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Adsorption of Highly Soluble Organic Compounds on Diatomite

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Abstract

The adsorption-structural characteristics of diatomite and the surface charge density of diatomite were studied in the solution pH range of 1–14. It was found that the sign of the diatomite surface charge changes from positive (in the pH range of 1–5.5) to negative (in the pH range of 5.5–14) at pHPZC 5.5. The adsorption of an anionic organic compound, eosin H, which is readily soluble in water, on diatomite has been studied. It was found that, with an increase in the pH of the solution and with a decrease in the surface charge density of diatomite, the adsorption of eosin H on diatomite decreases. A probable mechanism for the adsorption of anionic organic compounds on diatomite is proposed.

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Funding

Analytical research was done using equipment of “Research Chemical and Analytical Center NRC “Kurchatov Institute” Shared Research Facilities under project’s financial support by the Russian Federation, represented by The Ministry of Science and Higher Education of the Russian Federation, Agreement no. 075-15-2023-370 dd. 22.02.2023.

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Authors and Affiliations

  1. Institute of Chemical Reagents and Highly Pure Chemical Substances of National Research Centre “Kurchatov Institute”, 107076, Moscow, Russia

    Yu. A. Ubaskina

  2. Mendeleev Russian University of Chemical Technology, 125047, Moscow, Russia

    M. B. Alyokhina

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  1. Yu. A. Ubaskina
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  2. M. B. Alyokhina
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Correspondence to Yu. A. Ubaskina or M. B. Alyokhina.

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Ubaskina, Y.A., Alyokhina, M.B. Adsorption of Highly Soluble Organic Compounds on Diatomite. Prot Met Phys Chem Surf 59, 106–111 (2023). https://doi.org/10.1134/S2070205123700144

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  • DOI: https://doi.org/10.1134/S2070205123700144

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