Skip to main content
SpringerLink
Log in

The Role of Echium Angustifolium Mill Extract in The Corrosion Mitigation of Carbon Steel in Sulfuric Acid Solution

  • PHYSICOCHEMICAL PROBLEMS OF MATERIALS PROTECTION
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

The role of Echium angustifolium Mill extract for advancing corrosion resistance of carbon steel in 1.0 M H2SO4 solution was discussed in this research. Weight loss (WL), open circuit potential (OCP), potentiodynamic polarization (PP) and electrochemical impedance spectroscopy (EIS) methods were applied to monitor the corrosion behavior of carbon steel in 1.0 M H2SO4 solution. The influence of temperature was studied from 25–45°C and some thermodynamic parameters were computed. The Surface morphology of the carbon steel surface was examined via different techniques. These measurements confirmed that the existence of Echium angustifolium Mill extract reduces the corrosion rate (CR), corrosion current densities (icorr), and double layer capacities (Cdl), simultaneously increase the polarization resistance (Rp) values. Tafel plots observed that the Echium angustifolium Mill extract play as a mixed type inhibitor. Electrochemical impedance confirmed that the existence of the applicable extract reduced the double layer capacitance and enhanced the charge transfer resistance. The extract molecules adsorbed on the metal surface follow Langmuir adsorption isotherm. The gained data confirmed that the inhibition efficiency (η%) increase with the increase of extract concentration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.
Fig. 10.
Fig. 11.
Fig. 12.
Fig. 13.
Fig. 14.
Fig. 15.

Similar content being viewed by others

REFERENCES

  1. Deyab, M.A. and Abd El-Rehim, S.S., Corros. Sci., 2012, vol. 65, p. 309.

    Article  CAS  Google Scholar 

  2. Deyab, M.A. and Abd El-Rehim, S.S., Int. J. Electrochem. Sci., 2013, vol. 8, p. 12613.

    CAS  Google Scholar 

  3. Oddo, J.E. and Tomson, M.B., J. Pet. Technol., 1982, vol. 34, p. 1583.

    Article  CAS  Google Scholar 

  4. Ridd, B., Blakset, T.J., and Queen, D., Proc. NACE Int. Conference CORROSION/98, San Diego, CA, 1998, paper no. 78.

  5. Solomon, M.M., Umoren, S.A., Udosoro, I.I., and Udoh, A.P., Corros. Sci., 2010, vol. 52, p. 1317.

    Article  CAS  Google Scholar 

  6. Lahhit, N., Bouyanzer, A., Desjobert, J.M., et al., Port. Electrochim. Acta, 2010, vol. 29, p. 127.

    Article  CAS  Google Scholar 

  7. Vijayalakshmi, P.R., Rajalakshmi, R., and Subhashini, S., Port. Electrochim. Acta, 2011, vol. 29, p. 9.

    Article  CAS  Google Scholar 

  8. Anthony, N., Malarvizhi, E., Maheshwari, P., et al., Indian J. Chem. Technol., 2004, vol. 11, p. 346.

    CAS  Google Scholar 

  9. Fouda, A.S., Mostafa, H.A., El-Taib Haekel, F., and Elewady, G.Y., Corros. Sci., 2005, vol. 47, p. 1988.

    Article  CAS  Google Scholar 

  10. Ahamd, I. and Quraishi, M.A., Corros. Sci., 2010, vol. 52, p. 651.

    Article  CAS  Google Scholar 

  11. Singh, A.K. and Quraishi, M.A., Corros. Sci., 2010, vol. 52, pp. 152–160.

    Article  CAS  Google Scholar 

  12. Abdel Hameed, R.S., Al-Shafey, H.I., Abul Magd, A.S., and Shehata, H.A., J. Mater. Environ. Sci., 2012, vol. 3, p. 294.

