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Amide Compounds as Corrosion Inhibitors for Carbon Steel in Acidic Environment

  • PHYSICOCHEMICAL PROBLEMS OF MATERIALS PROTECTION
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Abstract

The inhibiting effect of some amide compounds in a drug form in 1 M HCl solutions on carbon steel has been studied using some chemical and electrochemical techniques as mass reduction (MR), potentiodynamic polarization (PDP), electrochemical impedance spectroscopy measurements (EIS), electrochemical frequency modulation (EFM) techniques. The inhibition efficiency of carbon steel corrosion increases by increasing inhibitor dose. The effect of temperature on the corrosion rate was investigated by mass reduction method as the inhibition efficiency decreases by raising the temperature range. The thermodynamic and adsorption parameters were calculated and discussed. The adsorption of these compounds obeyed Langmuir adsorption isotherm. In addition, surface examination and morphological studies were applied towards the inhibited carbon steel sample by scanning electron microscopy (SEM), energy dispersed X-ray (EDX) and Atomic force microscopy (AFM) techniques.

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REFERENCES

  1. Elachouri, M., Infante, M.R., Izqnierdo, F., Kerti, S., Gonttaya, H.M., and Nciri, B., Corros. Sci., 2001, vol. 43, p. 19.

    Article  CAS  Google Scholar 

  2. Fouda, A.S., El-Azaly, A.H., Awad, R.S., and Ahmed, A.M., Int. J. Electrochem. Sci., 2014, vol. 9, p. 1117.

    Google Scholar 

  3. Liao, L.L, Mo, S., Lei, J.L., Luo, H.Q., and Bing, N., J. Colloid Interface Sci., 2016, vol. 474, p. 68.

    Article  CAS  Google Scholar 

  4. Abdallah, M., Mater. Chem. Phys., 2003, vol. 82, p. 786.

    Article  CAS  Google Scholar 

  5. Elewady, G.Y., Int. J. Electrochem. Sci., 2008, vol. 3, p. 1149.

    CAS  Google Scholar 

  6. Zaafarany, I. and Abdallah, M., Int. J. Electrochem. Sci., 2010, vol. 5, p. 18.

    CAS  Google Scholar 

  7. Yurt, A., Balaban, A., Ustün Kandemir, S., and Bereket, G., Mater. Chem. Phys., 2004, vol. 85, p. 420.

    Article  CAS  Google Scholar 

  8. Ali, S.A., Al-Muallema, H.A., Rahman, S.U., and Saeed, M.T., Corros. Sci., 2008, vol. 50, p. 3070.

    Article  CAS  Google Scholar 

  9. Ju, H., Kai, Z.P., and Li, Y., Corros. Sci., 2008, vol. 50, p. 865.

    Article  CAS  Google Scholar 

  10. Gopi, D.I., Govindaraju, K., and Kavhith, L., J. Appl. Electrochem., 2010, vol. 40, p. 1349.

    Article  CAS  Google Scholar 

  11. Migahed, M.A., Abdul-Raheim, A.M, Atta, A.M., and Brostow, W., Mater. Chem. Phys., 2010, vol. 121, p. 208.

    Article  CAS  Google Scholar 

  12. Singh, A. and Quraish, M., J. Appl. Electrochem., 2010, vol. 40, p. 1293.

    Article  CAS  Google Scholar 

  13. Obot, I.B., Obi-Egbedi, N.O., and Odozi, N.W., Corros. Sci., 2010, vol. 52, p. 923.

    Article  CAS  Google Scholar 

  14. Obot, I.B. and Obi-Egbedi, N.O., Mater. Chem. Phys., 2010, vol. 122, p. 325.

    Article  CAS  Google Scholar 

  15. Ashassi-Sorkhabi, H. and Es’haghi, M., J. Solid State Electrochem., 2009, vol. 13, p. 1297.

    Article  CAS  Google Scholar 

  16. Mahgoub, F.M., Abdel-Nabey, B.A, and El-Samadisy, Y.A., Mater. Chem. Phys., 2010, vol. 120, p. 104.

    Article  CAS  Google Scholar 

  17. Zerg, B.I., Sfair, M., Tale, M., Hammouti, B., Touhami, M.E., Radi, S., and Rais, Z., J. Appl. Electrochem., 2010, vol. 40, p. 1575.

