Fabrication and Corrosion Resistance Evaluation of Novel Epoxy/Oxide Layer (MgO) Coating on Mg Alloy

Abstract

A protective novel (MgO) oxide layer (with 91.92% corrosion protection efficiency) was successfully applied on Mg–0.4%Ca alloy using protective oxidation at 390°C (without any pre-treatment). Oxide layer coated Mg alloy was then coated with pure epoxy coating (as top coat). This oxide inner barrier layer protected Mg substrate from 3.5wt % NaCl solution when it passes through from epoxy top layer. Lowest anodic current density and highest charge transfer resistance (1118.124 kΩ cm2) and impedance modulus (│Z│) at low frequency substantiated that the existence of thick epoxy top layer which is integrated (via physical anchoring) with the oxide inner barrier layer could considerably reduce the corrosion rate of magnesium substrate in the chloride containing solutions. Moreover, corrosion mechanism for coated Mg–0.4%Ca alloys was then suggested.

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REFERENCES

  1. 1

    Li, X., Wu, S., Yeung, K., Zheng, Y., and Chu, P.K., Acta Biomater., 2016, vol. 45, pp. 2–30.

    CAS  Article  Google Scholar 

  2. 2

    Mizutani, Y., Kim, S., Ichino, R., and Okido, M., Surf. Coat. Technol., 2003, vol. 169, pp. 143–146.

    Article  CAS  Google Scholar 

  3. 3

    Nakamura, K., Shimada, Y., Miyashita, T., Serizawa, A., and Ishizaki, T., Materials, 2018, vol. 11, no. 9, p. 1659.

    Article  CAS  Google Scholar 

  4. 4

    Tan, Q., Atrens, A., Mo, N., and Zhang, M.X., Corros. Sci., 2016, vol. 112, pp. 734–759.

    CAS  Article  Google Scholar 

  5. 5

    Daroonparvar, M., Yajid, M.A.M., Yusof, N.M., and Bakhsheshi-Rad, H.R., J. Alloys Compd., 2016, vol. 688, pp. 841–857.

    CAS  Article  Google Scholar 

  6. 6

    Walsh, F., Low, C., Wood, R., Stevens, K., Archer, J., Poeton, A., and Ryder, A., Trans.IMF, 2009, vol. 87, no. 3, pp. 122–135.

    CAS  Article  Google Scholar 

  7. 7

    Gray, J. and Luan, B., J. Alloys Compd., 2002, vol. 336, nos. 1–2, pp. 88–113.

    CAS  Article  Google Scholar 

  8. 8

    Daroonparvar, M., Yajid, M.A.M., Yusof, N.M., and Bakhsheshi-Rad, H.R., J. Alloys Compd., 2015, vol. 645, pp. 450–466.

    CAS  Article  Google Scholar 

  9. 9

    Daroonparvar, M., Yajid, M.A.M., Yusof, N.M., Bakhsheshi-Rad, H.R., Hamzah, E., and Kamali, H.A., J. Alloys Compd., 2014, vol. 615, pp. 657–671.

    CAS  Article  Google Scholar 

  10. 10

    Bakhsheshi-Rad, H.R., Hamzah, E., Ebrahimi-Kahrizsangi, R., Daroonparvar, M., and Medraj, M., Vacuum, 2016, vol. 125, pp. 185–188.

    CAS  Article  Google Scholar 

  11. 11

    Jun Cui, X., Tian Li, M., Song Yang, R., and Yu, Z., Appl. Surf. Sci., 2016, vol. 363, pp. 91–100.

    CAS  Article  Google Scholar 

  12. 12

    Liu, J., Yu, Q., Yu, M., Li, S., Zhao, K., Xue, B., and Zu, H., J. Alloys Compd., 2018, vol. 744, pp. 728–739.

    CAS  Article  Google Scholar 

  13. 13

    Lamaka, S.V., Xue, H.B., Meis, N.N.A.H., Esteves, A.C.C., and Ferreira, M.G.S., Prog. Org. Coat., 2015, vol. 80, pp. 98–105.

    CAS  Article  Google Scholar 

  14. 14

    Toorani, M., Aliofkhazraei, M., Naderi, R., Golabadi, M., and Rouhaghdam, A.S., J. Ind. Eng. Chem., 2017, vol. 53, pp. 213–227.

