Skip to main content
SpringerLink
Log in

The Effect of Chemical Modification of the Surface by Oxysilanes on Changes in the Structural and Phase States of Highly Porous Aluminum Oxyhydroxides at Annealing up to 1200°C

  • NANOSCALE AND NANOSTRUCTURED MATERIALS AND COATINGS
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

Changes in the composition and physicochemical properties of porous monolithic 3D nanostructures of aluminum oxyhydroxides (porous monolithic aluminum oxides, PMAO) chemically modified in methyltrimethoxysilane vapors have been studied by thermal-analysis methods. The conditions of formation and compositions of organosilicon compounds on the PMAO surface have been determined, a high degree of hydrolysis (91%) of the alkoxy groups of the modifier during chemisorption has been confirmed. The dependence of the composition of the porous nanocomposite structure (Al2O3–SiO2) on the conditions of chemical and thermal treatment has been investigated. General changes in the chemical composition of the nanocomposite when using different annealing times in the range from 100 to 1200°C has been described.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

REFERENCES

  1. Golovan, L.A., Timoshenko, V.Yu., and Kashkarov, P.K., Phys.-Usp., 2007, vol. 50, no. 6, p. 595.

    Article  CAS  Google Scholar 

  2. di Costanzo, T., Fomkin, A.A., Frappart, C., Khodan, A.N., Kuznetsov, D.G., Mazerolles, L., Michel, D., Minaev, A.A., Sinitsin, V.A., and Vignes, J.-L., Mater. Sci. Forum, 2004, vols. 453–454, p. 315.

    Article  Google Scholar 

  3. Vignes, J.-L., Frappart, C., di Costanzo, T., Rouchaud, J.-C., Mazerolles, L., and Michel, D., J. Mater. Sci., 2008, vol. 43, p. 1234.

    Article  CAS  Google Scholar 

  4. Khodan, A., Nguyen, T.H.N., Esaulkov, M., Kiselev, M.R., Amamra, M., Vignes, J.-L., and Kanaev, A., J. Nanopart. Res., 2018, vol. 20, p. 194.

    Article  Google Scholar 

  5. Karlash, A.Yu., Skryshevsky, V.A., Khodan, A.N., Kanaev, A.V., and Gayvoronsky, V.Ya., J. Phys. D: Appl. Phys., 2012, vol. 45, p. 365108.

    Article  Google Scholar 

  6. Khodan, A.N., Kopitsa, G.P., Yorov, Kh.E., Baranchikov, A.E., Ivanov, V.K., Feoktystov, A., and Pipich, V., J. Surf. Invest.: X-ray, Synchrotron Neutron Tech., 2018, vol. 12, no. 2, p. 296.

    Article  CAS  Google Scholar 

  7. Martynov, A.G., Bykov, A.V., Gorbunova, Yu.G., Khodan, A.N., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2018, vol. 54, p. 185.

    Article  CAS  Google Scholar 

  8. Yorov, Kh.E., Khodan, A.N., Baranchikov, A.E., Utochnikova, V.V., Simonenko, N.P., Beltiukov, A.N., Petukhov, D.I., Kanaev, A., and Ivanov, V.K., Microporous Mesoporous Mater., 2020, vol. 293, p. 109804.

    Article  CAS  Google Scholar 

  9. Bouslama, M., Amamra, M.C., Jia, Z., Ben Amar, M., Chhor, K., Brinza, O., Abderrabba, M., Vignes, J.-L., and Kanaev, A., ACS Catal., 2012, vol. 2, p. 1884.

    Article  CAS  Google Scholar 

  10. Bouslama, M., Amamra, M.C., Brinza, O., Tieng, S., Chhor, K., Abderrabba, M., Vignes, J.-L., and Kanaev, A., Appl. Catal., A, 2011, vol. 402, nos. 1–2, p. 156.

  11. Mukhin, V.I., Khodan, A.N., Nazarov, M.M., and Shkurinov, A.P., Radiophys. Quantum Electron., 2012, vol. 54, nos. 8–9, p. 591.

    Article  Google Scholar 

  12. Khatim, O., Nguyen, T.H.N., Amamra, M., Museur, L., Khodan, A.N., and Kanaev, A., Acta Mater., 2014, vol. 71, p. 108.

    Article  CAS  Google Scholar 

  13. Katsuki, F., Saguchi, A., Takahashi, W., and Watanabe, J., Jpn. J. Appl. Phys., 2002, vol. 41, p. 4919.

    Article  CAS  Google Scholar 

  14. Inoue, Y. and Takai, O., Plasma Sources Sci. Technol., 1996, vol. 5, p. 339.

    Article  CAS  Google Scholar 

  15. Blaine, B.L. and Hahn, B.K., J. Therm. Anal. Calorim., 1998, vol. 54, p. 695.

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported in part within project no. 22-23-01011 “New Composite Materials and Protective Coatings Based on 3D Porous Corundum Structures Filled with Tungsten or Tungsten Carbides with Increased Stability in High-Energy Gas and Plasma Flows.”

Author information

Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 199071, Moscow, Russia

    A. N. Khodan & M. R. Kiselev

  2. Derzhavin Tambov State University, 390000, Tambov, Russia

    A. N. Khodan

  3. Moscow State University, 119991, Moscow, Russia

    A. V. Bykov

Authors
  1. A. N. Khodan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Bykov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. R. Kiselev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. N. Khodan.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by D. Marinin

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Khodan, A.N., Bykov, A.V. & Kiselev, M.R. The Effect of Chemical Modification of the Surface by Oxysilanes on Changes in the Structural and Phase States of Highly Porous Aluminum Oxyhydroxides at Annealing up to 1200°C. Prot Met Phys Chem Surf 59, 149–154 (2023). https://doi.org/10.1134/S2070205123700193

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205123700193

Keywords:

Search

Navigation