. S. Panyuta
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  3. P. Yu. Morozova
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  4. A. A. Osipenko
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Correspondence to I. S. Garkushina.

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Translated by E. Boltukhina

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Garkushina, I.S., Panyuta, A.S., Morozova, P.Y. et al. Selective Sorbents Based on 2-Hydroxyethylmethacrylate and Ethylene Glycol Dimethacrylate Modified with Boric Acid as High-Affinity Ligands for Glucose. Prot Met Phys Chem Surf 59, 843–853 (2023). https://doi.org/10.1134/S2070205123701022

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  • DOI: https://doi.org/10.1134/S2070205123701022

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