    CAS  Article  Google Scholar 

  15. 15

    Conceicao, T.F., Scharnagl, N., Blawert, C., Dietzel, W., and Kainer, K., Corros. Sci., 2010, vol. 52, no. 6, pp. 2066–2079.

    CAS  Article  Google Scholar 

  16. 16

    Hu, R.-G., Zhang, S., Bu, J.-F., Lin, C.-J., and Song, G.-L., Prog. Org. Coat., 2012, vol. 73, nos. 2–3, pp. 129–141.

    CAS  Article  Google Scholar 

  17. 17

    Bakhsheshi-Rad, H.R., Hamzah, E., Abdul-Kadir, M.R., Daroonparvar, M., and Medraj, M., Vacuum, 2015, vol. 119, pp. 95–98.

    CAS  Article  Google Scholar 

  18. 18

    Bakhsheshi-Rad, H.R., Hamzah, E., Ismail, A.F., Daroonparvar, M., Medraj, M., and Yajid, M.A.M., J. Alloys Compd., 2016, vol. 658, pp. 440–452.

    CAS  Article  Google Scholar 

  19. 19

    Agarwal, S., Curtin, J., Duffy, B., and Jaiswal, S., Mater. Sci. Eng., C, 2016, vol. 68, pp. 948–963.

    CAS  Article  Google Scholar 

  20. 20

    Ju, H., Chang, W., Zhao, L., Chen, Y., Li, J., and Zhang, X., Mater. Lett., 2012, vol. 68, pp. 435–438.

    Article  CAS  Google Scholar 

  21. 21

    Hagans, P.L. and Haas, C., in ASM Handbook, vol. 5: Surface Engineering, Cotell, C.M., Sprague, J.A., and Smidt, F.A., Jr., Eds., Materials Park, OH: ASM Int., 1994, pp. 405–411.

  22. 22

    Darband, G., Aliofkhazraei, B., Hamghalam, M., and Valizade, N., J. Magnesium Alloys, 2017, vol. 5, no. 1, pp. 74–132.

    Article  CAS  Google Scholar 

  23. 23

    Lei, T., Ouyang, C., Tang, W., Li, L.F., and Zhou, L.S., Corros. Sci., 2010, vol. 52, pp. 3504–3508.

    CAS  Article  Google Scholar 

  24. 24

    Xu, Z., Eduok, U., and Szpunar, J., Surf. Coat. Technol., 2019, vol. 357, pp. 691–697.

    CAS  Article  Google Scholar 

  25. 25

    Gu, X.N., Zheng, W., Cheng, Y., and Zheng, Y.F., Acta Biomater., 2009, vol. 5, pp. 2790–2799.

    CAS  Article  Google Scholar 

  26. 26

    Wen, X., Jiang, Y.B., Yang, H., Yang, Q., Xia, X.S., and Pan, F.S., Appl. Surf. Sci., 2015, vol. 353, pp. 1013–1022.

    Article  CAS  Google Scholar 

  27. 27

    Tan, Q., Atrens, A., Mo, N., and Zhang M.X., Corros. Sci., 2016, vol. 112, pp. 734–759.

    CAS  Article  Google Scholar 

  28. 28

    Czerwinski, F., Corros. Sci., 2004, vol. 46, pp. 377–386.

    CAS  Article  Google Scholar 

  29. 29

    Qiyang Tan, Ning Mo, Bin Jiang, Fusheng Pan, and Andrej Atrens, Corros. Sci., 2017, vol. 122, pp. 1–11.

    CAS  Article  Google Scholar 

  30. 30

    Byung-Ho Choi, Bong-Sun Yo, Won-Wook Park, and Yan-Bin Huang, Met. Mater. Int., 2003, vol. 9, pp. 395–398.

    CAS  Article  Google Scholar 

  31. 31

    ASTM G1-03: Standard Practice for Preparing, Cleaning, and Evaluating Corrosion Test Specimens, West Conshohocken, PA: ASTM Int., 2011.

  32. 32

    Daroonparvar, M., Hussain, M.S., and Yajid, M.A.M., Appl. Surf. Sci., 2012, vol. 261, pp. 287–297.

    CAS  Article  Google Scholar 

  33. 33

    Daroonparvar, M., Yajid, M.A.M., Kay, C.M., Bakhsheshi-Rad, H.R., Gupta, R.K., et al., Corros. Sci., 2018, vol. 144, pp. 13–34.