    CAS  Google Scholar 

  13. Li, X., Deng, S., Mu, G., Fu, H., and Yang, F., Corros. Sci., 2008, vol. 50, p. 420.

    Article  CAS  Google Scholar 

  14. Abd El Rehim, S.S., Hassan, H.H., and Amin, M.A., Corros. Sci., 2004, vol. 46, p. 5.

    Article  CAS  Google Scholar 

  15. Abdel-Gaber, A.M., Khamis, E., Abo-El-Dahab, H., and Adeel, Sh., Mater. Chem. Phys., 2008, vol. 109, p. 297.

    Article  CAS  Google Scholar 

  16. Abiola, O.K. and James, A.O., Corros. Sci., 2010, vol. 52, p. 661.

    Article  CAS  Google Scholar 

  17. James, A.O. and Akaranta, O., Res. J. Chem. Sci., 2011, vol. 1, p. 31.

    CAS  Google Scholar 

  18. Fouda, Abd El-Aziz S., El-Katori, Emad E., and Al-Mhyawi, S., Int. J. Electrochem. Sci., 2017, vol. 12, p. 9104.

  19. Aboia, O.K. and James, A.O., Corros. Sci., 2010, vol. 52, p. 661.

    Article  CAS  Google Scholar 

  20. Saratha, R. and Vasudha, V.G., E-J. Chem., 2010, vol. 7, p. 677.

    Article  CAS  Google Scholar 

  21. El-Rokh, A.R., Negm, A., El-Shamy, M., El-Gindy, M., and Abdel-Mogib, M., Phytochemistry, 2018, vol. 149, p. 155.

    Article  CAS  Google Scholar 

  22. Kamis, E.T., Int. J. Adv. Sci. Tech. Res., 1990, vol. 46, p. 476.

    Google Scholar 

  23. El-Rehim, S.S.A., Ibrahim, M.A.M., and Khaled, K.F., J. Appl. Electrochem., 1999, vol. 29, p. 593.

    Article  CAS  Google Scholar 

  24. Fouda, A.S., El-Desoky, A.M., and Ead, D.M., Int. J. Electrochem. Sci., 2013, vol. 8, p. 8823.

    CAS  Google Scholar 

  25. Benali, O. and Ouazene, M., Arabian J. Chem., 2011, vol. 4, p. 443.

    Article  CAS  Google Scholar 

  26. Larabi, L., Benali, O., and Harek, Y., Mater. Lett., 2007, vol. 61, p. 3287.

    Article  CAS  Google Scholar 

  27. Larabi, L., Harek, Y., Benali, O., and Ghalem, S., Prog. Org. Coat., 2005, vol. 54, p. 256.

    Article  CAS  Google Scholar 

  28. Hassan, R.M. and Zaafarany, I.A., Materials, 2013, vol. 6, p. 2436.

    Article  CAS  Google Scholar 

  29. Khaled, K.F., Samardzija, K.B., and Hackerman, N., J. Appl. Electrochem., 2004, vol. 34, p. 697.

    Article  CAS  Google Scholar 

  30. Singh, A.K., Singh, A.K., and Ebenso, E.E., Int. J. Electrochem. Sci., 2014, vol. 9, p. 352.

    Google Scholar 

  31. Benabdellah, M., Aouniti, A., Dafali, A., et al., Appl. Surf. Sci., 2006, vol. 252, p. 8341.

    Article  CAS  Google Scholar 

  32. Ruhi, G., Modi, O.P., and Dhawan, S.K., Synth. Met., 2015, vol. 200, p. 24.

    Article  CAS  Google Scholar 

  33. Diggle, J.W., Downie, T.C., and Goulding, C.W., J. Electrochem. Soc., 1969, vol. 116, p. 1347.

    Article  CAS  Google Scholar 

  34. El Haleem, S.M.A., El Wanees, S.A., El Aal, E.E.A., and Farouk, A., Corros. Sci., 2013, vol. 68, p. 1.

    Article  CAS  Google Scholar 

  35. Fouda, A.S., Mahmoud, W.M., and Elawayeb, K.M.A., Prot. Met. Phys. Chem. Surf., 2017, vol. 53, p. 139.

    Article  CAS  Google Scholar 

