Skip to main content
SpringerLink
Log in

Electrochemical and QTAIM Evaluation of Anticorrosive Properties of bis(1,4-Isomeric Pyridine Thiosemicarbazides) in Acidic Media

  • PHYSICOCHEMICAL PROBLEMS OF MATERIALS PROTECTION
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

bis(1,4-Isomeric pyridine thiosemicarbazides) (P2) was synthesized and the protection performance of P2 on the corrosion of AA1005 alloy in acidic solution was evaluated using potentiodynamic polarization and electrochemical impedance spectroscopy. Inhibition efficiency of prepared inhibitor increases as inhibitor concentration increases. It was shown that the adsorption of P2 on the surface of the aluminum takes place through both physical and chemical adsorption. Experimental results prove that inhibitor is of mixed type. The best fit to the experimental results was obtained using Langmuir adsorption isotherm. Meanwhile, quantum chemical calculations give evidence to experimental results. Analysis of the QTAIM results shows that the sulfur and oxygen atoms have important roles in local charge and energy transfer in parallel/ perpendicular directions of these molecular systems. All the studied methods are showing good correlation with each other.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. Rashid, K.H. and Khadom, A.A., Korean J. Chem. Eng., 2019, vol. 36, p. 1350.

    Article  CAS  Google Scholar 

  2. Yüce, A.O., Mert, B.D., Kardaş, G., and Yazıcı, B., Corros. Sci., 2014, vol. 83, p. 310.

    Article  Google Scholar 

  3. Daoud, D., Douadi, T., Hamani, H., Chafaa, S., and Al-Noaimi, M., Corros. Sci., 2015, vol. 94, p. 21.

    Article  CAS  Google Scholar 

  4. Hegazy, M., El-Tabei, A., Bedair, A., and Sadeq, M., RSC Adv., 2015, vol. 5, p. 64633.

    Article  CAS  Google Scholar 

  5. Ehsani, A., Safari, R., Shiri, H.M., and Yazdanpanah, A.M., Prot. Met. Phys. Chem. Surf., 2019, vol. 55, no. 3, p. 371.

    Article  Google Scholar 

  6. Ehsani, A. and Mohammad Shiri, H., Prot. Met. Phys. Chem. Surf., 2016, vol. 52, no. 2, p. 347.

    Article  Google Scholar 

  7. Glasgow, I., Rostron, A., and Thomson, G., Corros. Sci., 1966, vol. 6, p. 469.

    Article  CAS  Google Scholar 

  8. Lgaz, H., Bhat, K.S., Salghi, R., Jodeh, S., Algarra, M., Hammouti, B., Ali, I.H., and Essamri, A., J. Mol. Liq., 2017, vol. 238, p. 71.

    Article  CAS  Google Scholar 

  9. Singh, P., Srivastava, V., and Quraishi, M., J. Mol. Liq., 2016, vol. 216, p. 164.

    Article  CAS  Google Scholar 

  10. Kovačević, N. and Kokalj, A., Corros. Sci., 2011, vol. 53, p. 909.

    Article  Google Scholar 

  11. Shukla, S.K. and Quraishi, M., Corros. Sci., 2009, vol. 51, p. 1990.

    Article  CAS  Google Scholar 

  12. Chaouiki, A., Lgaz, H., Zehra, S., Salghi, R., Chung, I.-M., El Aoufir, Y., Bhat, K.S., Ali, I.H., Gaonkar, S.L., and Khan, M.I., J. Adhes. Sci. Technol., 2019, vol. 33, p. 921.

    Article  CAS  Google Scholar 

  13. He, T., Emori, W., Zhang, R.-H., Okafor, P.C., Yang, M., and Cheng, C.-R., Bioelectrochemistry, 2019, vol. 130, p. 107332.

    Article  CAS  Google Scholar 

  14. Ituen, E., Mkpenie, V., Moses, E., and Obot, I., Bioelectrochemistry, 2019, vol. 129, p. 42.

    Article  CAS  Google Scholar 

  15. Wang, Q., Tan, B., Bao, H., Xie, Y., Mou, Y., Li, P., Chen, D., Shi, Y., Li, X., and Yang, W., Bioelectrochemistry, 2019, vol. 128, p. 49.