    CAS  Article  Google Scholar 

  34. 34

    Van Orman, J.A. and Crispin, K.L., Rev. Mineral. Geochem., 2010, vol. 72, pp. 757–825.

    CAS  Article  Google Scholar 

  35. 35

    Ahrens, L.H., Geochim. Cosmochim. Acta, 1952, vol. 2, pp. 155–169.

    CAS  Article  Google Scholar 

  36. 36

    Konar, B., Geun Kim, D., and Jung, I., Ceram. Int., 2017, vol. 43, pp. 13055–13062.

    CAS  Article  Google Scholar 

  37. 37

    Czerwinski, F., Acta Mater., 2002, vol. 50, pp. 2639–2654.

    CAS  Article  Google Scholar 

  38. 38

    Jeurgens, L.P.H., Vinodh, M.S., and Mittemeijer, E.J., Acta Mater., 2008, vol. 56, pp. 4621–4634.

    CAS  Article  Google Scholar 

  39. 39

    Nam, P.S., Zhao-Hua, J., and Zhong-Ping, Y., Surf. Coat. Technol., 2017, vol. 325, pp. 579–587.

    Article  CAS  Google Scholar 

  40. 40

    Cui, M., Wang, L., Ren, S., Qin, S., Xue, Q., and Zhao, H., RSC Adv., 2017, vol. 7, pp. 44043–44053.

    CAS  Article  Google Scholar 

  41. 41

    Daroonparvar, M., Yajid, M.A.M., Yusof, N.M., Bakhsheshi-Rad, H.R., Hamzah, E., and Mardanikivi, T., J. Alloys Compd., 2015, vol. 649, pp. 591–605.

    CAS  Article  Google Scholar 

  42. 42

    Bakhseshi-Rad, H.R., Idris, M.H., Abdulkadi, M.R., Ourdjini, A., Medraj, M., and Daroonparvar, M., Mater. Des., 2014, vol. 53, pp. 283–292.

    Article  CAS  Google Scholar 

  43. 43

    Daroonparvar, M., Yajid, M.A.M., Gupta, R.K., Yusof, N.M., Bakhsheshi-Rad, H.R., Ghandvar, H., and Ghasemi, E., Trans. Nonferrous Met. Soc. China, 2018, vol. 28, pp. 1571–1581.

    CAS  Article  Google Scholar 

  44. 44

    Zhang, X., Li, Y., Zhang, K., Wang, C., Li, H., Ma, M., and Zhang, B., Trans. Nonferrous Met. Soc. China, 2013, vol. 23, pp. 1226–1236.

    CAS  Article  Google Scholar 

  45. 45

    Xin, Z., Kui, Z., Gang, L., Xia, D., Wei, L., Wang, Z.B., and Shun, C., Trans. Nonferrous Met. Soc. China, 2012, vol. 22, pp. 1018–1027.

    Article  CAS  Google Scholar 

  46. 46

    Liopoulos, I., Karampekios, A., Jouhara, H., Tassou, S., Pandis, P.K., Vourdas, N., and Stathopoulos, V.N., Procedia Struct. Integr., 2018, vol. 10, pp. 295–302.

    Article  Google Scholar 

  47. 47

    Zhou, C., Lu, X., Xin, Z., Liu, J., and Zhang, Y., Corros. Sci., 2014, vol. 80, pp. 269–275.

    CAS  Article  Google Scholar 

  48. 48

    Brett, C.M.A., Dias, L., Trindade, B., Fischer, R., and Mies, S., Electrochim. Acta, 2006, vol. 51, pp. 1752–1760.

    CAS  Article  Google Scholar 

  49. 49

    Hou, S.S., Zhang, R.R., Guan, S.K., Ren, C.X., Gao, J.H., Lu, Q.B., and Cui, X.Z., Appl. Surf. Sci., 2012, vol. 258, pp. 3571–3577.

    CAS  Article  Google Scholar 

  50. 50

    Ren, M., Cai, S., et al., J. Alloys Compd., 2014, vol. 591, pp. 34–40.

    CAS  Article  Google Scholar 

  51. 51

    Bakhsheshi-Rad, H.R., Hamzah, E., Ismail, A.F., Aziz, M., Daroonparvar, M., and Chami, A., Surf. Coat. Technol., 2018, vol. 334, pp. 450–460.

