Skip to main content
SpringerLink
Log in

Synthesis and Electrochemical Behavior of Composite Materials Based on Polyaniline and Manganese Compounds on Activated Graphite Foil

  • NANOSCALE AND NANOSTRUCTURED MATERIALS AND COATINGS
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

Composite electroactive coatings (CEACs) are prepared on the basis of polyaniline (PANI) and manganese compounds (MnOx) by potentiodynamic electrodeposition on activated graphite foil using aniline sulfate solutions in 1 M H2SO4. Manganese ions are incorporated into the CEACs in several ways. The electrochemical behavior of prepared CEACs is fundamentally similar to that of pure PANI in acidic aqueous solutions. However, in the presence of incorporated manganese oxide compounds, the electrochemical capacitance nearly doubles at high current loads (up to 2.0 mA cm–2), while the stability during continuous cycling improves. X-ray photoelectron spectroscopy studies of the manganese oxide compounds incorporated into CEACs reveal their amorphous nature and that manganese atoms are present in CEACs in several oxidation states.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. Prasad, K.R. and Munichandraiah, N., J. Electrochem. Soc., 2002, vol. 149, p. A1393.

    Article  CAS  Google Scholar 

  2. Prasad, K.R. and Munichandraiah, N., J. Power Sources, 2002, vol. 112, p. 443.

    Article  CAS  Google Scholar 

  3. Fusalba, F., Gouerec, P., Villers, D., and Belanger, D., J. Electrochem. Soc., 2001, vol. 148, p. A1.

    Article  CAS  Google Scholar 

  4. Prasad, K.R. and Miura, N., Electrochem. Solid-State Lett., 2004, vol. 7, no. 11, p. A425.

    Article  CAS  Google Scholar 

  5. Dai, Y., Chen, L., Babayan, V., Cheng, Q., Saha, P., Jiang, H., and Li, C., J. Mater. Chem. A, 2015, vol. 3, p. 21337. https://doi.org/10.1039/c5ta06958k

    Article  CAS  Google Scholar 

  6. Xiea, Yi., Yanga, Ch., Chena, P., Yuana, D., and Guoa, K., J. Power Sources, 2019, vol. 425, p. 1.

    Article  Google Scholar 

  7. Dai, Yi., Chen, L., Babayan, V., Cheng, Q., Saha, P., Jiang, H., and Li, Ch., J. Mater. Chem., A, 2015, vol. 3, p. 21337.

    Article  CAS  Google Scholar 

  8. Feng, X., Li, Y., Chen, G., Liu, Z., Ning, X., Hu, A., Tang, Q., Chen, X., Shen, F., Pankratov, D., and Chi, Q., Curr. Opin. Electrochem., 2017, vol. 4, p. 133.

    Article  Google Scholar 

  9. Radhamani, A.V., Surendra, M.K., and Ramachandra Rao, M.S., Appl. Surf. Sci., 2018, vol. 450, p. 209. https://doi.org/10.1016/j.apsusc.2018.04.081

    Article  CAS  Google Scholar 

  10. Jaidev Jafri, R.I., Kumar, M.A., and Ramaprabhu, S., J. Mater. Chem., 2011, vol. 21, p. 17601.

    Article  Google Scholar 

  11. Hou, D., Tao, H., Zhu, X., and Li, M., Appl. Surf. Sci., 2017, vol. 419, p. 580. https://doi.org/10.1016/j.apsusc.2017.05.080

    Article  CAS  Google Scholar 

  12. Sun, L.-J., Liu, X.-X., Lau Kim, K.-T., Chen, L., and Gu, W.-M., Electrochim. Acta, 2008, vol. 53, p. 3036.

    Article  CAS  Google Scholar 

  13. Abalyaeva, V.V., Nikolaeva, G.V., Dremova, N.N., Knerel’man, E.I., Davydova, G.I., Efimov, O.N., and Ionov, S.G., Prot. Met. Phys. Chem. Surf., 2019, vol. 55, no. 2, pp. 321–329. https://doi.org/10.1134/S2070205119020023

    Article  CAS  Google Scholar 

  14. Abalyaeva, V.V., Nikolaeva, G.V., Kabachkov, E.N., and Efimov, O.N., Russ. J. Electrochem., 2019, vol. 55, no. 8, p. 745. https://doi.org/10.1134/S1023193519080020

    Article  CAS  Google Scholar 

  15. Hu, Ch.-Ch. and Wang, Ch.-Ch., J. Electrochem. Soc., 2003, vol. 150, no. 8, p. A1079.

    Article  CAS  Google Scholar 

  16. Chigane, M. and Ishikawa, M., J. Electrochem. Soc., 2000, vol. 47, p. 2246.

    Article  Google Scholar 

  17. Goswami, S., Maitia, U.N., Maitia, S., Nandy, S., Mitrab, M.K., Chattopadhyay, K.K., Zhang, X., Ji, L., Zhang, S., and Yang, W., J. Power Sources, 2007, vol. 173, p. 1017.

    Article  Google Scholar 

  18. Cruz-Silva, R., Romero-Garcia, J., Angulo-Sánchez, J.L., Flores-Loyola, E., and Diaz, J.A., Polymer, 2004, vol. 45, p. 4711.

    Article  CAS  Google Scholar 

Download references

Funding

The work was performed in accordance with state assignment no. 0089-2019-0010 and supported in part within the framework of state assignment no. АААА-А19-119061890019-5. Part of this study was carried out using the facilities of the Analytical Center for Collective Use of the Institute of Problems of Chemical Physics, Russian Academy of Sciences, and the Scientific Center in Chernogolovka, Russian Academy of Sciences.

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    V. V. Abalyaeva, O. N. Efimov, N. N. Dremova & E. N. Kabachkov

  2. Scientific Center in Chernogolovka, Russian Academy of Sciences, Chernogolovka, Russia

    E. N. Kabachkov

Authors
  1. V. V. Abalyaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. N. Efimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. N. Dremova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. N. Kabachkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Abalyaeva.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by A. Kukharuk

Abbreviations used: CEAC, composite electroactive coating; PANI, polyaniline; SEM, scanning electron microscopy; XPS, X-ray photoelectron spectroscopy.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Abalyaeva, V.V., Efimov, O.N., Dremova, N.N. et al. Synthesis and Electrochemical Behavior of Composite Materials Based on Polyaniline and Manganese Compounds on Activated Graphite Foil. Prot Met Phys Chem Surf 57, 500–506 (2021). https://doi.org/10.1134/S2070205121030023

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205121030023

Keywords:

Search

Navigation