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The MIL-125 Metal–Organic Framework Structure for Adsorption-Based Accumulation of Methane and Hydrogen

Abstract

A MIL-125 metal–organic framework structure was synthesized from titanium and 1, 4-benzenedicarboxylic acid. The specific micropore volume of the synthesized sample was found to be W0 = 0.59 cm3/g, and the specific BET surface area was SBET = 1320 m2/g. Analysis of the synthesized material revealed the possibility of its application for accumulating energetically important gases: methane and hydrogen. The adsorption of hydrogen and methane on MIL-125 was experimentally studied within the temperature range of 77−293 K for hydrogen and 213−293 K for methane at absolute pressures up to 1.5 bar. The high heats of methane and hydrogen adsorption on the synthesized sample of about 26 and 14 kJ/mol were evaluated. It was found that, due to narrow pores, the adsorbent may be effective in accumulating methane at high temperatures. MIL-125 exhibited the best adsorption performance for hydrogen. At the temperature of 77 K and atmospheric pressure, the sample can accumulate up to 2.3 wt % hydrogen.

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ACKNOWLEDGMENTS

MOF was synthesized in the laboratory of Photoactive Nanocomposite Materials of St. Petersburg State University within the framework of a project of St. Petersburg State University, pure ID: 51124539.

Funding

This work was carried out in the framework of state assignment no. 0081-2019-0018, Fundamental physicochemical laws of adsorption, adsorption separation, adsorption-electrochemical ion-exchange processes in nanoporous materials and the basis of targeted synthesis of new adsorbents.

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Correspondence to O. V. Solovtsova.

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Translated by E. Khozina

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Solovtsova, O.V., Maevsky, A.V., Poloneeva, D.Y. et al. The MIL-125 Metal–Organic Framework Structure for Adsorption-Based Accumulation of Methane and Hydrogen. Prot Met Phys Chem Surf 57, 672–679 (2021). https://doi.org/10.1134/S2070205121040225

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