  36. Migahed, M.A., Azzam, E.M.S., and Morsy, S.M.I., Corros. Sci., 2009, vol. 51, p. 1636.

    Article  CAS  Google Scholar 

  37. Singh, A.K., Singh, A.K., and Ebenso, E.E., Int. J. Electrochem. Sci., 2014, vol. 9, p. 352.

    Google Scholar 

  38. Bentiss, F., Lebrini, M., and Lagrenee, M., Corros. Sci., 2005, vol. 47, p. 2915.

    Article  CAS  Google Scholar 

  39. Silverman, D.C. and Carrico, J.E., Corrosion, 1988, vol. 44, p. 280.

    Article  CAS  Google Scholar 

  40. Bayol, E., Kayakirilmaz, K., and Erbil, M., Mater. Chem. Phys., 2007, vol. 104, p. 74.

    Article  CAS  Google Scholar 

  41. Benalli, O., Larabi, L., Traisnel, M., Gengembra, L., and Harek, Y., Appl. Surf. Sci., 2007, vol. 253, p. 6130.

    Article  CAS  Google Scholar 

  42. Ramachandran, S., Tsai, M., Blanco, M., Chen, H., and Tang, W.A., Electrochim. Acta, 2008, vol. 53, p. 3484.

    Article  CAS  Google Scholar 

  43. Fouda, A.S. and Ibrahim, A.R., Prot. Met. Phys. Chem. Surf., 2018, vol. 54, p. 1194.

    Article  CAS  Google Scholar 

  44. Anupama, K.K., Ramya, K., Shainy, K.M., and Joseph, A., Mater. Chem. Phys., 2015, vol. 167, p. 28.

    Article  CAS  Google Scholar 

  45. Yuli Yetri, Emriadi, Novesar Jamarun, and Gunawarman, Proc. Int. Conference on Biological, Chemical and Environmental Sciences (BCES-2014), Penang, 2014, vol. 14, p. 15.

  46. Shalabi, K. and Abdel Nazeer, A.,Prot. Met. Phys. Chem. Surf., 2015, vol. 51, p. 908.

    Article  CAS  Google Scholar 

  47. Hazazi, O.A., Fawzy, A., and Awad, M., Int. J. Electrochem. Sci., 2014, vol. 9, p. 4086.

    Google Scholar 

  48. Jevremović, I., Singer, M., Nešić, S., and Mišković-Stanković, V., Corros. Sci., 2013, vol. 77, p. 265.

    Article  CAS  Google Scholar 

  49. Ehsani, A., Mahjani, M.G., Hosseini, M., Safari, R., Moshrefi, R., and Shiri, H.M., J. Colloid Interface Sci., 2017, vol. 490, p. 444.

    Article  CAS  Google Scholar 

  50. Li, X., Deng, S., and Fu, H., Corros. Sci., 2009, vol. 51, p. 1344.

    Article  CAS  Google Scholar 

  51. Saliyan, R. and Adhikari, A.V., Bull. Mater. Sci., 2008, vol. 31, p. 699.

    Article  CAS  Google Scholar 

  52. Sin, H.L.Y., Rahim, A.A., Gan, C.Y., Saad, B., Salleh, M.I., and Umeda, M., Measurement, 2017, vol. 109, p. 334.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, New Valley University, 72511, El-Kharja, Egypt

    Emad E. El-Katori

Authors
  1. Emad E. El-Katori
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Emad E. El-Katori.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Emad E. El-Katori The Role of Echium Angustifolium Mill Extract in The Corrosion Mitigation of Carbon Steel in Sulfuric Acid Solution. Prot Met Phys Chem Surf 56, 1081–1095 (2020). https://doi.org/10.1134/S207020512005010X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S207020512005010X

Keywords:

Search

Navigation