    Article  CAS  Google Scholar 

  18. Hermas, A.A., Morad, M.S., and. Wahdan, M.H., J. Appl. Electrochem., 2004, vol. 34, p. 95.

    Article  CAS  Google Scholar 

  19. Alonejad, S., Naderi, R., and Mahdauian, M., Prog. Org. Coat., 2016, vol. 101, p. 142.

    Article  CAS  Google Scholar 

  20. Abdallah, M., Eletre, A.Y., Soliman, M.G., and Mabrouk, E.M., Anti-Corros. Methods Mater., 2006, vol. 53, p. 123.

    Article  CAS  Google Scholar 

  21. Abdallah, M., Corros. Sci., 2003, vol. 44, p. 717.

    Article  Google Scholar 

  22. Galal, A., Alta, N.F., and Al Hassan, M.H.S., Mater. Chem. Phys., 2005, vol. 89, p. 28.

    Article  CAS  Google Scholar 

  23. Fouda, A.S., Elmorsi, M.A., and Abou-Elmagd, B.S., Pol. J. Chem. Technol., 2017, vol. 19, p. 95.

    Article  CAS  Google Scholar 

  24. Fouda, A.S., EL-Ewady, G., and Ali, A.H., Green Chem. Lett. Rev., 2017, vol. 10, p. 88.

    Article  CAS  Google Scholar 

  25. Abdallah, M., Helal, E.A., and Fouda, A.S., Corros. Sci., 2006, vol. 48, p. 1639.

    Article  CAS  Google Scholar 

  26. Özcan, M.O., Solmaz, R., Kardas, G., Dehri, İ., Colloids Surf., A, 2008, vol. 325, p. 57.

    Article  CAS  Google Scholar 

  27. Kermannezhad, K., Chermahini, A.N., Momeni, M.M., and Rezaei, B., Chem. Eng. J., 2016, vol. 306, p. 849.

    Article  CAS  Google Scholar 

  28. Abd El-Maksoud, S.A. and Fouda, A.S., Mater. Chem. Phys., 2005, vol. 84, p.76e.

    Google Scholar 

  29. Diamanti-Kandarakis, E., Curr. Pharm. Des., 1999, vol. 5, p. 707.

    CAS  Google Scholar 

  30. Seeherman, R., Del. Med. J., 1957, vol. 29, p. 265.

    CAS  Google Scholar 

  31. Binnig, G., Quate, C.F., and Gerber, Ch., Phys. Rev. Lett., 1986, vol. 56, p. 930.

    Article  CAS  Google Scholar 

  32. Allam, N.K., Appl. Surf. Sci., 2007, vol. 253, p. 4457.

    Article  CAS  Google Scholar 

  33. EL-Din, M.N. and Khamis, E., J. Ind. Eng. Chem., 2015, vol. 24, p. 342.

    Article  CAS  Google Scholar 

  34. Martinez, S. and Stern, I., Appl. Surf. Sci., 2002, vol. 199, p. 83.

    Article  CAS  Google Scholar 

  35. Saliyan, V.R. and Adhikari, A.V., Bull. Mater. Sci., 2008, vol. 31, p. 699.

    Article  CAS  Google Scholar 

  36. Saleh, M.M. and Atia, A.A., J. Appl. Electrochem., 2006, vol. 36, p. 899.

    Article  CAS  Google Scholar 

  37. Yurt, A., Bereket, G., Kivrak, A., Balaban, A., and Erk, B., J. Appl. Electrochem., 2005, vol. 35, p. 1025.

    Article  CAS  Google Scholar 

  38. Durnie, W., Marco, R.D, Jefferson, A., and Kinsella, B., J. Electrochem. Soc., 1999, vol. 146, p. 1751.

    Article  CAS  Google Scholar 

  39. El Achouri, M., Kertit, S., Gouttaya, H.M., Nciri, B., Bensouda, Y, Perez, L., Infante, M.R., and Elkacemi K., Prog. Org. Coat., 2001, vol. 43, p. 267.

    Article  CAS  Google Scholar 

  40. Trabanelli, G., Montecelli, C., Grassi, V., and Frignani, A., Cem. Concr. Res., 2005, vol. 35, p. 1804.

    Article  CAS  Google Scholar 

  41. Trowsdate, A.J., Noble, B., Haris, S.J., Gibbins, I.S.R., Thomson, G.E., and Wood, G.C., Corros. Sci., 1996, vol. 38, p. 177.

    Article  Google Scholar 

  42. Mertens, S.F., Xhoffer, C., Decooman, B.C., and Temmerman, E., Corrosion, 1997, vol. 53, p. 381.

    Article  CAS  Google Scholar 

  43. Kus, E. and Mansfeld, F., Corros. Sci., 2006, vol. 48, p. 965.

    Article  CAS  Google Scholar 

  44. Bentiss, F., Jama, C., Mernari, B., Attari, H.E., Kadi, L.E., Ebrini, M.L., Traisnel, M., and Lagrenee, M., Corros. Sci., 2009, vol. 51, p. 1628.

    Article  CAS  Google Scholar 

  45. Caigman, G.A., Metcalf, S.K., and Holt, E.M., J. Chem. Crystallogr., 2000, vol. 30, p. 415.

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Mansoura University, 35516, Mansoura, Egypt

    A. S. Fouda & Dina Mansour

  2. Department of Chemistry, Faculty of Science, Tanta University, 31527, Tanta, Egypt

    H. S. El-Desoky & M. M. Abdel-Galeil

Authors
  1. A. S. Fouda
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  2. H. S. El-Desoky
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  3. M. M. Abdel-Galeil
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  4. Dina Mansour
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Correspondence to A. S. Fouda.

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Fouda, A.S., El-Desoky, H.S., Abdel-Galeil, M.M. et al. Amide Compounds as Corrosion Inhibitors for Carbon Steel in Acidic Environment. Prot Met Phys Chem Surf 58, 151–167 (2022). https://doi.org/10.1134/S2070205122010105

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  • DOI: https://doi.org/10.1134/S2070205122010105

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