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Preparation of PCLF/Si–Mg–FA Nanocomposite Coating on Ti-based Alloy: Synthesis, Corrosion behavior and Cytocompatibility

  • NANOSCALE AND NANOSTRUCTURED MATERIALS AND COATINGS
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Abstract

In the present study, polycaprolactone fumarate (PCLF) and polycaprolactone fumarate/silicon and magnesium codoped fluorapatite nanoparticles (PCLF/Si–Mg–FA nanocomposite) were deposited on the surface of Ti–6Al–4V alloy via dip-coating technique. The adhesion test, scanning electron microscopy (SEM) equipped with energy dispersive spectrometer (EDS), X-ray diffraction (XRD) technique, Fourier transform infrared spectroscopy (FTIR), electrochemical, and in vitro biocompatibility evaluations were utilized to characterize coated and uncoated specimens. The results show that uniform nanocomposite coating (thickness of about 6.65 µm) with appropriate adhesion strength and a homogeneous distribution of Si-Mg-FA nanoparticles throughout the PCLF matrix was coated on the substrate. The potentiodynamic polarization and electrochemical impedance tests, in agreement with each other, indicated higher corrosion resistance of nanocomposite coating in comparison to uncoated and PCLF-coated specimens. Cell cytotoxicity (MTT) evaluation and cell adhesion examinations show no toxicity and represent a good cell attachment with flattened sheet morphologies for nanocomposite coating.

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Authors and Affiliations

  1. Department of Materials Engineering, Shahreza Branch, Islamic Azad University, P.O. Box: 86145-311, Shahreza, Iran

    Nasibollah Hatami

  2. Razi Chemistry Research Center (RCRC), Shahreza Branch, Islamic Azad University, Isfahan, Iran

    Nasibollah Hatami

  3. Department of Biomedical Engineering, Islamic Azad University, Central Tehran Branch, P.O. Box 13185/768, Tehran, Iran

    Tahmineh Ahmadi

  4. Department of Materials and Metallurgical Engineering, Abadeh Higher Education Centre, Shiraz University, Abadeh, Iran

    Majid Taghian Dehaghani

  5. Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran

    Hamid Reza Bakhsheshi-Rad

  6. Department of Chemical Engineering Materials Environment, Sapienza University of Rome, Eudossiana 18, 00184, Roma, Italy

    Filippo Berto

Authors
  1. Nasibollah Hatami
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  2. Tahmineh Ahmadi
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  3. Majid Taghian Dehaghani
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  4. Hamid Reza Bakhsheshi-Rad
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  5. Filippo Berto
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Correspondence to Tahmineh Ahmadi or Hamid Reza Bakhsheshi-Rad.

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Hatami, N., Ahmadi, T., Dehaghani, M.T. et al. Preparation of PCLF/Si–Mg–FA Nanocomposite Coating on Ti-based Alloy: Synthesis, Corrosion behavior and Cytocompatibility. Prot Met Phys Chem Surf 59, 191–198 (2023). https://doi.org/10.1134/S2070205122060077

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  • DOI: https://doi.org/10.1134/S2070205122060077

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