Skip to main content

Analysis of CH4 Adsorption Isotherms onto MIL-101 (Cr) Metal-Organic Framework and Its Derivatives with Alkali Ion Dopants

Abstract

In this paper, methane (CH4) adsorption isotherms for metal-organic framework (MOF) adsorbents in the subcritical regions have been reported. Virgin MIL i-101 i-i (Cr) MOF and its derivatives doped with alkali ions, are used to study the impact of alkali dopants on CH4 adsorption isotherms. The CH4 adsorption isotherms have been analyzed by Langmuir, Toth and Dubinin–Astakohv adsorption models to determine the adsorption parameters. It has been observed that the isosteric heat of adsorption diminishes with increasing alkali dopant size, while the induced surface structural heterogeneity increases with increasing alkali dopant size.

This is a preview of subscription content, access via your institution.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

REFERENCES

  1. Konstas, K., Osl, T., Yang, Y., Batten, M., Burke, N., and Hill, A.J., J. Mater. Chem., 2012, vol. 22, p. 16698.

    CAS  Article  Google Scholar 

  2. Thamsiriroj, T., Smyth, H., and Murphy, J.D., Renewable Sustainable Energy Rev., 2011, vol. 15, p. 4642.

    CAS  Article  Google Scholar 

  3. He, Y., Zhou, W., Qian, G., and Chen, B., Chem. Soc. Rev., 2014, vol. 43, p. 5657.

    CAS  Article  Google Scholar 

  4. Waller, M.G., Williams, E.D., Matteson, S.W., and Trabold, T.A., Appl. Energy, 2014, vol. 127, p. 55.

    Article  Google Scholar 

  5. Banfield, G.R. and Fairbairn, G.W., Proc. Inst. Mech. Eng., Part E, 1990, vol. 204, p. 25.

    Google Scholar 

  6. Nwaoha, T.C., Yang, Z., Wang, J., and Bonsall, S., Proc. Inst. Mech. Eng., Part E, 2010, vol. 225, p. 40.

    Google Scholar 

  7. Ma, S. and Zhou, H.C., Chem. Commun., 2010, vol. 46, p. 44.

    CAS  Article  Google Scholar 

  8. Li, J.R., Kuppler, R.J., and Zhou, H.C., Chem. Soc. Rev., 2009, vol. 38, p. 1477.

    CAS  Article  Google Scholar 

  9. Menon, V.C. and Komarneni, S., J. Porous Mater., 1998, vol. 5, p. 43.

    CAS  Article  Google Scholar 

  10. Ruthven, D.M., Principles of Adsorption and Adsorption Processes, New York: Wiley, 1984.

    Google Scholar 

  11. Alcaniz-Monge, J., Lozano-Castello, D., Cazorla-Amoros, D., and Linares-Solano, A., Microporous Mesoporous Mater., 2009, vol. 124, p. 110.

    CAS  Article  Google Scholar 

  12. Wegrzyn, J. and Gurevich, M., Appl. Energy, 1996, vol. 55, p. 71.

    CAS  Article  Google Scholar 

  13. Mason, J.A., Veenstra, M., and Long, J.R., Chem. Sci., 2014, vol. 5, p. 32.

    CAS  Article  Google Scholar 

  14. He, Y., Zhou, W., Krishna, R., and Chen, B., Chem. Commun., 2012, vol. 48, p. 11813.

    CAS  Article  Google Scholar 

  15. Lee, J.S., Jhung, S.H., Yoon, J.W., Hwang, Y.K., and Chang, J.S., J. Ind. Eng. Chem., 2009, vol. 15, p. 674.

    CAS  Article  Google Scholar 

  16. Peng, Y., Krungleviciute, V., Eryazici, I., Hupp, J.T., Farha, O.K., and Yildirim, T., J. Am. Chem. Soc., 2013, vol. 135, p. 11887.