    Article  CAS  Google Scholar 

  16. Pakiet, M., Kowalczyk, I., Leiva Garcia, R., Moorcroft, R., Nichol, T., Smith, T., Akid, R., and Brycki, B., Bioelectrochemistry, 2019, vol. 128, p. 252.

    Article  CAS  Google Scholar 

  17. Rajan, J.P., Shrivastava, R., and Mishra, R.K., Prot. Met. Phys. Chem. Surf., 2017, vol. 53, p. 1161.

    Article  CAS  Google Scholar 

  18. Palomar-Pardavé, M., Romero-Romo, M., Herrera-Hernández, H., Abreu-Quijano, M., Likhanova, N.V., Uruchurtu, J., and Juárez-García, J., Corros. Sci., 2012, vol. 54, p. 231.

    Article  Google Scholar 

  19. Mobinikhaledi, A., Foroughifar, N., Kalhor, M., Ebrahimi, S., and Bodaghi Fard, M.A., Phosphorus, Sulfur Silicon Relat. Elem., 2011, vol. 186, p. 67.

    Article  CAS  Google Scholar 

  20. Ehsani, A., Rezaei, Z., Agah, A., Mohammad Shiri, H., and Heidari, A.A., Microchem. J., 2021, vol. 165, p. 106074.

    Article  CAS  Google Scholar 

  21. Ehsani, A., Esfahaniha, M., Khodaei Kahriz, P., Safari, R., and Parsimehr, H.R., Surf. Interfaces, 2021, vol. 22, p. 100817.

    Article  CAS  Google Scholar 

  22. Ehsani, A., Moftakhar, M., and Karimi, F., J. Energy Storage, 2021, vol. 35, p. 102291.

    Article  Google Scholar 

  23. Ehsani, A., Mirtamizdoust, B., Karimi, F., Bigdeloo, M., and Parsimehr, H., Plast., Rubber Compos., 2021, vol. 50, no. 4, p. 172.

    Article  CAS  Google Scholar 

  24. Ehsani, A., Mahjani, M., and Jafarian, M., Turk. J. Chem., 2011, vol. 35, no. 5, p. 735.

    CAS  Google Scholar 

  25. Mahjani, M.G., Ehsani, A., and Jafarian, M., Synth. Met., 2010, vol. 160, p. 1252.

    Article  CAS  Google Scholar 

  26. Ehsani, A., Parsimehr, H., Nourmohammadi, H., Safari, R., and Doostikhah, S., Polym. Compos., 2019, vol. 40, no. 12, p. 4629.

    Article  CAS  Google Scholar 

  27. Ehsani, A., Mahjani, M.G., Nasseri, M., and Jafarian, M., Anti-Corros. Methods Mater., 2014, vol. 61, p. 146.

    Article  CAS  Google Scholar 

  28. Naghdi, S., Jaleh, B., and Ehsani, A., Bull. Chem. Soc. Jpn., 2015, vol. 88, p. 722.

    Article  CAS  Google Scholar 

  29. Ehsani, A., Mahjani, M.G., Moshrefi, R., Mostaanzadeh, H., and Shabani, J., RSC Adv., 2014, vol. 4, no. 38, p. 20031.

    Article  CAS  Google Scholar 

  30. Beikmohammadi, M., Fotouhi, L., Ehsani, A., and Naseri, M., Solid State Ionics, 2018, vol. 342, p. 138.

    Article  Google Scholar 

  31. Ehsani, A., Mahjani, M., Hosseini, M., Safari, R., Moshrefi, R., and Shiri, H.M., J. Colloid Interface Sci., 2017, vol. 490, p. 444.

    Article  CAS  Google Scholar 

  32. Ehsani, A., Heidari, A.A., and Sajedi, M., Chem. Rec., 2020, vol. 20, no. 6, p. 467.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Qom, Qom, Iran

    A. Ehsani & R. Safari

  2. Department of Chemistry, Payame Noor University, Tehran, Iran

    Z. Samiee & M. Kalhor

Authors
  1. A. Ehsani
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. Samiee
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Kalhor
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. Safari
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Ehsani.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ehsani, A., Samiee, Z., Kalhor, M. et al. Electrochemical and QTAIM Evaluation of Anticorrosive Properties of bis(1,4-Isomeric Pyridine Thiosemicarbazides) in Acidic Media. Prot Met Phys Chem Surf 58, 168–175 (2022). https://doi.org/10.1134/S2070205122010087

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205122010087

Keywords:

Search

Navigation