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Structure and Oxidation Resistance of Titanium Silicide Ti5Si3–Titanium Binder Powder Composites

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Abstract

In the gasless combustion mode of powder mixtures of titanium and silicon, titanium silicide Ti5Si3–titanium ligament metal–matrix composites were synthesized. The structure of the composites consists of silicide grains separated by titanium binder interlayers with a thickness that depends on the titanium content in the reaction mixtures. During oxidation in air at temperatures up to 1000°C, the predominant oxidation of the titanium binder occurs with the formation of titanium oxide TiO2 (rutile).

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ACKNOWLEDGMENTS

We are grateful to V.P. Krivopalov for help in the synthesis of powders and scale resistance tests.

Funding

This work was carried out under the governmental contract no. FWRW-2021-0005.

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Authors and Affiliations

  1. Institute of Strength Physics and Materials Science, Siberian Branch, Russian Academy of Sciences, 634055, Tomsk, Russia

    G. A. Pribytkov, M. G. Krinitsyn, V. V. Korzhova, I. A. Firsina & E. N. Korosteleva

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  1. G. A. Pribytkov
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  2. M. G. Krinitsyn
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  3. V. V. Korzhova
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  4. I. A. Firsina
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  5. E. N. Korosteleva
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Correspondence to G. A. Pribytkov.

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Pribytkov, G.A., Krinitsyn, M.G., Korzhova, V.V. et al. Structure and Oxidation Resistance of Titanium Silicide Ti5Si3–Titanium Binder Powder Composites. Prot Met Phys Chem Surf 58, 70–75 (2022). https://doi.org/10.1134/S2070205122010166

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  • DOI: https://doi.org/10.1134/S2070205122010166

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