    CAS  Article  Google Scholar 

  52. 52

    Niu, B., Shi, P., Shanshan, E., Wei, D., Li, Q., and Chen, Y., Surf. Coat. Technol., 2016, vol. 286, pp. 42–48.

    CAS  Article  Google Scholar 

  53. 53

    Chen, L., Gu, Y., Liu, L., Liu, S., Hou, B., Liu, Q., and Ding, H., J. Alloys Compd., 2015, vol. 635, pp. 278–288.

    CAS  Article  Google Scholar 

  54. 54

    Liu, M., Mao, X., Zhu, H., Lin, A., and Wang, D., Corros. Sci., 2013, vol. 75, pp. 106–113.

    CAS  Article  Google Scholar 

  55. 55

    Ye, X., Cai, S., Dou, Y., Xu, G., Huang, K., Ren, M., and Wang, X., Appl. Surf. Sci., 2012, vol. 259, pp. 799–805.

    CAS  Article  Google Scholar 

  56. 56

    Wang, Y., Wang, X., et al., J. Mater. Sci. Technol., 2013, vol. 29, pp. 1129–1133.

    Article  CAS  Google Scholar 

  57. 57

    Yousof, M.F., Abdul Kadir, M.R., et al., Surf. Coat. Technol., 2014, vol. 245, pp. 102–107.

    Article  CAS  Google Scholar 

  58. 58

    Mandal, M., Moon, A.P., Deo, G., Mendis, C.L., and Mondal, K., Corros. Sci., 2014, vol. 78, pp. 172–182.

    CAS  Article  Google Scholar 

  59. 59

    Ryu, H.S., Park, D.S., and Hong, S.H., Surf. Coat. Technol., 2013, vol. 219, pp. 82–87.

    CAS  Article  Google Scholar 

  60. 60

    Daroonparvar, M., Yajid, M.M., Bakhsheshi-Rad, H., Yusof, N.M., Izman, S., Hamzah, E., and Kadir, M.R.A., Vacuum, 2014, vol. 108, pp. 61–65.

    CAS  Article  Google Scholar 

  61. 61

    Saud, S.N., Hosseinian, R., Bakhsheshi-Rad, H.R., Yaghoubidoust, F., Hamzah, E.C.H., and Ooi, R., Mater. Sci. Eng., C, 2016, vol. 68, pp. 687–694.

    CAS  Article  Google Scholar 

  62. 62

    Narayanan, T.S.N.S., Park, L.S., and Lee, M.H., Prog. Mater. Sci., 2014, vol. 60, pp. 1–71.

    Article  CAS  Google Scholar 

  63. 63

    Daroonparvar, M., Yajid, M.M., Yusof, N.M., Bakhsheshi-Rad, H., Hamzah, E., Ceram. Int., 2016, vol. 42, pp. 357–371.

  64. 64

    Bakhsheshi-Rad, H., Hamzah, E., Daroonparvar, M., Saud, S.N., Abdul-kadir, M., Vacuum, 2014. vol. 110, p. 135.

  65. 65

    Daroonparvar, M., Yajid, M.M., Gupta, R.K., Yusof, N.M., Bakhsheshi-Rad, H., Ghandvar, H., Prot. Met. Phys. Chem. Surf., 2018, vol. 54, pp. 425–441.

  66. 66

    Daroonparvar, M., Yajid, M.M., Yusof, N.M., Bakhsheshi-Rad, H., Adabi, M., Hamzah, E., Kamali, H., J. Mater. Eng. Perform., 2015, vol. 24, pp. 2614–2627.

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Funding

The authors would like to acknowledge the Universiti Teknologi Malaysia (UTM) for providing research facilities and financial support under grants of Fundamental Research Grant Scheme (FRGS), Ministry of Education (R.J130000.7851.5F023), RUG—Q.J130000.2524.16H35 and Nippon Sheet Glass—R.J130000.7324.4B300.

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Mohammadreza Daroonparvar, Yajid, M.A., Bakhsheshi-Rad, H.R. et al. Fabrication and Corrosion Resistance Evaluation of Novel Epoxy/Oxide Layer (MgO) Coating on Mg Alloy. Prot Met Phys Chem Surf 56, 1039–1050 (2020). https://doi.org/10.1134/S2070205120050093

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Keywords:

  • composite materials
  • oxidation
  • corrosion
  • microstructure
  • X-ray diffraction