    CAS  Article  Google Scholar 

  17. Duren, T., Sarkisov, L., Yaghi, O.M., and Snurr, R.Q., Langmuir, 2004, vol. 20, p. 2683.

    Article  Google Scholar 

  18. Knyazeva, M.K., Tsivadze, A.Yu., Solovtsova, O.V., Fomkin, A.A., Pribylov, A.A., Shkolin, A.V., et al., Prot. Met. Phys. Chem. Surf., 2019, vol. 55, p. 9.

    CAS  Article  Google Scholar 

  19. Knyazeva, M.K., Tsivadze, A.Yu., Fomkin, A.A., Shkolin, A.V., Solovtsova, O.V., Pribylov, A.A., et al., Prot. Met. Phys. Chem. Surf., 2020, vol. 56, p. 682.

    Article  Google Scholar 

  20. Fomkin, A.A., Tsivadze, A.Yu., Aksyutin, O.E., Ishkov, A.G., Pribylov, A.A., Shkolin, A.V., et al., Prot. Met. Phys. Chem. Surf., 2018, vol. 54, p. 347.

    CAS  Article  Google Scholar 

  21. Matranga, K.R., Myers, A.L., and Glandt, E.D., Chem. Eng. Sci., 1992, vol. 47, p. 1569.

    CAS  Article  Google Scholar 

  22. Anuchin, K.M., Fomkin, A.A., Korotych, A.P., and Tolmachev, A.M., Prot. Met. Phys. Chem. Surf., 2014, vol. 50, p. 173.

    CAS  Article  Google Scholar 

  23. Kayal, S., Sun, B., and Chakraborty, A., Energy, 2015, vol. 91, p. 772.

    CAS  Article  Google Scholar 

  24. Aijaz, A., Karkamkar, A., Choi, Y.J., Tsumori, N., Ronnebro, E., Autrey, T., et al., J. Am. Chem. Soc., 2012, vol. 134, p. 13926.

    CAS  Article  Google Scholar 

  25. Sun, B., Chakraborty, A., Ali, S.M., and Kayal, S., Appl. Therm. Eng., 2016, vol. 93, p. 1175.

    CAS  Article  Google Scholar 

  26. Sircar, S., Adsorption, 2017, vol. 23, p. 121.

    CAS  Article  Google Scholar 

  27. Loh, W.S., Rahman, K.A., Chakraborty, A., Saha, B.B., Choo, Y.S., Khoo, B.C., et al., J. Chem. Eng. Data, 2010, vol. 55, p. 2840.

    CAS  Article  Google Scholar 

  28. Rahman, K.A., Loh, W.S., Yanagi, H., Chakraborty, A., Saha, B.B., Chun, W.G., et al., J. Chem. Eng. Data, 2010, vol. 55, p. 4961.

    CAS  Article  Google Scholar 

  29. Do, D.D., Adsorption Analysis: Equilibria and Kinetics, London: Imperial College Press, 1998.

    Book  Google Scholar 

  30. Dubinin, M.M., Chem. Rev., 1960, vol. 60, p. 235.

    CAS  Article  Google Scholar 

  31. Abdulsalam, J., Mulopo, J., Bada, S.O., and Oboirien, B., ACS Omega, 2020, vol. 5, p. 32530.

    CAS  Article  Google Scholar 

  32. Aristov, Y., Appl. Therm. Eng., 2014, vol. 72, p. 166.

    Article  Google Scholar 

  33. Jagiello, J. and Thommesi, M., Carbon, 2004, vol. 42, p. 1227.

    CAS  Article  Google Scholar 

  34. Amankwah, K.A.G. and Schwarz, J.A., Carbon, 1995, vol. 33, p. 1313.

    CAS  Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sibnath Kayal.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Singh, A., Kayal, S. Analysis of CH4 Adsorption Isotherms onto MIL-101 (Cr) Metal-Organic Framework and Its Derivatives with Alkali Ion Dopants. Prot Met Phys Chem Surf 58, 478–485 (2022). https://doi.org/10.1134/S2070205122030200

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205122030200

Keywords:

  • MIL-101 (Cr) MOF
  • alkali ion dopants
  • methane adsorption isotherms
  • adsorption model equations